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Statistical Associating Fluid Theory
Statistical associating fluid theory (SAFT) is a chemical theory, based on perturbation theory, that uses statistical thermodynamics to explain how complex fluids and fluid mixtures form associations through hydrogen bonds. Widely used in industry and academia, it has become a standard approach for describing complex mixtures. Since it was first proposed in 1990, SAFT has been used in a large number of molecular-based equation of state models for describing the Helmholtz energy contribution due to association. Overview SAFT is a Helmholtz energy term that can be used in equations of state that describe the thermodynamic and phase equilibrium properties of pure fluids and fluid mixtures. SAFT was developed using statistical mechanics. SAFT models the Helmholtz free energy contribution due to association, i.e. hydrogen bonding. SAFT can be used in combination with other Helmholtz free energy terms. Other Helmholtz energy contributions consider for example Lennard-Jones interactio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a Chemical reaction, reaction with other Chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolytes
An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also function as electrolytes. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equations Of State
In physics, chemistry, and thermodynamics, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. Most modern equations of state are formulated in the Helmholtz free energy. Equations of state are useful in describing the properties of pure substances and mixtures in liquids, gases, and solid states as well as the state of matter in the interior of stars. Overview At present, there is no single equation of state that accurately predicts the properties of all substances under all conditions. An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures. This equation becomes increasingly inaccurate at higher pressures and lower temperatures, and fails to pred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mechanical Engineering
Mechanical engineering is the study of physical machines that may involve force and movement. It is an engineering branch that combines engineering physics and mathematics principles with materials science, to design, analyze, manufacture, and maintain mechanical systems. It is one of the oldest and broadest of the engineering branches. Mechanical engineering requires an understanding of core areas including mechanics, dynamics, thermodynamics, materials science, structural analysis, and electricity. In addition to these core principles, mechanical engineers use tools such as computer-aided design (CAD), computer-aided manufacturing (CAM), and product lifecycle management to design and analyze manufacturing plants, industrial equipment and machinery, heating and cooling systems, transport systems, aircraft, watercraft, robotics, medical devices, weapons, and others. Mechanical engineering emerged as a field during the Industrial Revolution in Europe in the 18th century; ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Engineering Thermodynamics
Engineering is the use of scientific principles to design and build machines, structures, and other items, including bridges, tunnels, roads, vehicles, and buildings. The discipline of engineering encompasses a broad range of more specialized fields of engineering, each with a more specific emphasis on particular areas of applied mathematics, applied science, and types of application. See glossary of engineering. The term ''engineering'' is derived from the Latin ''ingenium'', meaning "cleverness" and ''ingeniare'', meaning "to contrive, devise". Definition The American Engineers' Council for Professional Development (ECPD, the predecessor of ABET) has defined "engineering" as: The creative application of scientific principles to design or develop structures, machines, apparatus, or manufacturing processes, or works utilizing them singly or in combination; or to construct or operate the same with full cognizance of their design; or to forecast their behavior under specif ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equations Of Physics
In mathematics, an equation is a formula that expresses the equality of two expressions, by connecting them with the equals sign . The word ''equation'' and its cognates in other languages may have subtly different meanings; for example, in French an ''équation'' is defined as containing one or more variables, while in English, any well-formed formula consisting of two expressions related with an equals sign is an equation. ''Solving'' an equation containing variables consists of determining which values of the variables make the equality true. The variables for which the equation has to be solved are also called unknowns, and the values of the unknowns that satisfy the equality are called solutions of the equation. There are two kinds of equations: identities and conditional equations. An identity is true for all values of the variables. A conditional equation is only true for particular values of the variables. An equation is written as two expressions, connected by an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lattice Field Theory
