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Spin Diffusion
Spin diffusion describes a situation wherein the individual nuclear spins undergo continuous exchange of energy. This permits polarization differences within the sample to be reduced on a timescale much shorter than relaxation effects. Spin diffusion is a process by which magnetization can be exchanged spontaneously between spins. The process is driven by dipolar coupling, and is therefore related to internuclear distances. Spin diffusion has been used to study many structural problems in the past, ranging from domain sizes in polymers and disorder in glassy materials to high-resolution crystal structure determination of small molecules and proteins. In solid-state nuclear magnetic resonance, spin diffusion plays a major role in Cross Polarization (CP) experiments. As mentioned before, by transferring the magnetization (and thus the population) from nuclei with different values for the spin-lattice relaxation (''T1''), the overall time for the experiment is reduced. Is a very ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin (physics)
Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nucleus, atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbital angular momentum operator is the quantum-mechanical counterpart to the classical angular momentum of orbital revolution and appears when there is periodic structure to its wavefunction as the angle varies. For photons, spin is the quantum-mechanical counterpart of the Polarization (waves), polarization of light; for electrons, the spin has no classical counterpart. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum. The existence of the electron spin can also be inferred theoretically from the spin–statistics theorem and from th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin Polarization
Spin polarization is the degree to which the spin, i.e., the intrinsic angular momentum of elementary particles, is aligned with a given direction. This property may pertain to the spin, hence to the magnetic moment, of conduction electrons in ferromagnetic metals, such as iron, giving rise to spin-polarized currents. It may refer to (static) spin waves, preferential correlation of spin orientation with ordered lattices (semiconductors or insulators). It may also pertain to beams of particles, produced for particular aims, such as polarized neutron scattering or muon spin spectroscopy. Spin polarization of electrons or of nuclei, often called simply magnetization, is also produced by the application of a magnetic field. Curie law is used to produce an induction signal in Electron spin resonance (ESR or EPR) and in Nuclear magnetic resonance (NMR). Spin polarization is also important for spintronics, a branch of electronics. Magnetic semiconductors are being researched as possib ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Relaxation Time
In the physical sciences, relaxation usually means the return of a perturbed system into equilibrium. Each relaxation process can be categorized by a relaxation time τ. The simplest theoretical description of relaxation as function of time ''t'' is an exponential law (exponential decay). In simple linear systems Mechanics: Damped unforced oscillator Let the homogeneous differential equation: :m\frac+\gamma\frac+ky=0 model damped unforced oscillations of a weight on a spring. The displacement will then be of the form y(t) = A e^ \cos(\mu t - \delta). The constant T (=2m/\gamma) is called the relaxation time of the system and the constant μ is the quasi-frequency. Electronics: RC circuit In an RC circuit containing a charged capacitor and a resistor, the voltage decays exponentially: : V(t)=V_0 e^ \ , The constant \tau = RC\ is called the ''relaxation time'' or RC time constant of the circuit. A nonlinear oscillator circuit which generates a repeating waveform by the r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid-state Nuclear Magnetic Resonance
Solid-state NMR (ssNMR) spectroscopy is a technique for characterizing atomic level structure in solid materials e.g. powders, single crystals and amorphous samples and tissues using nuclear magnetic resonance (NMR) spectroscopy. The anisotropic part of many spin interactions are present in solid-state NMR, unlike in solution-state NMR where rapid tumbling motion averages out many of the spin interactions. As a result, solid-state NMR spectra are characterised by larger linewidths than in solution state NMR, which can be utilized to give quantitative information on the molecular structure, conformation and dynamics of the material. Solid-state NMR is often combined with magic angle spinning to remove anisotropic interactions and improve the resolution as well as the sensitivity of the technique. Nuclear spin interactions The resonance frequency of a nuclear spin depends on the strength of the magnetic field at the nucleus, which can be modified by isotropic (e.g. chemical shift, i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gyromagnetic Ratio
In physics, the gyromagnetic ratio (also sometimes known as the magnetogyric ratio in other disciplines) of a particle or system is the ratio of its magnetic moment to its angular momentum, and it is often denoted by the symbol , gamma. Its SI unit is the radian per second per tesla (rad⋅s−1⋅T−1) or, equivalently, the coulomb per kilogram (C⋅kg−1). The term "gyromagnetic ratio" is often used as a synonym for a ''different'' but closely related quantity, the -factor. The -factor only differs from the gyromagnetic ratio in being dimensionless. For a classical rotating body Consider a nonconductive charged body rotating about an axis of symmetry. According to the laws of classical physics, it has both a magnetic dipole moment due to the movement of charge and an angular momentum due to the movement of mass arising from its rotation. It can be shown that as long as its charge and mass density and flow are distributed identically and rotationally symmetric, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantum Field Theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and in condensed matter physics to construct models of quasiparticles. QFT treats particles as excited states (also called Quantum, quanta) of their underlying quantum field (physics), fields, which are more fundamental than the particles. The equation of motion of the particle is determined by minimization of the Lagrangian, a functional of fields associated with the particle. Interactions between particles are described by interaction terms in the Lagrangian (field theory), Lagrangian involving their corresponding quantum fields. Each interaction can be visually represented by Feynman diagrams according to perturbation theory (quantum mechanics), perturbation theory in quantum mechanics. History Quantum field theory emerged from the wo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
