Taraxacoside
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Taraxacoside
Taraxacoside is an acylated γ-butyrolactone glycoside with the molecular formula C18H22O10 which has been isolated from roots of the plant ''Taraxacum officinale ''Taraxacum officinale'', the dandelion or common dandelion, is a flowering Herbaceous plant, herbaceous perennial plant of the Dandelion, dandelion genus in the family Asteraceae (syn. Compositae). The common dandelion is well known for its yell ...''. References Further reading * Glycosides Tetrahydrofurans Phenyl compounds {{organic-compound-stub ...
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Acylated γ-butyrolactone Glycoside
In chemistry, acylation (or alkanoylation) is the chemical reaction in which an acyl group () is added to a compound. The compound providing the acyl group is called the acylating agent. Because they form a strong electrophile when treated with some metal catalysts, acyl halides are commonly used as acylating agents. For example, Friedel–Crafts acylation uses acetyl chloride (ethanoyl chloride or ) as the agent and aluminum chloride () as a catalyst to add an ethanoyl (acetyl) group to benzene: The mechanism of this reaction is electrophilic aromatic substitution. Acyl halides and acid anhydrides of carboxylic acids are also commonly used acylating agents. In some cases, active esters exhibit comparable reactivity. All react with amines to form amides and with alcohols to form esters by nucleophilic acyl substitution. Acylation can be used to prevent rearrangement reactions that would normally occur in alkylation. To do this an acylation reaction is performed, then the carb ...
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Taraxacum Officinale
''Taraxacum officinale'', the dandelion or common dandelion, is a flowering herbaceous perennial plant of the dandelion genus in the family Asteraceae (syn. Compositae). The common dandelion is well known for its yellow flower heads that turn into round balls of many silver-tufted fruits that disperse in the wind. These balls are usually called "clocks" in both British and American English. The name "blowball" is also used. The common dandelion grows in temperate regions of the world in areas with moist soils. It is most often considered a weed, especially in lawns and along roadsides, but the leaves, flowers, and roots are sometimes used in herbal medicine and as food. Description ''Taraxacum officinale'' grows from (generally unbranched) taproots and produces several hollow, leafless flower stems that are typically tall, but sometimes up to tall. The stems can be tinted purplish, they are upright or lax, and produce flower heads that are held as tall or taller than the ...
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Glycosides
In chemistry, a glycoside is a molecule in which a sugar is bound to another functional group via a glycosidic bond. Glycosides play numerous important roles in living organisms. Many plants store chemicals in the form of inactive glycosides. These can be activated by enzyme hydrolysis, which causes the sugar part to be broken off, making the chemical available for use. Many such plant glycosides are used as medications. Several species of ''Heliconius'' butterfly are capable of incorporating these plant compounds as a form of chemical defense against predators. In animals and humans, poisons are often bound to sugar molecules as part of their elimination from the body. In formal terms, a glycoside is any molecule in which a sugar group is bonded through its anomeric carbon to another group via a glycosidic bond. Glycosides can be linked by an O- (an ''O-glycoside''), N- (a ''glycosylamine''), S-(a ''thioglycoside''), or C- (a '' C-glycoside'') glycosidic bond. According to th ...
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