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Spinel Group
The spinels are any of a class of minerals of general formulation which crystallise in the cubic (isometric) crystal system, with the X anions (typically chalcogens, like oxygen and sulfur) arranged in a cubic close-packed lattice and the cations A and B occupying some or all of the octahedral and tetrahedral sites in the lattice.H-J MeyerFestkörperchemiein: H-J Meyer (ed.), ''Riedel Moderne Anorganische Chemie'', Walter de Gruyter, 2012, . Retrieved 15 April 2018. Although the charges of A and B in the prototypical spinel structure are +2 and +3, respectively (), other combinations incorporating divalent, trivalent, or tetravalent cations, including magnesium, zinc, iron, manganese, aluminium, chromium, titanium, and silicon, are also possible. The anion is normally oxygen; when other chalcogenides constitute the anion sublattice the structure is referred to as a thiospinel. A and B can also be the same metal with different valences, as is the case with magnetite, (as ), whic ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The Geology, geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock (geology), rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate (geology), aggregate of two or more different types of m ...
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Chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardness. A major development in steel production was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel. Stainless steel and chrome plating ( electroplating with chromium) together comprise 85% of the commercial use. Chromium is also greatly valued as a metal that is able to be highly polished while resisting tarnishing. Polished chromium reflects almost 70% of the visible spectrum, and almost 90% of infrared light. The name of the element is derived from the Greek word χρῶμα, ''chrōma'', meaning color, because many chromium compounds are intensely colored. Industrial production of chromium proceeds from chromite ore (mostly FeCr2O4) to produce ...
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Cuprospinel
Cuprospinel is a mineral. Cuprospinel is an inverse spinel with the chemical formula CuFe2O4, where copper substitutes some of the iron cations in the structure. Its structure is similar to that of magnetite, Fe3O4, yet with slightly different chemical and physical properties due to the presence of copper. The type locality of cuprospinel is Baie Verte, Newfoundland, Canada, where the mineral was found in an exposed ore dump. The mineral was first characterized by Ernest Henry Nickel, a mineralogist with the Department of Energy, Mines and Resources in Australia, in 1973. Cuprospinel is also found in other places, for example, in Hubei province, China and at Tolbachik volcano in Kamchatka, Russia. Structural properties Cuprospinel, like many other spinels has the general formula AB2O4. Yet, cuprospinel is an ''inverse'' spinel in that its ''A'' element, in this case copper (Cu2+), only occupies octahedral sites in the structure and the ''B'' element, iron (Fe2+ and Fe3+), ...
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Pleonaste
Ceylonite (first cited 1793) and pleonaste (first cited 1801) or pleonast are dingy blue or grey to black varieties of spinel. Ceylonite, named for the island of Ceylon, is a ferroan spinel with Mg:Fe from 3:1 and 1:1, and little or no ferric iron. Pleonaste is named from the Greek for 'abundant,' for its many crystal forms, and is distinguished chemically by low Mg:Fe ratios of approximately 1:3. It is sometimes used as a gemstone.Precious stones and gems, their history and distinguishing characteristics By Edwin William Streeter, p.33-34 Composition The mineral ceylonite has the chemical composition of (Mg, Fe2+) Al2O4, putting it into a group of minerals known as the spinels, or the oxide spinels. The oxide spinels have a formula of the model B]2O4; where is commonly Fe2+, Mg2+, or Mn2+, and is Fe3+, Al3+, or Cr3+. Structure Ceylonite has the structural formula l2O4, where cation is Mg2+ or Fe2+. This formula creates a face centered cubic Bravais lattice, with a space ...
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Galaxite
Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula . Galaxite is the manganese (Mn) rich endmember of the aluminium (Al) series of the spinel group. Divalent iron (Fe) and magnesium (Mg) readily substitute for the manganese in the crystal structure. Trivalent iron may also substitute for the aluminium. Thus, reflecting most natural samples, the formula may be better represented as . Galaxite generally occurs as small granular aggregates with a red-brownish tone. It has a vitreous luster and leaves a brownish-red streak. It is rated 7.5 on the Mohs Scale. It was first described in 1932 for an occurrence at Bald Knob, Alleghany County, North Carolina near its namesakes, the town of Galax, Virginia, named after the plant galax or wandflower which grows in the area. It occurs in carbonate-rich metamorphosed manganese ore deposits. It occurs associated with alleghanyite, rhodonite, sonolite, ...
