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Stoichiometric Amount
Stoichiometry () is the relationship between the weights of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the balanced equation is: : Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. Stoichiometry ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Combustion Reaction Of Methane
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescence, incandescent light in t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jeremias Benjamin Richter
Jeremias Benjamin Richter (; 10 March 1762 – 4 May 1807) was a German chemist. He was born at Hirschberg in Silesia, became a mining official at Breslau in 1794, and in 1800 was appointed assessor to the department of mines and chemist to the royal porcelain factory at Berlin, where he died. He is known for introducing the term ''stoichiometry''. Developer of titration He made some of the earliest known determinations of the quantities by weight in which acids saturate bases and bases acids. He realised that those amounts of different bases which can saturate the same quantity of a particular acid are equivalent to each other (see ''Titration''). He was thus led to conclude that chemistry is a branch of applied mathematics and to endeavour to trace a law according to which the quantities of different bases required to saturate a given acid formed an arithmetical progression, and the quantities of acids saturating a given base a geometric progression. Law of definite propor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Avogadro Constant
The Avogadro constant, commonly denoted or , is the proportionality factor that relates the number of constituent particles (usually molecules, atoms or ions) in a sample with the amount of substance in that sample. It is an SI defining constant with an exact value of . It is named after the Italian scientist Amedeo Avogadro by Stanislao Cannizzaro, who explained this number four years after Avogadro's death while at the Karlsruhe Congress in 1860. The numeric value of the Avogadro constant expressed in reciprocal moles, a dimensionless number, is called the Avogadro number. In older literature, the Avogadro number is denoted or , which is the number of particles that are contained in one mole, exactly . The Avogadro number is the approximate number of nucleons (protons or neutrons) in one gram of ordinary matter. The value of the Avogadro constant was chosen so that the mass of one mole of a chemical compound, in grams, is approximately the number of nucleons in one cons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dalton (unit)
The dalton or unified atomic mass unit (symbols: Da or u) is a non-SI unit of mass widely used in physics and chemistry. It is defined as of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at rest. The atomic mass constant, denoted ''m''u, is defined identically, giving . This unit is commonly used in physics and chemistry to express the mass of atomic-scale objects, such as atoms, molecules, and elementary particles, both for discrete instances and multiple types of ensemble averages. For example, an atom of helium-4 has a mass of . This is an intrinsic property of the isotope and all helium-4 atoms have the same mass. Acetylsalicylic acid (aspirin), , has an average mass of approximately . However, there are no acetylsalicylic acid molecules with this mass. The two most common masses of individual acetylsalicylic acid molecules are , having the most common isotopes, and , in which one carbon is carbon-13. The molecular mass ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon-12
Carbon-12 (12C) is the most abundant of the two stable isotopes of carbon (carbon-13 being the other), amounting to 98.93% of element carbon on Earth; its abundance is due to the triple-alpha process by which it is created in stars. Carbon-12 is of particular importance in its use as the standard from which atomic masses of all nuclides are measured, thus, its atomic mass is exactly 12 daltons by definition. Carbon-12 is composed of 6 protons, 6 neutrons, and 6 electrons. History Before 1959, both the IUPAP and IUPAC used oxygen to define the mole; the chemists defining the mole as the number of atoms of oxygen which had mass 16 g, the physicists using a similar definition but with the oxygen-16 isotope only. The two organizations agreed in 1959/60 to define the mole as follows. ''Mole is the amount of substance of a system which contains as many elementary entities as there are atoms in 12 gram of carbon 12; its symbol is "mol".'' This was adopted by the CIPM (Inte ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Mass
The atomic mass (''m''a or ''m'') is the mass of an atom. Although the SI unit of mass is the kilogram (symbol: kg), atomic mass is often expressed in the non-SI unit dalton (symbol: Da) – equivalently, unified atomic mass unit (u). 1 Da is defined as of the mass of a free carbon-12 atom at rest in its ground state. The protons and neutrons of the nucleus account for nearly all of the total mass of atoms, with the electrons and nuclear binding energy making minor contributions. Thus, the numeric value of the atomic mass when expressed in daltons has nearly the same value as the mass number. Conversion between mass in kilograms and mass in daltons can be done using the atomic mass constant m_= = 1\ \rm . The formula used for conversion is: :1\ = m_ = 1.660\ 539\ 066\ 60(50)\times 10^\ \mathrm , where M_ is the molar mass constant, N_ is the Avogadro constant, and M(^\mathrm) is the experimentally determined molar mass of carbon-12. The relative isotopic mass (see ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Elementary Reaction
