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TEX86
TEX86 is an organic paleothermometer based upon the membrane lipids of mesophilic marine Nitrososphaerota (formerly Marine Group 1 Crenarchaeota). Basics The membrane lipids of Nitrososphaerota are composed of glycerol dialkyl glycerol tetraethers (GDGTs) which contain 0-3 cyclopentane moieties. Nitrososphaerota also synthesise crenarchaeol which contains four cyclopentane moieties and a single cyclohexane moiety and a regio-isomer. The cyclohexane and cyclopentane rings, formed by internal cyclisation of one of the biphytane chains, have a pronounced effect on the thermal transition points of the Nitrososphaerota cell membrane. Mesocosm studies demonstrate that the degree of cyclisation is generally governed by growth temperature. Calibrations Based upon the relative distribution of isoprenoidal GDGTs, Schouten et al. (2002) proposed the tetraether index of 86 carbon atoms (TEX86) as a proxy for sea surface temperature (SST). GDGT-0 is excluded from the calibration as it can ha ...
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Glycerol Dialkyl Glycerol Tetraethers
Glycerol dialkyl glycerol tetraether lipids (GDGTs) are a class of membrane lipids synthesized by archaea and some bacteria, making them useful biomarkers for these organisms in the geological record. Their presence, structure, and relative abundances in natural materials can be useful as proxies for temperature, terrestrial organic matter input, and soil pH for past periods in Earth history. Some structural forms of GDGT form the basis for the TEX86 paleothermometer. Isoprenoid GDGTs, now known to be synthesized by many archaeal classes, were first discovered in extremophilic archaea cultures. Branched GDGTs, likely synthesized by acidobacteriota, were first discovered in a natural Dutch peat sample in 2000. Chemical structure The two primary structural classes of GDGTs are isoprenoid (isoGDGT) and branched (brGDGT), which refer to differences in the carbon skeleton structures. Isoprenoid compounds are numbered -0 through -8, with the numeral representing the number of cyclopentan ...
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Mg/Ca
A paleothermometer is a methodology that provides an estimate of the ambient temperature at the time of formation of a natural material. Most paleothermometers are based on empirically-calibrated proxy relationships, such as the tree ring or TEX86 methods. Isotope methods, such as the δ18O method or the clumped-isotope method, are able to provide, at least in theory, direct measurements of temperature. Common paleothermometers The isotopic ratio of 18O to 16O, usually in foram tests or ice cores. High values mean low temperatures. Confounded by ice volume - more ice means higher values. Ocean water is mostly H216O, with small amounts of HD16O and H218O. In Standard Mean Ocean Water (SMOW) the ratio of D to H is and 18O/16O is . Fractionation occurs during changes between condensed and vapour phases: the vapour pressure of heavier isotopes is lower, so vapour contains relatively more of the lighter isotopes and when the vapour condenses the precipitation preferentia ...
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Paleothermometer
A paleothermometer is a methodology that provides an estimate of the ambient temperature at the time of formation of a natural material. Most paleothermometers are based on empirically-calibrated proxy relationships, such as the tree ring or TEX86 methods. Isotope methods, such as the δ18O method or the clumped-isotope method, are able to provide, at least in theory, direct measurements of temperature. Common paleothermometers The isotopic ratio of 18O to 16O, usually in foram tests or ice cores. High values mean low temperatures. Confounded by ice volume - more ice means higher values. Ocean water is mostly H216O, with small amounts of HD16O and H218O. In Standard Mean Ocean Water (SMOW) the ratio of D to H is and 18O/16O is . Fractionation occurs during changes between condensed and vapour phases: the vapour pressure of heavier isotopes is lower, so vapour contains relatively more of the lighter isotopes and when the vapour condenses the precipitation preferentia ...
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Paleothermometer
A paleothermometer is a methodology that provides an estimate of the ambient temperature at the time of formation of a natural material. Most paleothermometers are based on empirically-calibrated proxy relationships, such as the tree ring or TEX86 methods. Isotope methods, such as the δ18O method or the clumped-isotope method, are able to provide, at least in theory, direct measurements of temperature. Common paleothermometers The isotopic ratio of 18O to 16O, usually in foram tests or ice cores. High values mean low temperatures. Confounded by ice volume - more ice means higher values. Ocean water is mostly H216O, with small amounts of HD16O and H218O. In Standard Mean Ocean Water (SMOW) the ratio of D to H is and 18O/16O is . Fractionation occurs during changes between condensed and vapour phases: the vapour pressure of heavier isotopes is lower, so vapour contains relatively more of the lighter isotopes and when the vapour condenses the precipitation preferentia ...
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Nitrososphaerota
The Nitrososphaerota (syn. Thaumarchaeota) are a phylum of the Archaea proposed in 2008 after the genome of ''Cenarchaeum symbiosum'' was sequenced and found to differ significantly from other members of the hyperthermophilic phylum Thermoproteota (formerly Crenarchaeota). Three described species in addition to ''C. symbiosum'' are ''Nitrosopumilus maritimus'', ''Nitrososphaera viennensis'', and ''Nitrososphaera gargensis''. The phylum was proposed in 2008 based on phylogenetic data, such as the sequences of these organisms' ribosomal RNA genes, and the presence of a form of type I topoisomerase that was previously thought to be unique to the eukaryotes. This assignment was confirmed by further analysis published in 2010 that examined the genomes of the ammonia-oxidizing archaea ''Nitrosopumilus maritimus'' and ''Nitrososphaera gargensis'', concluding that these species form a distinct lineage that includes ''Cenarchaeum symbiosum''. The lipid crenarchaeol has been found only i ...
