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Thermal Runaway
Thermal runaway describes a process that is accelerated by increased temperature, in turn releasing energy that further increases temperature. Thermal runaway occurs in situations where an increase in temperature changes the conditions in a way that causes a further increase in temperature, often leading to a destructive result. It is a kind of uncontrolled positive feedback. In chemistry (and chemical engineering), thermal runaway is associated with strongly exothermic reactions that are accelerated by temperature rise. In electrical engineering, thermal runaway is typically associated with increased current flow and power dissipation. Thermal runaway can occur in civil engineering, notably when the heat released by large amounts of curing concrete is not controlled. In astrophysics, runaway nuclear fusion reactions in stars can lead to nova and several types of supernova explosions, and also occur as a less dramatic event in the normal evolution of solar-mass stars, the " he ...
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4 Degrees And Beyond International Climate Conference
The 4 Degrees and Beyond International Climate Conference, subtitled ''Implications of a Global Climate Change of 4+ Degrees for People, Ecosystems and the Earth-system'', was held 28–30 September 2009 at Oxford, United Kingdom. The three-day conference had about 140 science, government, NGO and private sector delegates, and included 35 oral presentations and 18 poster presentations. The conference website includes a page for downloading abstracts, presentations, audio recordings, and the programme. Links to a number of news stories are also provided. The conference was sponsored by the University of Oxford, the Tyndall Centre for Climate Change Research, and the Met Office Hadley Centre. Video podcasts of all oral presentations are posted on a University of Oxford website; however, to find videos by presenter names the above cited program must first be consulted to find the presentation title. In January 2011, eleven papers and three introductory articles resulting from the co ...
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Chemical Accidents
A chemical accident is the unintentional release of one or more chemical hazard substances which could harm human health and the environment. Such events include fires, explosions, leakages or release of toxic or hazardous materials that can cause people illness, injury, or disability. Chemical accident can be caused by natural disaster, or accidental human error, or deliberate move to cause chaos and destructions for personal gain. While chemical accidents may occur whenever toxic materials are stored, transported or used, the most severe are industrial accidents, involving major chemical manufacturing and storage facilities. Examples The most dangerous chemical accident recorded in history was the 1984 Bhopal gas tragedy in India, in which more than 3,000 people died after a highly toxic vapor, methyl isocyanate, was released at a Union Carbide Pesticides factory. The release happened after the storage tank safety valve had failed to contain the excess pressure created by t ...
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Reaction Rate
The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. Reaction rates can vary dramatically. For example, the oxidative rusting of iron under Earth's atmosphere is a slow reaction that can take many years, but the combustion of cellulose in a fire is a reaction that takes place in fractions of a second. For most reactions, the rate decreases as the reaction proceeds. A reaction's rate can be determined by measuring the changes in concentration over time. Chemical kinetics is the part of physical chemistry that concerns how rates of chemical reactions are measured and predicted, and how reaction-rate data can be used to deduce probable reaction mechanisms. The concepts of chemical kinetics are applied in many disciplines, such as chemical engineering, enzymology and environmental engin ...
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Exothermic Reaction
In thermochemistry, an exothermic reaction is a "reaction for which the overall standard enthalpy change Δ''H''⚬ is negative." Exothermic reactions usually release heat. The term is often confused with exergonic reaction, which IUPAC defines as "... a reaction for which the overall standard Gibbs energy change Δ''G''⚬ is negative." A strongly exothermic reaction will usually also be exergonic because Δ''H''⚬ makes a major contribution to Δ''G''⚬. Most of the spectacular chemical reactions that are demonstrated in classrooms are exothermic and exergonic. The opposite is an endothermic reaction, which usually takes up heat and is driven by an entropy increase in the system. Examples Examples are numerous: combustion, the thermite reaction, combining strong acids and bases, polymerizations. As an example in everyday life, hand warmers make use of the oxidation of iron to achieve an exothermic reaction: :4Fe  + 3O2  → 2Fe2O3  ...
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Organic Chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; Greeves, N. and Warren, S. (2012) ''Organic Chemistry''. Oxford University Press. pp. 1–15. . Study of structure determines their structural formula. Study of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior. The study of organic reactions includes the chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical ( in silico) study. The range of chemicals studied in organic chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but also containing other elements, especially oxygen, nitrogen, sulfur, phosphorus (included in ...
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Clathrate Gun Hypothesis
The clathrate gun hypothesis is a proposed explanation for the periods of rapid warming during the Quaternary. The idea is that changes in fluxes in upper intermediate waters in the ocean caused temperature fluctuations that alternately accumulated and occasionally released methane clathrate on upper continental slopes. This would have had an immediate impact on the global temperature, as methane is a much more powerful greenhouse gas than carbon dioxide. Despite its atmospheric lifetime of around 12 years, methane's global warming potential is 72 times greater than that of carbon dioxide over 20 years, and 25 times over 100 years (33 when accounting for aerosol interactions).These warming events would have caused the Bond Cycles and individual interstadial events, such as the Dansgaard–Oeschger interstadials. The hypothesis was supported for the Bølling-Allerød and Preboreal period, but not for Dansgaard–Oeschger interstadials, although there are still debates on the to ...
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Methane Clathrate
Methane clathrate (CH4·5.75H2O) or (8CH4·46H2O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice. Originally thought to occur only in the outer regions of the Solar System, where temperatures are low and water ice is common, significant deposits of methane clathrate have been found under sediments on the ocean floors of the Earth. Methane hydrate is formed when hydrogen-bonded water and methane gas come into contact at high pressures and low temperatures in oceans. Methane clathrates are common constituents of the shallow marine geosphere and they occur in deep Sedimentary rock, sedimentary structures and form outcrops on the ocean floor. Methane hydrates are believed to form by the precipitation or crystallisation of methane migrating from d ...
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Permafrost
Permafrost is ground that continuously remains below 0 °C (32 °F) for two or more years, located on land or under the ocean. Most common in the Northern Hemisphere, around 15% of the Northern Hemisphere or 11% of the global surface is underlain by permafrost, with the total area of around 18 million km2. This includes substantial areas of Alaska, Greenland, Canada and Siberia. It can also be located on mountaintops in the Southern Hemisphere and beneath ice-free areas in the Antarctic. Permafrost does not have to be the first layer that is on the ground. It can be from an inch to several miles deep under the Earth's surface. It frequently occurs in ground ice, but it can also be present in non-porous bedrock. Permafrost is formed from ice holding various types of soil, sand, and rock in combination. Permafrost contains large amounts of biomass and decomposed biomass that has been stored as methane and carbon dioxide, making tundra soil a carbon sink. As global war ...
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Wetland
A wetland is a distinct ecosystem that is flooded or saturated by water, either permanently (for years or decades) or seasonally (for weeks or months). Flooding results in oxygen-free (anoxic) processes prevailing, especially in the soils. The primary factor that distinguishes wetlands from terrestrial land forms or Body of water, water bodies is the characteristic vegetation of aquatic plants, adapted to the unique anoxic hydric soils. Wetlands are considered among the most biologically diverse of all ecosystems, serving as home to a wide range of plant and animal species. Methods for assessing wetland functions, wetland ecological health, and general wetland condition have been developed for many regions of the world. These methods have contributed to wetland conservation partly by raising public awareness of the functions some wetlands provide. Wetlands occur naturally on every continent. The water in wetlands is either freshwater, brackish or seawater, saltwater. The main w ...
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Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ...
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