An elementary reaction is a chemical reaction in which one or more chemical species react directly to form products in a single reaction step and with a single transition state. In practice, a reaction is assumed to be elementary if no reaction intermediates have been detected or need to be postulated to describe the reaction on a molecular scale. An apparently elementary reaction may be in fact a stepwise reaction, i.e. a complicated sequence of chemical reactions, with reaction intermediates of variable lifetimes. In a unimolecular elementary reaction, a molecule dissociates or isomerises to form the products(s) :\mbox \rightarrow \mbox At constant temperature, the rate of such a reaction is proportional to the concentration of the species :\frac=-kmbox In a bimolecular elementary reaction, two atoms, molecules, ions or radicals, and , react together to form the product(s) :\mbox \rightarrow \mbox The rate of such a reaction, at constant temperature, is proportional to the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Transmutation
Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed. A transmutation can be achieved either by nuclear reactions (in which an outside particle reacts with a nucleus) or by radioactive decay, where no outside cause is needed. Natural transmutation by stellar nucleosynthesis in the past created most of the heavier chemical elements in the known existing universe, and continues to take place to this day, creating the vast majority of the most common elements in the universe, including helium, oxygen and carbon. Most stars carry out transmutation through fusion reactions involving hydrogen and helium, while much larger stars are also capable of fusing heavier elements up to iron late in their evolution. Elements heavier than iron, such as gold or lead, are created through elemental transmutations that can ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Law Of Reciprocal Proportions
The law of reciprocal proportions also called law of equivalent proportions or law of permanent ratios is one of the basic laws of stoichiometry. It relates the proportions in which elements combine across a number of different elements. It was first formulated by Jeremias Richter in 1791. A simple statement of the law is:- :If element A combines with element B and also with C, then, if B and C combine together, the proportion by weight in which they do so will be simply related to the weights of B and C which separately combine with a constant weight of A. :As an example, 1 gram of sodium (Na = A) is observed to combine with either 1.54 grams of chlorine (Cl = B) or 5.52 grams of iodine (I = C). (These ratios correspond to the modern formulas NaCl and NaI). The ratio of these two weights is 5.52/1.54 = 3.58. It is also observed that 1 gram of chlorine reacts with 1.19 g of iodine. This ratio of 1.19 obeys the law because it is a simple fraction (1/3) of 3.58. (This is because it c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Law Of Multiple Proportions
In chemistry, the law of multiple proportions states that if two elements form more than one compound, then the ratios of the masses of the second element which combine with a fixed mass of the first element will always be ratios of small whole numbers. This law is also known as: ''Dalton's Law'', named after John Dalton, the chemist who first expressed it. For example, Dalton knew that the element carbon forms two oxides by combining with oxygen in different proportions. A fixed mass of carbon, say 100 grams, may react with 133 grams of oxygen to produce one oxide, or with 266 grams of oxygen to produce the other. The ratio of the masses of oxygen that can react with 100 grams of carbon is 266:133 = 2:1, a ratio of small whole numbers. Dalton interpreted this result in his atomic theory by proposing (correctly in this case) that the two oxides have one and two oxygen atoms respectively for each carbon atom. In modern notation the first is CO (carbon monoxide) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Law Of Constant Composition
In chemistry, the law of definite proportions, sometimes called Proust's law, or law of constant composition states that a given chemical compound always contains its component elements in fixed ratio (by mass) and does not depend on its source and method of preparation. For example, oxygen makes up about 8/9 of the mass of any sample of pure water, while hydrogen makes up the remaining 1/9 of the mass: the mass of two elements in a compound are always in the same ratio. Along with the law of multiple proportions, the law of definite proportions forms the basis of stoichiometry. History The law of constant proportion was given by Joseph Proust in 1797. This observation was first made by the English theologian and chemist Joseph Priestley, and Antoine Lavoisier, a French nobleman and chemist centered on the process of combustion. The law of definite proportions might seem obvious to the modern chemist, inherent in the very definition of a chemical compound. At the end of the 18 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Law Of Definite Proportions
In chemistry, the law of definite proportions, sometimes called Proust's law, or law of constant composition states that a given chemical compound always contains its component elements in fixed ratio (by mass) and does not depend on its source and method of preparation. For example, oxygen makes up about 8/9 of the mass of any sample of pure water, while hydrogen makes up the remaining 1/9 of the mass: the mass of two elements in a compound are always in the same ratio. Along with the law of multiple proportions, the law of definite proportions forms the basis of stoichiometry. History The law of constant proportion was given by Joseph Proust in 1797. This observation was first made by the English theologian and chemist Joseph Priestley, and Antoine Lavoisier, a French nobleman and chemist centered on the process of combustion. The law of definite proportions might seem obvious to the modern chemist, inherent in the very definition of a chemical compound. At the end of the 18 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