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Eocene
The Eocene ( ) Epoch is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (mya). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene'' comes from the Ancient Greek (''ēṓs'', "dawn") and (''kainós'', "new") and refers to the "dawn" of modern ('new') fauna that appeared during the epoch. The Eocene spans the time from the end of the Paleocene Epoch to the beginning of the Oligocene Epoch. The start of the Eocene is marked by a brief period in which the concentration of the carbon isotope Carbon-13, 13C in the atmosphere was exceptionally low in comparison with the more common isotope Carbon-12, 12C. The end is set at a major extinction event called the ''Grande Coupure'' (the "Great Break" in continuity) or the Eocene–Oligocene extinction event, which may be related to the impact of one or more large bolides in Popigai impact structure, Siberia and in what is now ...
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Molecular Structures And HPLC Detection Of GDGTs
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and ''molecule'' is often used when referring to polyatomic ions. A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H2O). In the kinetic theory of gases, the term ''molecule'' is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considere ...
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Cenozoic
The Cenozoic ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterised by the dominance of mammals, birds and flowering plants, a cooling and drying climate, and the current configuration of continents. It is the latest of three geological eras since complex life evolved, preceded by the Mesozoic and Paleozoic. It started with the Cretaceous–Paleogene extinction event, when many species, including the non-avian dinosaurs, became extinct in an event attributed by most experts to the impact of a large asteroid or other celestial body, the Chicxulub impactor. The Cenozoic is also known as the Age of Mammals because the terrestrial animals that dominated both hemispheres were mammalsthe eutherians (placentals) in the northern hemisphere and the metatherians (marsupials, now mainly restricted to Australia) in the southern hemisphere. The extinction of many groups allowed mammals and birds to greatly diversify so that l ...
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Tasman Gateway
Tasman most often refers to Abel Tasman (1603–1659), Dutch explorer. Tasman may also refer to: Animals and plants * Tasman booby * Tasman flax-lily * Tasman parakeet (other) * Tasman starling * Tasman whale People * Tasman (name), a name of Dutch origin, including a list of people with the name Places New Zealand * Mount Tasman, in the Southern Alps of South Island * Tasman Bay / Te Tai-o-Aorere, at the northern end of South Island * Tasman Glacier, in the Southern Alps of South Island * Tasman Lake, formed by recent melting and retreat of the Tasman Glacier * Tasman Region, a region and a district of New Zealand in the north of South Island * Tasman River, flowing from Tasman Lake and contributed to by other glacial rivers Tasmania, Australia * Tasman Fracture, an ocean trench southwest of Tasmania * Tasman Island, an island off the southeast coast of the Tasman Peninsula * Tasman National Park, at the south end of the Tasman Peninsula * Tasman Outflow, an ocean ...
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Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ...
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Alkenones
Alkenones are long-chain unsaturated methyl and ethyl ''n''-ketones produced by a few phytoplankton species of the class Prymnesiophyceae.Marlowe, I.T., Green, J.C., Neal, A.C., Brassell, S.C., Eglinton, G. and Course, P.A. (1984) "Long-chain (''n''-C37-C39) alkenones in the Prymnesiophyceae. Distribution of alkenones and other lipids and their taxonomic significance." ''British Phycological Journal'' 19, 203-216; doi:10.1080/00071618400650221. Alkenones typically contain between 35 and 41 carbon atoms and with between two and four double bonds.Rontani J.F., Prahl F.G. and Volkman J.K. (2006) "Re-examination of the double bond positions in alkenones and derivatives: biosynthetic implications." ''Journal of Phycology'' 42, 800–813; doi:10.1111/j.1529-8817.2006.00251.x. Uniquely for biolipids, alkenones have a spacing of five methylene groups between double bonds, which are of the less common E configuration. The biological function of alkenones remains under debate although it ...
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Foraminifera
Foraminifera (; Latin for "hole bearers"; informally called "forams") are single-celled organisms, members of a phylum or class of amoeboid protists characterized by streaming granular Ectoplasm (cell biology), ectoplasm for catching food and other uses; and commonly an external shell (called a "Test (biology), test") of diverse forms and materials. Tests of chitin (found in some simple genera, and Textularia in particular) are believed to be the most primitive type. Most foraminifera are marine, the majority of which live on or within the seafloor sediment (i.e., are benthos, benthic), while a smaller number float in the water column at various depths (i.e., are planktonic), which belong to the suborder Globigerinina. Fewer are known from freshwater or brackish conditions, and some very few (nonaquatic) soil species have been identified through molecular analysis of small subunit ribosomal DNA. Foraminifera typically produce a test (biology), test, or shell, which can have eithe ...
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