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Spectroelectrochemistry
Spectroelectrochemistry (SEC) is a set of multi-response analytical techniques in which complementary chemical information ( electrochemical and spectroscopic) is obtained in a single experiment. Spectroelectrochemistry provides a whole vision of the phenomena that take place in the electrode process. The first spectroelectrochemical experiment was carried out by Theodore Kuwana, PhD, in 1964. The main objective of spectroelectrochemical experiments is to obtain simultaneous, time-resolved and in-situ electrochemical and spectroscopic information on reactions taking place on the electrode surface. The base of the technique consist in studying the interaction of a beam of electromagnetic radiation with the compounds involved in these reactions. The changes of the optical and electrical signal allow us to understand the evolution of the electrode process. The techniques on which the spectroelectrochemistry is based are: * Electrochemistry, which studies the interaction betwee ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Theodore Kuwana
Theodore Kuwana (1931–2022) was a chemist and academic researcher known as the founding father of the field of spectroelectrochemistry. Kuwana's academic career included appointments at California Institute of Technology, the University of California, Riverside, Case Institute of Technology, Ohio State University, and finally at the University of Kansas. At KU, he was Regents Distinguished Professor of Chemistry and Pharmaceutical Chemistry, the Director of the Center for Bioanalytical Research, and Emeritus Distinguished Professor. He served as managing director of the Analytical Sciences Digital Library. During his career, Kuwana mentored more than 70 graduate students. Early life and education Theodore Kuwana, a son of Japanese immigrant ('' Issei'') parents Yoshino and Nenokichi Kuwana, was born August 3, 1931, in Idaho Falls, Idaho, in the United States. Kuwana wrote, "I was the youngest of six children; my parents were immigrant tenant potato farmers.. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
UV-Vis Absorption Spectroelectrochemistry
Ultraviolet-visible (UV-Vis) absorption spectroelectrochemistry (SEC) is a multiresponse technique that analyzes the evolution of the Absorption spectroscopy, absorption spectra in UV-Vis regions during an electrode process. This technique provides information from an Electrochemistry, electrochemical and Spectroscopy, spectroscopic point of view. In this way, it enables a better perception about the chemical system of interest. On one hand, molecular information related to the electronic levels of the molecules is obtained from the evolution of the spectra. On the other hand, kinetic and thermodynamic information of the processes is obtained from the electrochemical signal. UV-Vis absorption Spectroelectrochemistry, SEC allows qualitative analysis, through the characterization of the different present compounds, and quantitative analysis, by determining the concentration of the analytes of interest. Furthermore, it helps to determine different electrochemical parameters such as abso ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Available Light
In photography and cinematography, available light (also called ambient light or practical light) refers to any ''available'' source of light that is not explicitly supplied by the photographer for the purpose of taking pictures. The term usually refers to light sources in the surrounding environment that are present naturally (e.g. sunlight, moonlight, starlight, etc.) or artificial lighting that are already pre-existing (e.g. street lights, room lights, etc.). It generally excludes flashes, although arguably flash lighting provided by other photographers shooting simultaneously in the same space could be considered available light. Light sources that affect the scene and are included in the actual frame are called practical light sources, or simply practicals. Use of available light is an important factor in candid photography in order not to disturb the subjects. The use of available light may pose a challenge for a photographer. The brightness and direction of the light ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Magnetic Resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Emission Spectrum
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to an electron making a atomic electron transition, transition from a high energy state to a lower energy state. The photon energy of the emitted photon is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances. Emission In physics, emission is the process by which a higher energy quantum mechanical state of a particle becomes converted to a lower one through the emission of a photon, resulting in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absorption (chemistry)
