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Silicon Monohydride
Silylidyne is a chemical substance occurring as a molecule found in stars and probably existing in interstellar space, or as a monolayer on the surface of solid silicon. The SiH molecule is a radical, and can be made experimentally by striking an electric arc to silicon on a low pressure hydrogen gas. Surface As a surface layer, silicon hydrides form when the silicon is cleaned with hydrofluoric acid. These hydrides decompose to SiH when heated to 750 K. Other ways to coat a silicon surface in hydrogen is via reaction with atomic hydrogen, or hot silane. A (111) crystal face will become covered in the pure monohydride, but other faces on a silicon crystal will also have the dihydride and trihydride groups. Group The silylidyne group, not to be confused with silylidyne, is a ≡SiH group that is bonded with a triple bond. The hydrogen can be substituted by other groups to make a more generic family of silylidynes. It is known as a ligand on molybdenum. Natural occurrence Silylid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monolayer
A monolayer is a single, closely packed layer of atoms, molecules, or cells. In some cases it is referred to as a self-assembled monolayer. Monolayers of layered crystals like graphene and molybdenum disulfide are generally called 2D materials. Chemistry A Langmuir monolayer or insoluble monolayer is a one-molecule thick layer of an insoluble organic material spread onto an aqueous subphase in a Langmuir-Blodgett trough. Traditional compounds used to prepare Langmuir monolayers are amphiphilic materials that possess a hydrophilic headgroup and a hydrophobic tail. Since the 1980s a large number of other materials have been employed to produce Langmuir monolayers, some of which are semi-amphiphilic, including polymeric, ceramic or metallic nanoparticles and macromolecules such as polymers. Langmuir monolayers are extensively studied for the fabrication of Langmuir-Blodgett film (LB films), which are formed by transferred monolayers on a solid substrate. A Gibbs monolayer or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, lead, and flerovium are below it. It is relatively unreactive. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its oxides form a family of anions known as silicates. Its melting and boiling points of 1414 °C and 3265 °C, respectively, are the second highest among all the metalloids and nonmetals, being surpassed only by boron. Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is widely distributed in space in cosmic dusts, planetoids, and planets as various forms of silicon dioxide ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radical (chemistry)
In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes. A notable example of a radical is the hydroxyl radical (HO·), a molecule that has one unpaired electron on the oxygen atom. Two other examples are triplet oxygen and triplet carbene (꞉) which have two unpaired electrons. Radicals may be generated in a number of ways, but typical methods involve redox reactions. Ionizing radiation, heat, electrical discharges, and electrolysis are known to produce radicals. Radicals are intermediates in many chemical reactions, more so than is apparent from the balanced equations. Radicals are important in combustion, atmospheric chemistry, polymerization, plasma chemistry, biochemistry, and many other chemical processes. A majority of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Arc
An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The electric current, current through a normally Electrical conductance, nonconductive medium such as air produces a plasma (physics), plasma; the plasma may produce visible light. An arc discharge is characterized by a lower voltage than a glow discharge and relies on thermionic emission of electrons from the electrodes supporting the arc. An archaic term is voltaic arc, as used in the phrase "voltaic arc lamp". Techniques for arc suppression can be used to reduce the duration or likelihood of arc formation. In the late 19th century, Arc lamp, electric arc lighting was in wide use for Street light#Arc lamps, public lighting. Some low-pressure electric arcs are used in many applications. For example, fluorescent lamp, fluorescent tubes, mercury, sodium, and metal-halide lamps are used for lighting; xenon arc lamps have been used for movie projectors. Electric a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370,000 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Hydrogen
A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe. In everyday life on Earth, isolated hydrogen atoms (called "atomic hydrogen") are extremely rare. Instead, a hydrogen atom tends to combine with other atoms in compounds, or with another hydrogen atom to form ordinary (diatomic) hydrogen gas, H2. "Atomic hydrogen" and "hydrogen atom" in ordinary English use have overlapping, yet distinct, meanings. For example, a water molecule contains two hydrogen atoms, but does not contain atomic hydrogen (which would refer to isolated hydrogen atoms). Atomic spectroscopy shows that there is a discrete infinite set of states in which a hydrogen (or any) atom can exist, contrary to the predictions of classical physics. Attempts to develop a theoreti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silane
