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Synthetic Colorant
A colorant is any substance that changes the spectral transmittance or reflectance of a material. Synthetic colorants are those created in a laboratory or industrial setting. The production and improvement of colorants was a driver of the early synthetic chemical industry, in fact many of today's largest chemical producers started as dye-works in the late 19th or early 20th centuries, including Bayer AG(1863). Synthetics are extremely attractive for industrial and aesthetic purposes as they have they often achieve higher intensity and color fastness than comparable natural pigments and dyes used since ancient times. Market viable large scale production of dyes occurred nearly simultaneously in the early major producing countries Britain (1857), France (1858), Germany (1858), and Switzerland (1859), and expansion of associated chemical industries followed. The mid-nineteenth century through WWII saw an incredible expansion of the variety and scale of manufacture of synthetic colorants. ...
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The Aniline Colours Of The Badische Anilin- & Soda-Fabrik, Ludwigshafen On Rhine And Their Application On Wool, Cotton, Silk And Other Textile Fibres, Page 295
''The'' () is a grammatical Article (grammar), article in English language, English, denoting persons or things already mentioned, under discussion, implied or otherwise presumed familiar to listeners, readers, or speakers. It is the definite article in English. ''The'' is the Most common words in English, most frequently used word in the English language; studies and analyses of texts have found it to account for seven percent of all printed English-language words. It is derived from gendered articles in Old English which combined in Middle English and now has a single form used with pronouns of any gender. The word can be used with both singular and plural nouns, and with a noun that starts with any letter. This is different from many other languages, which have different forms of the definite article for different genders or numbers. Pronunciation In most dialects, "the" is pronounced as (with the voiced dental fricative followed by a schwa) when followed by a consonant s ...
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Potassium Carbonate
Potassium carbonate is the inorganic compound with the formula K2 CO3. It is a white salt, which is soluble in water. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and glass. History Potassium carbonate is the primary component of potash and the more refined pearl ash or salts of tartar. Historically, pearl ash was created by baking potash in a kiln to remove impurities. The fine, white powder remaining was the pearl ash. The first patent issued by the US Patent Office was awarded to Samuel Hopkins in 1790 for an improved method of making potash and pearl ash. In late 18th-century North America, before the development of baking powder, pearl ash was used as a leavening agent for quick breads. Production Potassium carbonate is prepared commercially by the reaction potassium hydroxide with carbon dioxide: : 2 KOH + CO2 → K2CO3 + H2O From the solution crystallizes the sesquihydrate K2CO3·H2O ("potas ...
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Kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () octahedra. Rocks that are rich in kaolinite are known as kaolin () or china clay. Kaolin is occasionally referred to by the antiquated term lithomarge, from the Ancient Greek ''litho-'' and Latin ''marga'', meaning 'stone of marl'. Presently the name lithomarge can refer to a compacted, massive form of kaolin. The name ''kaolin'' is derived from Gaoling (), a Chinese village near Jingdezhen in southeastern China's Jiangxi Province. The name entered English in 1727 from the French version of the word: , following François Xavier d'Entrecolles's reports on the making of Jingdezhen porcelain. Kaolinite has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g). It is a soft, ear ...
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Ultramarine
Ultramarine is a deep blue color pigment which was originally made by grinding lapis lazuli into a powder. The name comes from the Latin ''ultramarinus'', literally 'beyond the sea', because the pigment was imported into Europe from mines in Afghanistan by Italian traders during the 14th and 15th centuries. Ultramarine was the finest and most expensive blue used by Renaissance painters. It was often used for the robes of the Virgin Mary and symbolized holiness and humility. It remained an extremely expensive pigment until a synthetic ultramarine was invented in 1826. Structure The pigment consists primarily of a zeolite-based mineral containing small amounts of polysulfides. It occurs in nature as a proximate component of lapis lazuli containing a blue cubic mineral called lazurite. In the Colour Index International, the pigment of ultramarine is identified as P. Blue 29 77007. The major component of lazurite is a complex sulfur-containing sodium-silicate (Na8–10Al6Si6 ...
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Lapis Lazuli
Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color. As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines,David Bomford and Ashok Roy, ''A Closer Look- Colour'' (2009), National Gallery Company, London, () in Shortugai, and in other mines in Badakhshan province in northeast Afghanistan. Lapis lazuli artifacts, dated to 7570 BC, have been found at Bhirrana, which is the oldest site of Indus Valley civilisation. Lapis was highly valued by the Indus Valley Civilisation (7570–1900 BC). Lapis beads have been found at Neolithic burials in Mehrgarh, the Caucasus, and as far away as Mauritania. It was used in the funeral mask of Tutankhamun (1341–1323 BC). By the end of the Middle Ages, lapis lazuli began to be exported to Europe, where it was ground into powder and made into ultramarine, the finest and most expensive of all blue pigments. U ...