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Hercynite
Hercynite is a spinel mineral with the formula FeAl2O4. It occurs in high-grade metamorphosed iron rich argillaceous sediments as well as in mafic and ultramafic igneous rocks. Due to its hardness it also is found in placers. It was first described in 1847 and its name originates from the Latin name for the Harz, Silva Hercynia, where the species was first found. Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe2+) ions and aluminium ions (Al3+), however some ferric ions (Fe3+) may be located in the structure of hercynite. Melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ... of this mineral is inbetween . References Iron minerals Aluminium minerals Spinel group Cubic ...
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Gahnite
Gahnite, ZnAl2O4, is a rare mineral belonging to the spinel group. It forms octahedral crystals which may be green, blue, yellow, brown or grey. It often forms as an alteration product of sphalerite in altered massive sulphide deposits such as at Broken Hill, Australia. Other occurrences include Falun, Sweden where it is found in pegmatites and skarns; and, in the United States, Charlemont, Massachusetts; Spruce Pine, North Carolina; White Picacho district, Arizona; Topsham, Maine; and Franklin, New Jersey. It was first described in 1807 for an occurrence in the Falu mine, Falun, Dalarna, Sweden, and named after the Swedish chemist, Johan Gottlieb Gahn Johan Gottlieb Gahn (19 August 1745 – 8 December 1818) was a Swedish chemist and metallurgist who isolated manganese in 1774. Gahn studied in Uppsala 1762 – 1770 and became acquainted with chemists Torbern Bergman and Carl Wilhelm Scheele. 17 ... (1745–1818), the discoverer of the element manganese. It is sometimes ca ...
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Spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties Spinel crystallizes in the isometric system; common crystal forms are octahedra, usually twinned. It has no true cleavage, but shows an octahedral parting and a conchoidal fracture. Its hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender, blue, green, brown, black, or yellow. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the " Timur ruby" in the British Crown Jewels, and the "Côte de Bretagne", formerly from the French Crown jewels. The Samarian Spinel is the largest known spinel in the world, weighing . The transparent red spinels were called spinel-rubies ...
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Corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange. The name "corundum" is derived from the Tamil- Dravidian word ''kurundam'' (ruby-sapphire) (appearing in Sanskrit as ''kuruvinda''). Because of corundum's hardness (pure corundum is defined to have 9.0 on the Mohs scale), it can scratch almost all other minerals. It is commonly used as an abrasive on sandpaper and on large tools used in machining metals, plastics, and wood. Emery, a variety of corundum with no val ...
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Encyclopædia Britannica
The (Latin for "British Encyclopædia") is a general knowledge English-language encyclopaedia. It is published by Encyclopædia Britannica, Inc.; the company has existed since the 18th century, although it has changed ownership various times through the centuries. The encyclopaedia is maintained by about 100 full-time editors and more than 4,000 contributors. The 2010 version of the 15th edition, which spans 32 volumes and 32,640 pages, was the last printed edition. Since 2016, it has been published exclusively as an online encyclopaedia. Printed for 244 years, the ''Britannica'' was the longest running in-print encyclopaedia in the English language. It was first published between 1768 and 1771 in the Scottish capital of Edinburgh, as three volumes. The encyclopaedia grew in size: the second edition was 10 volumes, and by its fourth edition (1801–1810) it had expanded to 20 volumes. Its rising stature as a scholarly work helped recruit eminent ...
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Ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphires. Ruby is one of the traditional cardinal gems, alongside amethyst, sapphire, emerald, and diamond. The word ''ruby'' comes from ''ruber'', Latin for red. The color of a ruby is due to the element chromium. Some gemstones that are popularly or historically called rubies, such as the Black Prince's Ruby in the British Imperial State Crown, are actually spinels. These were once known as "Balas rubies". The quality of a ruby is determined by its color, cut, and clarity, which, along with carat weight, affect its value. The brightest and most valuable shade of red, called blood-red or pigeon blood, commands a large premium over other rubies of similar quality. After color follows clarity: similar to diamonds, a clear stone ...
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Spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties Spinel crystallizes in the isometric system; common crystal forms are octahedra, usually twinned. It has no true cleavage, but shows an octahedral parting and a conchoidal fracture. Its hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender, blue, green, brown, black, or yellow. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the " Timur ruby" in the British Crown Jewels, and the "Côte de Bretagne", formerly from the French Crown jewels. The Samarian Spinel is the largest known spinel in the world, weighing . The transparent red spinels were called spinel-rubies ...
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