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Silver Cyanide
Silver cyanide is the chemical compound with the formula AgCN. It is a white salt that is precipitated upon treatment of solutions containing Ag+ with cyanide, which is used in some schemes to recover silver from solution. Silver cyanide is used in silver-plating. Structure The structure of silver cyanide consists of - g-CN chains in which the linear two-coordinate Ag+ ions are bridged by the cyanide ions, typical of silver(I) and other d10 ions. This is the same binding mode as seen in the more famous case of Prussian blue. These chains then pack hexagonally with adjacent chains offset by +/- 1/3 of the ''c'' lattice parameter. This is the same as the structure adopted by the high temperature polymorph of copper(I) cyanide. The silver to carbon and silver to nitrogen bond lengths in AgCN are both ~2.06 Å and the cyanide groups show head-to-tail disorder. Reactions AgCN precipitates upon the addition of sodium cyanide to a solution containing Ag+. On the addition of further cy ...
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Weighing Scale
A scale or balance is a device used to measure weight or mass. These are also known as mass scales, weight scales, mass balances, massometers, and weight balances. The traditional scale consists of two plates or bowls suspended at equal distances from a fulcrum. One plate holds an object of unknown mass (or weight), while objects of known mass or weight, called '' weights'', are added to the other plate until mechanical equilibrium is achieved and the plates level off, which happens when the masses on the two plates are equal. The perfect scale rests at neutral. A spring scale will make use of a spring of known stiffness to determine mass (or weight). Suspending a certain mass will extend the spring by a certain amount depending on the spring's stiffness (or spring constant). The heavier the object, the more the spring stretches, as described in Hooke's law. Other types of scales making use of different physical principles also exist. Some scales can be calibrate ...
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Chemical Formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called '' empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of atoms ...
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List Of Compounds With Carbon Number 1
This is a partial list of molecules that contain 1 carbon atom. C+H+O compounds Each hydrogen added to a molecule can be considered as a proton plus a one-electron reduction of the redox state, while each oxygen counts as a two-electron oxidation. Thus a net addition of H2O is a simple hydration with no net change in redox state and frequently occurs reversibly in aqueous solution. These relationships may be viewed in the following table (peroxide In chemistry, peroxides are a group of Chemical compound, compounds with the structure , where the R's represent a radical (a portion of a complete molecule; not necessarily a free radical) and O's are single oxygen atoms. Oxygen atoms are joined ...s and ions are excluded; unstable or hypothetical compounds are italicized). See also * Carbon number * List of compounds with carbon number 2 {{DEFAULTSORT:Dictionary Of Chemical Formulas Merge C C00 ...
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Potassium Argentocyanide
Potassium dicyanoargentate is an inorganic compound with the formula KAg(CN)2. A white solid, it is the K+ salt of the linear coordination complex g(CN)2sup>−. It forms upon treatment of virtually any silver salt with two equivalents of potassium cyanide. Uses and reactions KAg(CN)2 is significant adventitious product of gold mining using cyanide as an extractant. It can be used in silver plating, as a bactericide A bactericide or bacteriocide, sometimes abbreviated Bcidal, is a substance which kills bacteria. Bactericides are disinfectants, antiseptics, or antibiotics. However, material surfaces can also have bactericidal properties based solely on their p ..., and in the manufacture of antiseptics. It forms a variety of coordination polymers, a property that exploits the bridging tendency of the cyanide ligand. References Potassium compounds Silver compounds Cyano complexes {{inorganic-stub ...
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Luminescent
Luminescence is a spontaneous emission of radiation from an electronically or vibrationally excited species not in thermal equilibrium with its environment. A luminescent object emits ''cold light'' in contrast to incandescence, where an object only emits light after heating. Generally, the emission of light is due to the movement of electrons between different energy levels within an atom after excitation by external factors. However, the exact mechanism of light emission in vibrationally excited species is unknown. The dials, hands, scales, and signs of aviation and navigational instruments and markings are often coated with luminescent materials in a process known as ''luminising''. Types * Ionoluminescence, a result of bombardment by fast ions * Radioluminescence, a result of bombardment by ionizing radiation * Electroluminescence, a result of an electric current passed through a substance ** Cathodoluminescence, a result of a luminescent material being struck by electro ...