In physics, lattice field theory is the study of lattice models of quantum field theory, that is, of field theory on a space or spacetime that has been discretised onto a lattice. Details Although most lattice field theories are not exactly solvable, they are of tremendous appeal because they can be studied by simulation on a computer, often using Markov chain Monte Carlo methods. One hopes that, by performing simulations on larger and larger lattices, while making the lattice spacing smaller and smaller, one will be able to recover the behavior of the continuum theory as the continuum limit is approached. Just as in all lattice models, numerical simulation gives access to field configurations that are not accessible to perturbation theory, such as solitons. Likewise, non-trivial vacuum states can be discovered and probed. The method is particularly appealing for the quantization of a gauge theory. Most quantization methods keep Poincaré invariance manifest but sacrifice mani ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubic Equations Of State
Cubic equations of state are a specific class of thermodynamic models for modeling the pressure of a gas as a function of temperature and density and which can be rewritten as a cubic function of the molar volume. Equations of state are generally applied in the fields of physical chemistry and chemical engineering, particularly in the modeling of vapor–liquid equilibrium and chemical engineering process design. Van der Waals equation of state The van der Waals equation of state may be written as : \left(p + \frac\right)\left(V_\text - b\right) = RT where T is the absolute temperature, p is the pressure, V_\text is the molar volume and R is the universal gas constant. Note that V_\text = V / n, where V is the volume, and n=N/N_\text, where n is the number of moles, N is the number of particles, and N_\text is the Avogadro constant. These definitions apply to all equations of state below as well. The substance-specific constants a and b can be calculated from the critical pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
PC-SAFT
PC-SAFT (perturbed chain SAFT) is an equation of state that is based on statistical associating fluid theory (SAFT). Like other SAFT equations of state, it makes use of chain and association terms developed by Chapman, et al from perturbation theory.Chapman, Walter G., et al. "SAFT: Equation-of-state solution model for associating fluids." ''Fluid Phase Equilibria'' 52 (1989): 31-38. However, unlike earlier SAFT equations of state that used unbonded spherical particles as a reference fluid, it uses spherical particles in the context of hard chains as reference fluid for the dispersion term.Gross J, Sadowski G. Perturbed-chain SAFT: An equation of state based on a perturbation theory for chain molecules. Industrial & engineering chemistry research. 2001 Feb 21;40(4):1244-60. PC-SAFT was developed by Joachim Gross and Gabriele Sadowski, and was first presented in their 2001 article. Further research extended PC-SAFT for use with associating and polar molecules, and it has also been ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Industrial And Engineering Chemistry Research
''Industrial & Engineering Chemistry Research'' is a peer-reviewed scientific journal published by the American Chemical Society covering all aspects of chemical engineering. The editor-in-chief is Phillip E. Savage (Pennsylvania State University). History The journal was established in 1909 as the ''Journal of Industrial & Engineering Chemistry''. It was renamed in 1930 as ''Industrial & Engineering Chemistry'' before obtaining its current title in 1970. From 1911 to 1916 it was edited by Milton C. Whitaker. From 1921 to 1942 it was edited by Dr. Harrison E. Howe. The journal ''I&EC Product Research and Development'' was established in 1962. It was renamed ''Product R&D'' in 1969 and renamed again in 1978 as ''Industrial & Engineering Chemistry Product Research and Development''. In 1986, it and the journals ''Industrial & Engineering Chemistry Fundamentals'' and ''Industrial & Engineering Chemistry Process Design and Development'', both also established in 1962, were combine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
George Jackson (chemist)
George Jackson, , , (born 31 July 1962) is a British professor of chemical physics in the Department of Chemical Engineering at Imperial College London. He is noted for developing molecular models that describe the thermodynamic properties of complex fluids; as one of the developers of statistical associating fluid theory (SAFT); and for his work in molecular systems engineering. His theoretical work has found a wide range of practical applications in industries such as gas extraction and emerging fields like carbon capture and storage. Early life and career Jackson was born in Spain and grew up in Switzerland. He took a B.Sc. in chemistry at Chelsea College (1980-1983), followed by a D.Phil. in Physical Chemistry at Exeter College, University of Oxford (1983-1986). After postdoctoral work at Cornell University with Keith E. Gubbins (1986-1989), he became a lecturer and reader in physical chemistry at the University of Sheffield (1989-1998), and has been professor of Che ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michael Wertheim
Michael may refer to: People * Michael (given name), a given name * Michael (surname), including a list of people with the surname Michael Given name "Michael" * Michael (archangel), ''first'' of God's archangels in the Jewish, Christian and Islamic religions * Michael (bishop elect), English 13th-century Bishop of Hereford elect * Michael (Khoroshy) (1885–1977), cleric of the Ukrainian Orthodox Church of Canada * Michael Donnellan (1915–1985), Irish-born London fashion designer, often referred to simply as "Michael" * Michael (footballer, born 1982), Brazilian footballer * Michael (footballer, born 1983), Brazilian footballer * Michael (footballer, born 1993), Brazilian footballer * Michael (footballer, born February 1996), Brazilian footballer * Michael (footballer, born March 1996), Brazilian footballer * Michael (footballer, born 1999), Brazilian footballer Rulers =Byzantine emperors= *Michael I Rangabe (d. 844), married the daughter of Emperor Nikephoros I *Mich ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
