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Stannate
In chemistry the term stannate refers to compounds of tin (Sn). Stannic acid (Sn(OH)4), the formal precursor to stannates, does not exist and is actually a hydrate of SnO2. The term is also used in naming conventions as a suffix; for example the hexachlorostannate ion is . In materials science, two kinds of tin oxyanions are distinguished: *''orthostannates'' contain discrete units (e.g. K4SnO4) or have a spinel structure (e.g. Mg2SnO4) *''metastannates'' with a stoichiometry MIISnO3, MSnO3 which may contain polymeric anions or may be sometimes better described as mixed oxides These materials are semiconductors."Preparation, characterization and structure of metal stannates: a new family of photocatalysts for organic pollutants degradation." ''Handbook of Photocatalysts'' (2010), pp. 493–510. Nova Science Publishers, Inc., Hauppauge, NY Examples * Barium metastannate (BaSnO3) * Cobalt stannate (Co2SnO4), primary constituent of the pigment cerulean blue Cerulean (), ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stannic Acid
Tin(IV) oxide, also known as stannic oxide, is the inorganic compound with the formula SnO2. The mineral form of SnO2 is called cassiterite, and this is the main ore of tin. With many other names, this oxide of tin is an important material in tin chemistry. It is a colourless, diamagnetic, amphoteric solid. Structure Tin(IV) oxide crystallises with the rutile structure. As such the tin atoms are six coordinate and the oxygen atoms three coordinate. SnO2 is usually regarded as an oxygen-deficient n-type semiconductor. Hydrous forms of SnO2 have been described as stannic acid. Such materials appear to be hydrated particles of SnO2 where the composition reflects the particle size. Preparation Tin(IV) oxide occurs naturally. Synthetic tin(IV) oxide is produced by burning tin metal in air. Annual production is in the range of 10 kilotons. SnO2 is reduced industrially to the metal with carbon in a reverberatory furnace at 1200–1300 °C. Amphoterism Although SnO2 is insoluble ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tin Dioxide
Tin(IV) oxide, also known as stannic oxide, is the inorganic compound with the formula SnO2. The mineral form of SnO2 is called cassiterite, and this is the main ore of tin. With many other names, this oxide of tin is an important material in tin chemistry. It is a colourless, diamagnetic, amphoteric solid. Structure Tin(IV) oxide crystallises with the rutile structure. As such the tin atoms are six coordinate and the oxygen atoms three coordinate. SnO2 is usually regarded as an oxygen-deficient n-type semiconductor. Hydrous forms of SnO2 have been described as stannic acid. Such materials appear to be hydrated particles of SnO2 where the composition reflects the particle size. Preparation Tin(IV) oxide occurs naturally. Synthetic tin(IV) oxide is produced by burning tin metal in air. Annual production is in the range of 10 kilotons. SnO2 is reduced industrially to the metal with carbon in a reverberatory furnace at 1200–1300 °C. Amphoterism Although SnO2 is insolub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerulean
Cerulean (), also spelled caerulean, is a shade of blue ranging between azure and a darker sky blue. The first recorded use of ''cerulean'' as a colour name in English was in 1590. The word is derived from the Latin word '' caeruleus'', "dark blue, blue, or blue-green", which in turn probably derives from ''caerulum'', diminutive of ''caelum'', "heaven, sky". "Cerulean blue" is the name of a pigment. The pigment was discovered in the late eighteenth century and designated as cerulean blue in the nineteenth century. Cerulean blue pigment The primary chemical constituent of the pigment is cobalt(II) stannate (). The precise hue of the pigment is dependent on a variable silicate component. The pigment Cerulean blue was discovered in 1789 by the Swiss chemist Albrecht Höpfner. Subsequently, there was a limited German production under the name of ''Cölinblau''. It was in 1860 first marketed in the United Kingdom by colourman George Rowney, as "coeruleum". Other nineteenth ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stannite (ion)
The stannite ion is , or similar. Stannite ion can be formed by adding strong base to stannous hydroxide. Stannite ion is a strong reducing agent; also, it may disproportionate to tin metal plus stannate ion. There are stannite compounds, for example, sodium stannite, . See also * Stannate In chemistry the term stannate refers to compounds of tin (Sn). Stannic acid (Sn(OH)4), the formal precursor to stannates, does not exist and is actually a hydrate of SnO2. The term is also used in naming conventions as a suffix; for example the ... Oxyanions {{Chem-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals. Properties Spinel crystallizes in the isometric system; common crystal forms are octahedra, usually twinned. It has no true cleavage, but shows an octahedral parting and a conchoidal fracture. Its hardness is 8, its specific gravity is 3.5–4.1, and it is transparent to opaque with a vitreous to dull luster. It may be colorless, but is usually various shades of red, lavender, blue, green, brown, black, or yellow. Some spinels are among the most famous gemstones; among them are the Black Prince's Ruby and the " Timur ruby" in the British Crown Jewels, and the "Côte de Bretagne", formerly from the French Crown jewels. The Samarian Spinel is the largest known spinel in the world, weighing . The transparent red spinels were called spinel-rubies ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. Its conducting properties may be altered in useful ways by introducing impurities (" doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called " metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical elem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