In chemistry, absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter some bulk phase – liquid or solid material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface (as in the case for adsorption). A more common definition is that "Absorption is a chemical or physical phenomenon in which the molecules, atoms and ions of the substance getting absorbed enters into the bulk phase (gas, liquid or solid) of the material in which it is taken up." A more general term is ''sorption'', which covers absorption, adsorption, and ion exchange. Absorption is a condition in which something takes in another substance. In many processes important in technology, the chemical absorption is used in place of the physical process, e.g., absorption of carbon dioxide by sodium hydroxide – such acid-base processes do not follow the Nernst partition law (see: solubility). For ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radiation
In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visible light, ultraviolet, x-rays, and gamma radiation (γ) * ''particle radiation'', such as alpha radiation (α), beta radiation (β), proton radiation and neutron radiation (particles of non-zero rest energy) * '' acoustic radiation'', such as ultrasound, sound, and seismic waves (dependent on a physical transmission medium) * ''gravitational wave, gravitational radiation'', that takes the form of gravitational waves, or ripples in the curvature of spacetime Radiation is often categorized as either ''ionizing radiation, ionizing'' or ''non-ionizing radiation, non-ionizing'' depending on the energy of the radiated particles. Ionizing radiation carries more than 10 electron volt, eV, which is enough to ionize atoms and molecules and break ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronic Transition
A quantum jump is the abrupt transition of a quantum system (atom, molecule, atomic nucleus) from one quantum state to another, from one energy level to another. When the system absorbs energy, there is a transition to a higher energy level (excitation); when the system loses energy, there is a transition to a lower energy level. The concept was introduced by Niels Bohr, in his 1913 Bohr model. A quantum jump is a phenomenon that is peculiar to quantum systems and distinguishes them from classical systems, where any transitions are performed gradually. In quantum mechanics, such jumps are associated with the non-unitary evolution of a quantum-mechanical system during measurement. A quantum jump can be accompanied by the emission or absorption of photons; energy transfer during a quantum jump can also occur by non-radiative resonant energy transfer or in collisions with other particles. In modern physics, the concept of a quantum jump is rarely used; as a rule scientists speak ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-rays
An X-ray, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10 Picometre, picometers to 10 Nanometre, nanometers, corresponding to frequency, frequencies in the range 30 Hertz, petahertz to 30 Hertz, exahertz ( to ) and energies in the range 145 electronvolt, eV to 124 keV. X-ray wavelengths are shorter than those of ultraviolet, UV rays and typically longer than those of gamma rays. In many languages, X-radiation is referred to as Röntgen radiation, after the German scientist Wilhelm Röntgen, Wilhelm Conrad Röntgen, who discovered it on November 8, 1895. He named it ''X-radiation'' to signify an unknown type of radiation.Novelline, Robert (1997). ''Squire's Fundamentals of Radiology''. Harvard University Press. 5th edition. . Spellings of ''X-ray(s)'' in English include the variants ''x-ray(s)'', ''xray(s)'', and ''X ray(s)''. The most familiar use of X-ra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monochromatic Light
{{Short description, Electromagnetic radiation with a single constant frequency In physics, monochromatic radiation is electromagnetic radiation with a single constant frequency. When that frequency is part of the visible spectrum (or near it) the term monochromatic light is often used. Monochromatic light is perceived by the human eye as a spectral color. When monochromatic radiation propagates through vacuum or a homogeneous transparent medium, it has a single constant wavelength. Practical monochromaticity No radiation can be totally monochromatic, since that would require a wave of infinite duration as a consequence of the Fourier transform's localization property (cf. spectral coherence). In practice, "monochromatic" radiation — even from lasers or spectral lines — always consists of components with a range of frequencies of non-zero width. Generation Monochromatic radiation can be produced by a number of methods. Isaac Newton observed that a beam of light from th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raman Scattering
Raman scattering or the Raman effect () is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes Raman scattering. The effect is exploited by chemists and physicists to gain information about materials for a variety of purposes by performing various forms of Raman spectroscopy. Many other variants of Raman spectroscopy allow rotational energy to be examined (if gas samples are used) and electronic energy levels may be examined if an X-ray source is used in addition to other possibilities. More complex techniques involving pulsed lasers, multiple laser beams and so on are known. Light has a certain probability of being scattered by a material. When photons are scattered, most of them are elastically scattered (Rayleigh scatt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