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Phosphine
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula , classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (). With traces of present, is spontaneously flammable in air ( pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure. Phosphines are compounds that include and the organophosphines, which are derived from by substituting one or more hydrogen atoms with organic groups. They have the general formula . Phosphanes are saturated phosphorus hydrides of the form , such as triphosphane. Phosphine () is the smallest of the phosphines and the smallest of the phosphanes. History Philippe Gengembre (1764–1838), a student of Lavoisi ...
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Sodium Cyanide
Sodium cyanide is a compound with the formula Na C N and the structure . It is a white, water-soluble solid. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt. Its main application, in gold mining, also exploits its high reactivity toward metals. It is a moderately strong base. Production and chemical properties Sodium cyanide is produced by treating hydrogen cyanide with sodium hydroxide: : Worldwide production was estimated at 500,000 tons in the year 2006. Formerly it was prepared by the Castner process involving the reaction of sodium amide with carbon at elevated temperatures. : The structure of solid NaCN is related to that of sodium chloride. The anions and cations are each six-coordinate. Potassium cyanide (KCN) adopts a similar structure. When treated with acid, it forms the toxic gas hydrogen cyanide: : Because the salt is derived from a weak acid, sodium cyanide readily reverts to HCN by hydrolysis; the moist solid emits smal ...
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Copper(I) Cyanide
Copper(I) cyanide (cuprous cyanide) is an inorganic compound with the formula CuCN. This off-white solid occurs in two polymorphs; impure samples can be green due to the presence of Cu(II) impurities. The compound is useful as a catalyst, in electroplating copper, and as a reagent in the preparation of nitriles.H. Wayne Richardson "Copper Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. Structure Copper cyanide is a coordination polymer. It exists in two polymorphs both of which contain - u-CN chains made from linear copper(I) centres linked by cyanide bridges. In the high-temperature polymorph, HT-CuCN, which is isostructural with AgCN, the linear chains pack on a hexagonal lattice and adjacent chains are off set by +/- 1/3 ''c'', Figure 1. In the low-temperature polymorph, LT-CuCN, the chains deviate from linearity and pack into rippled layers which pack in an AB fashion with chains in adjacent layers rotated by 49 °, Figure 2. File ...
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Prussian Blue
Prussian blue (also known as Berlin blue, Brandenburg blue, Parisian and Paris blue) is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula . It consists of cations, where iron is in the oxidation state of +3, and anions, where iron is in the oxidation state of +2, so, the other name of this salt is iron(III) hexacyanoferrate(II). Turnbull's blue is essentially identical chemically, excepting that it has different impurities and particle sizes—because it is made from different reagents—and thus it has a slightly different color. Prussian blue was created in the early 18th century and is the first modern chemical synthesis, synthetic pigment. It is prepared as a very fine colloidal dispersion, because the compound is not soluble in water. It contains variable amounts of other ions and its appearance depends sensitively on the size of the colloidal particles. The pigment is used in paints, it became prominent in 19th-century ...
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Inorganic Chemistry (journal)
''Inorganic Chemistry'' is a biweekly peer-reviewed scientific journal published by the American Chemical Society since 1962. It covers research in all areas of inorganic chemistry. The current editor-in-chief is Stefanie Dehnen ( Karlsruhe Institute of Technology). Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2022 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a type of journal ranking. Journals with higher impact factor values are considered more prestigious or important within their field. The Impact Factor of a journa ... of 4.6. See also * '' Organometallics'' References External links * American Chemical Society academic journals Biweekly journals Academic journals established in 1962 English-language journals Inorganic chemistry journals {{chem-journal-stub ...
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Cyanide
In chemistry, cyanide () is an inorganic chemical compound that contains a functional group. This group, known as the cyano group, consists of a carbon atom triple-bonded to a nitrogen atom. Ionic cyanides contain the cyanide anion . This anion is extremely poisonous. Soluble cyanide salts such as sodium cyanide (NaCN), potassium cyanide (KCN) and tetraethylammonium cyanide () are highly toxic. Covalent cyanides contain the group, and are usually called nitriles if the group is linked by a single covalent bond to carbon atom. For example, in acetonitrile , the cyanide group is bonded to methyl . In tetracyanomethane , four cyano groups are bonded to carbon. Although nitriles generally do not release cyanide ions, the cyanohydrins do and are thus toxic. The cyano group may be covalently bonded to atoms different than carbon, e.g., in cyanogen azide , phosphorus tricyanide and trimethylsilyl cyanide . Hydrogen cyanide, or , is a highly volatile toxic liquid tha ...
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