Silane is an inorganic compound with chemical formula, . It is a colourless, pyrophoric, toxic gas with a sharp, repulsive smell, somewhat similar to that of acetic acid. Silane is of practical interest as a precursor to elemental silicon. Silane with alkyl groups are effective water repellents for mineral surfaces such as concrete and masonry. Silanes with both organic and inorganic attachments are used as coupling agents. Production Commercial-scale routes Silane can be produced by several routes. Typically, it arises from the reaction of hydrogen chloride with magnesium silicide: : Mg2Si + 4 HCl -> 2 MgCl2 + SiH4 It is also prepared from metallurgical-grade silicon in a two-step process. First, silicon is treated with hydrogen chloride at about 300 °C to produce trichlorosilane, HSiCl3, along with hydrogen gas, according to the chemical equation : Si + 3 HCl -> HSiCl3 + H2 The trichlorosilane is then converted to a mixture of silane and silicon tetrachloride: : 4 HS ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silylidene
Silylene is a chemical compound with the formula SiH2. It is the silicon analog of methylene, the simplest carbene. Silylene is a stable molecule as a gas but rapidly reacts in a bimolecular manner when condensed. Unlike carbenes, which can exist in the singlet or triplet state, silylene (and all of its derivatives) are singlets. Silylenes are formal derivatives of silylene with its hydrogens replaced by other substituents. Most examples feature amido (NR2) or alkyl/aryl groups. Silylenes have been proposed as reactive intermediates. They are carbene analogs. Synthesis and properties Silylenes are generally synthesized by thermolysis or photolysis of polysilanes, by silicon atom reactions (insertion, addition or abstraction), by pyrolysis of silanes, or by reduction of 1,1-dihalosilane. It has long been assumed that the conversion of metallic Si to tetravalent silicon compounds proceeds via silylene intermediates: :Si + Cl2 → SiCl2 :SiCl2 + Cl2 → SiCl4 Similar considera ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silyl
Silylation is the introduction of one or more (usually) substituted silyl groups (R3Si) to a molecule. The process is the basis of organosilicon chemistry. Of organic compounds Alcohols, carboxylic acids, amines, thiols, and phosphates can be silylated. The process involves the replacement of a proton with a trialkylsilyl group, typically trimethylsilyl (-SiMe3). Generally the substrate is deprotonated with a suitable strong base followed by treatment with a silyl chloride (e.g. trimethylsilyl chloride). Often strong bases such butyl lithium or a Grignard reagent are used, as illustrated by the synthesis of a trimethylsilyl ethers as protecting groups from an alcohol: :ROH + BuLi → ROLi + BuH :ROLi + Me3SiCl → ROSiMe3 + LiCl Bis(trimethylsilyl)acetamide ("BSA", Me3SiNC(OSiMe3)Me is an efficient silylation agent used for the derivatisation of compounds. The reaction of BSA with alcohols gives the corresponding trimethylsilyl ether, together with N-(trimethylsilyl)acetamide as a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sun Spot
Sunspots are phenomena on the Sun's photosphere that appear as temporary spots that are darker than the surrounding areas. They are regions of reduced surface temperature caused by concentrations of magnetic flux that inhibit convection. Sunspots appear within active regions, usually in pairs of opposite magnetic polarity. Their number varies according to the approximately 11-year solar cycle. Individual sunspots or groups of sunspots may last anywhere from a few days to a few months, but eventually decay. Sunspots expand and contract as they move across the surface of the Sun, with diameters ranging from to . Larger sunspots can be visible from Earth without the aid of a telescope. They may travel at relative speeds, or proper motions, of a few hundred meters per second when they first emerge. Indicating intense magnetic activity, sunspots accompany other active region phenomena such as coronal loops, prominences, and reconnection events. Most solar flares and coronal mas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mira Variable Star
Mira variables (named for the prototype star Mira) are a class of pulsating stars characterized by very red colours, pulsation periods longer than 100 days, and amplitudes greater than one magnitude in infrared and 2.5 magnitude at visual wavelengths. They are red giants in the very late stages of stellar evolution, on the asymptotic giant branch (AGB), that will expel their outer envelopes as planetary nebulae and become white dwarfs within a few million years. Mira variables are stars massive enough that they have undergone helium fusion in their cores but are less than two solar masses, stars that have already lost about half their initial mass. However, they can be thousands of times more luminous than the Sun due to their very large distended envelopes. They are pulsating due to the entire star expanding and contracting. This produces a change in temperature along with radius, both of which factors cause the variation in luminosity. The pulsation depends on the mass and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
M-type Star
In astronomy, stellar classification is the classification of stars based on their spectral characteristics. Electromagnetic radiation from the star is analyzed by splitting it with a prism or diffraction grating into a spectrum exhibiting the rainbow of colors interspersed with spectral lines. Each line indicates a particular chemical element or molecule, with the line strength indicating the abundance of that element. The strengths of the different spectral lines vary mainly due to the temperature of the photosphere, although in some cases there are true abundance differences. The ''spectral class'' of a star is a short code primarily summarizing the ionization state, giving an objective measure of the photosphere's temperature. Most stars are currently classified under the Morgan–Keenan (MK) system using the letters ''O'', ''B'', ''A'', ''F'', ''G'', ''K'', and ''M'', a sequence from the hottest (''O'' type) to the coolest (''M'' type). Each letter class is then subdivided ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
acetamide.svg "Click for more on -> Silyl")
_2007-04-30_T001456.gif "Click for more on -> Sun Spot")