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Basic Copper Carbonate
Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It is an ionic compound (a salt) consisting of the ions copper(II) , carbonate , and hydroxide . The name most commonly refers to the compound with formula ()2. It is a green crystalline solid that occurs in nature as the mineral malachite. It has been used since antiquity as a pigment, and it is still used as such in artist paints, sometimes called verditer, green bice, or mountain green. Sometimes the name is used for ()2()2, a blue crystalline solid also known as the mineral azurite. It too has been used as pigment, sometimes under the name mountain blue or blue verditer. Both malachite and azurite can be found in the verdigris patina that is found on weathered brass, bronze, and copper. The composition of the patina can vary, in a maritime environment depending on the environment a basic chloride may be present, in an urban environment basic sulfates may be present. This co ...
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Malachite
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur. Etymology and history The stone's name derives (via la, molochītis, frm, melochite, and Middle English ''melochites'') from Greek Μολοχίτης λίθος ''molochites lithos'', "mallow-green stone", from μολόχη ''molochē'', variant of μαλάχη ''malāchē'', "mallow". The mineral was given this name due to its resemblance to the leaves of the mallow plant. Malachite was mined from deposits near the Isthmus of Suez and the Sinai as early as 4000 BCE. It ...
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Arsenic Trisulfide
Arsenic trisulfide is the inorganic compound with the formula . It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI, intrinsic p-type semiconductor and exhibits photo-induced phase-change properties. Structure occurs both in crystalline and amorphous forms. Both forms feature polymeric structures consisting of trigonal pyramidal As(III) centres linked by sulfide centres. The sulfide centres are two-fold coordinated to two arsenic atoms. In the crystalline form, the compound adopts a ruffled sheet structure. The bonding between the sheets consists of van der Waals forces. The crystalline form is usually found in geological samples. Amorphous does not possess a layered structure but is more highly cross-linked. Like other glasses, there is no medium or long-range order, but the first co-or ...
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Orpiment
Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of another arsenic sulfide mineral, realgar. Orpiment takes its name from the Latin ''auripigmentum'' (''aurum'', "gold" + ''pigmentum'', " pigment") because of its deep-yellow color. Historical uses Orpiment was traded in the Roman Empire and was used as a medicine in China, even though it is very toxic. It has been used as fly poison and to tip arrows with poison. Because of its striking color, it was of interest to alchemists, both in China and the West, searching for a way to make gold. It also has been found in the wall decorations of Tutankhamun's tomb and ancient Egyptian scrolls, and on the walls of the Taj Mahal. For centuries, orpiment was ground down and used as a pigment in painting and for sealing wax, and was even used in ancie ...
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Mercury Sulfide
Mercury sulfide, or mercury(II) sulfide is a chemical compound composed of the chemical elements mercury and sulfur. It is represented by the chemical formula HgS. It is virtually insoluble in water. Crystal structure HgS is dimorphic with two crystal forms: * red cinnabar (α-HgS, trigonal, hP6, P3221) is the form in which mercury is most commonly found in nature. Cinnabar has rhombohedral crystal system. Crystals of red are optically active. This is caused by the Hg-S helices in the structure. * black metacinnabar (β-HgS) is less common in nature and adopts the zinc blende (''T''2d-''F'3m'') crystal structure. Preparation and chemistry β-HgS precipitates as a black solid when Hg(II) salts are treated with H2S. The reaction is conveniently conducted with an acetic acid solution of mercuric acetate. With gentle heating of the slurry, the black polymorph converts to the red form. β-HgS is unreactive to all but concentrated acids. Mercury is produced from the cinnab ...
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Vermilion
Vermilion (sometimes vermillion) is a color, color family, and pigment most often made, since antiquity until the 19th century, from the powdered mineral cinnabar (a form of mercury sulfide, which is toxic) and its corresponding color. It is very often synonymous with red orange, which often takes a modern form just 11% brighter (at full brightness). Etymology and orthography The word vermilion came from the Old French word ''vermeillon'', which was derived from ''vermeil'', from the Latin ''vermiculus'', the diminutive of the Latin word ''vermis'', or worm. The name originated because it had a similar color to the natural red dye made from an insect, '' Kermes vermilio'', which was widely used in Europe. The first recorded use of "vermilion" as a color name in English was in 1289. The term cinnabar was used interchangeably with vermilion until the 17th century, when vermilion became the more common name. Now the term "cinnabar" is used in mineralogy and crystallography f ...
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Manganese Oxide
Manganese oxide is any of a variety of manganese oxides and hydroxides.Wells A.F. (1984) ''Structural inorganic chemistry'' 5th edition Oxford Science Publications, . These include * Manganese(II) oxide, MnO * Manganese(II,III) oxide, Mn3O4 * Manganese(III) oxide, Mn2O3 * Manganese dioxide, MnO2 * Manganese(VI) oxide, MnO3 * Manganese(VII) oxide, Mn2O7 Other manganese oxides include Mn5O8, Mn7O12 and Mn7O13. Minerals It may refer more specifically to the following manganese minerals: * Birnessite * Buserite * Hausmannite * Manganite * Manganosite * Psilomelane * Pyrolusite Manganese may also form mixed oxides with other metals : * Bixbyite, a manganese iron oxide mineral * Jacobsite, a manganese iron oxide mineral * Columbite * Tantalite, a mineral group close to columbite * Coltan, a mixture of columbite and tantalite * Galaxite Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula ...
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