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Titanium Silicon Carbide
Titanium silicon carbide, chemical formula Ti3SiC2, is a material with both metallic and ceramic properties. It is one of the MAX phases The MAX phases are layered, hexagonal carbides and nitrides which have the general formula: Mn+1AXn, (MAX) where n = 1 to 4, and M is an early transition metal, A is an A-group (mostly IIIA and IVA, or groups 13 and 14) element and X is either carbo .... References Extra reading * * Titanium compounds Carbides Silicon compounds {{Material-stub ...
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Metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile (can be drawn into wires) and malleable (they can be hammered into thin sheets). These properties are the result of the ''metallic bond'' between the atoms or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polymeric sulfur nitride. In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of absolute zero. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal iodine gradually becomes a metal at a pressure of between 40 and 170 thousand times atmospheric pressure. Equally, some materials regarded as metals ...
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Ceramic
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, and brick. The earliest ceramics made by humans were pottery objects (''pots,'' ''vessels or vases'') or figurines made from clay, either by itself or mixed with other materials like silica, hardened and sintered in fire. Later, ceramics were glazed and fired to create smooth, colored surfaces, decreasing porosity through the use of glassy, amorphous ceramic coatings on top of the crystalline ceramic substrates. Ceramics now include domestic, industrial and building products, as well as a wide range of materials developed for use in advanced ceramic engineering, such as in semiconductors. The word "'' ceramic''" comes from the Greek word (), "of pottery" or "for pottery", from (), "potter's clay, tile, pottery". The earliest kno ...
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MAX Phases
The MAX phases are layered, hexagonal carbides and nitrides which have the general formula: Mn+1AXn, (MAX) where n = 1 to 4, and M is an early transition metal, A is an A-group (mostly IIIA and IVA, or groups 13 and 14) element and X is either carbon and/or nitrogen. The layered structure consists of edge-sharing, distorted XM6 octahedra interleaved by single planar layers of the A-group element. History In the 1960s, H. Nowotny and co-workers discovered a large family of ternary, layered carbides and nitrides, which they called the 'H' phases, now known as the '211' MAX phases (i.e. n = 1), and several '312' MAX phases. Subsequent work extended to '312' phases such as Ti3SiC2 and showed it to have unusual mechanical properties. In 1996, Barsoum and El-Raghy synthesized for the first time fully dense and phase pure Ti3SiC2 and revealed, by characterization, that it possesses a distinct combination of some of the best properties of metals and engineering ceramics. In 1999 they a ...
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Titanium Compounds
The +4 oxidation state dominates titanium chemistry, but compounds in the +3 oxidation state are also numerous. Commonly, titanium adopts an octahedral coordination geometry in its complexes, but tetrahedral TiCl4 is a notable exception. Because of its high oxidation state, titanium(IV) compounds exhibit a high degree of covalent bonding. Oxides, sulfides, and alkoxides The most important oxide is TiO2, which exists in three important polymorphs; anatase, brookite, and rutile. All three are white diamagnetic solids, although mineral samples can appear dark (see rutile). They adopt polymeric structures in which Ti is surrounded by six oxide ligands that link to other Ti centers. The term ''titanates'' usually refers to titanium(IV) compounds, as represented by barium titanate (BaTiO3). With a perovskite structure, this material exhibits piezoelectric properties and is used as a transducer in the interconversion of sound and electricity. Many minerals are titanates, such as ilme ...
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Carbides
In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece. Interstitial / Metallic carbides The carbides of the group 4, 5 and 6 transition metals (with the exception of chromium) are often described as interstitial compounds. These carbides have metallic properties and are refractory. Some exhibit a range of stoichiometries, being a non-stoichiometric mixture of various carbides arising due to crystal defects. Some of them, including titanium carbide and tungsten carbide, are important industrially and are used to coat metals in cutting tools. The long-held view is that the carbon atoms fit into octahedral interstices in a close-packed metal lattice when the metal atom radius is greater than approximately 135 pm: *When the metal atoms are cubic close-packed, (ccp), then filling all of the octahedral interstices with carbon achieves 1:1 stoich ...
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