Selenide Mineral
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Selenide Mineral
Selenide minerals are those minerals that have the selenide anion as a main component. Selenides are similar to sulfides and often grouped with them. Examples include: * achavalite * athabascaite * clausthalite * ferroselite * penroseite * stilleite * tiemannite * umangite Umangite is a copper selenide mineral, Cu3 Se2, discovered in 1891. It occurs only in small grains or fine granular aggregates with other copper minerals of the sulfide group. It has a hardness of 3. It is blue-black to red-violet in color with a ... References {{Mineral-stub ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct ...
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Selenide
A selenide is a chemical compound containing a selenium anion with oxidation number of −2 (Se2−), much as sulfur does in a sulfide. The chemistry of the selenides and sulfides is similar. Similar to sulfide, in aqueous solution, the selenide ion, Se2−, is prevalent only in very basic conditions. In neutral conditions, hydrogen selenide ion, HSe−, is most common. In acid conditions, hydrogen selenide, H2Se, is formed. Some selenides are reactive to oxidation by air. Owing to the greater reducing power of selenide, metal selenides are more easily decomposed to the elements than are sulfides (tellurides are even more labile). Selenides of electropositive metals: such as aluminium selenide readily hydrolyse, even in moist air, evolving toxic hydrogen selenide gas. Pure selenide minerals are rare, instead selenium tends to partially substitute for sulfide in many sulfide minerals. The degree of substitution is only of commercial interest for copper sulfide ores, in which case ...
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Sulfide Minerals
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite *Jame ...
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Athabascaite
Athabascaite is a member of the copper selenide minerals, and forms with other copper selenides. It was first discovered by S. Kaiman in 1949 while he was researching radioactive materials around Lake Athabasca. Kaiman was conducting research near Uranium City, Saskatchewan where mass amounts of uranium mines were present.Harris, D.C., Cabri, L.J., and Kaiman, S. (1970Athabascaite: A New Copper Selenide Mineral from Martin Lake, Saskatchewan The Canadian Mineralogist, 10(2), 207-215. History Kaiman sent his specimens for testing to J. W. Earley, then a graduate student. With the invention of the microprobe analyzer, D.C. Harris decided to delve further into the virtually unknown mineral with little success.Earley, J.W. (1950Description and Synthesis of the Selenide Minerals The American Mineralogist 35(5&6), 337-364. Structure Because of unavailability of sufficiently large single crystals, little is known about the atomic structure of athabascaite. Copper (Cu+) serves as the cat ...
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Clausthalite
Clausthalite is a lead selenide mineral, PbSe. It forms a solid solution series with galena PbS. Occurrence It occurs in low-sulfur hydrothermal deposits with other selenides and in mercury deposits. It is associated with tiemannite, klockmannite, berzelianite, umangite, gold, stibiopalladinite and uraninite. It was first described in 1832 and named for the discovery locality of Clausthal-Zellerfeld in the Harz Mountains, Germany. See also * Classification of minerals * List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ... References Lead minerals Selenide minerals Galena group {{mineral-stub ...
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Ferroselite
Orthorhombic ferroselite and its isometric polymorph dzharkenite are iron selenides of general formula FeSe2 precipitated under reducing conditions in anoxic environments. They are a source of selenium in the Rocky Mountains where selenium occurrence is associated with Upper Cretaceous shale deposits. In the frame of safety assessment calculations made for deep disposal of high-level radioactive waste, ferroselite and dzharkenite are also considered in geochemical calculations as one of the mineral phases limiting the solubility of Selenium-79. Names Dzharkenite's type locale is in the Suluchekinskoye Se-U deposit in the Dzharkenskaya Depression of the Middle Ili River, Almaty Province, in southeastern Kazakhstan. It was discovered in 1995 and named after the depression. Ferroselite was first reported in 1955 for an occurrence in the Ust’-Uyuk uranium deposit in Tuva, Siberia. Its name comes from the Latin ''ferro'' (iron) and "sel" for selenium. See also * Coccolithoph ...
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Penroseite
Penroseite is a rare selenide mineral with formula (Ni,Co,Cu)Se2. It has a gray-steel color and black streak with a hardness of 3. It is an isometric mineral, 2/m. Penroseite was first discovered in 1925 in a Bolivian rhyolite. It was named for Richard Penrose (1863–1931), an economic geologist. Penroseite is a rare mineral found in the Pacajake mines in Bolivia. It was discovered in 1925. It used to be found in fissure veins in the extrusive igneous rhyolite rock. It is considered as a member of the pyrite group from the perspective of its structure, with a cubic space group (Bayliss, 1989). Penroseite makes extensive solid solutions with other minerals. For example, penroseite can be a result of alteration process of many selenides, such as olsacherite Pb2(SO4)(SeO4). Olsacherite forms very sparingly in well formed crystal covering the walls of the external side of the small cracks (Hurlbut, 1969). Another mineral related to penroseite is piretite. It occurs as an altera ...
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Stilleite
Stilleite is a selenide mineral, zinc selenide, with the formula Zn Se. It has been found only as microscopic gray crystals occurring as inclusions in linnaeite associated with other selenide and sulfides. It was originally discovered in Katanga Province, Zaire in 1956 and is named for the German geologist, Hans Stille (1876–1966). It has been reported from the Santa Brigida mine, La Rioja Province, Argentina and from Tilkerode (Abberode) in the Harz Mountains, Germany. Associated minerals include pyrite, linnaeite, clausthalite, selenian vaesite, molybdenite and dolomite in the Shinkolobwe region of the Congo); and with tiemannite, clausthalite, eucairite, umangite, klockmannite in the Santa Brigida mine, Argentina. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A *Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2004)alfred *Abswurmbac ...
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Tiemannite
Tiemannite is a mineral, mercury selenide, formula HgSe. It occurs in hydrothermal veins associated with other selenides, or other mercury minerals such as cinnabar, and often with calcite. Discovered in 1855 in Germany, it is named after Johann Carl Wilhelm Tiemann (1848–1899). See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A * Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2004)alfred *Abswurmbachite: Cu2+Mn3+6O8SiO4 – German mineralogist I ... References * Tiemannite from a micro-disseminated gold deposit in Qiongmo, Liu Jiajun, Zheng Minghua, Liu Jianming, Lu Wenquan, Journal of Chengdu Institute of Technology, vol. 23 (2), pages 21–28 (1996) * Timanite and onofrite in ores of Siberian mercury deposits, Vasil'yev V.I., Lavrent'yev Y.G., Doklady (Academy of Sciences of the USSR, Earth Sciences Section) vol. 222, Pages 159-162 ...
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Umangite
Umangite is a copper selenide mineral, Cu3 Se2, discovered in 1891. It occurs only in small grains or fine granular aggregates with other copper minerals of the sulfide group. It has a hardness of 3. It is blue-black to red-violet in color with a black streak. It has a metallic luster. Umangite is named after the locality of Sierra de Umango, La Rioja province in Argentina. It also occurs at other localities including the Harz Mountains in Germany, and at Skrickerum, Sweden. See also *List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ... References Copper(I,II) minerals Selenide minerals Tetragonal minerals Minerals in space group 113 {{mineral-stub ...
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