Rose Metal
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Rose Metal
Rose's metal, Rose metal or Rose's alloy is a fusible alloy with a low melting point. Rose's metal consists of 50% bismuth, 25–28% lead and 22–25% tin. Its melting point is between . The alloy does not appreciably contract or expand on solidification, this characteristic being a function of its bismuth percentage. Uses Rose's metal has several common uses: #As a solder. It was used to secure cast iron railings and balusters in pockets in stone bases and steps. #As a heat transfer medium in heating baths. #As a malleable filling to prevent tubes and pipes from crimping when bent. Rose's metal is melted and poured into the tube. It then solidifies in place but remains malleable. This allows the tube or pipe to be bent and reworked without crimping. After the desired shape is achieved the Rose's metal is remelted and removed, leaving the pipe or tube in its modified shape. History It was discovered by the German chemist Valentin Rose the Elder, the grandfather of Heinrich Rose ...
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Fusible Alloy
A fusible alloy is a metal alloy capable of being easily fused, i.e. easily meltable, at relatively low temperatures. Fusible alloys are commonly, but not necessarily, eutectic alloys. Sometimes the term "fusible alloy" is used to describe alloys with a melting point below . Fusible alloys in this sense are used for solder. Introduction From a practical view, low-melting alloys can be divided into the following categories: * Mercury-containing alloys *Only alkali metal-containing alloys *Gallium-containing alloys (but neither alkali metal nor mercury) *Only bismuth, lead, tin, cadmium, zinc, indium, and sometimes thallium-containing alloys *Other alloys (rarely used) Some reasonably well-known fusible alloys are Wood's metal, Field's metal, Rose metal, Galinstan, and NaK. Applications Melted fusible alloys can be used as coolants as they are stable under heating and can give much higher thermal conductivity than most other coolants; particularly with alloys made with a high th ...
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Melting Point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of substances to supercool, the freezing point can easily appear to be below its actual value. When the "characteristic freezing point" of a substance is determined, in fact, the actual methodology is almost always "the principle of observing the disappearance rather than the formation of ice, that is, the melting point." Examples For most substances, melting and freezing points are approximately equal. For example, the melting point ''and'' freezing point of mercury is . How ...
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Bismuth
Bismuth is a chemical element with the Symbol (chemistry), symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs naturally, and its sulfide and oxide forms are important commercial ores. The free element is 86% as dense as lead. It is a brittle metal with a silvery-white color when freshly produced. Passivation (chemistry), Surface oxidation generally gives samples of the metal a somewhat rosy cast. Further oxidation under heat can give bismuth a vividly Iridescence, iridescent appearance due to thin-film interference. Bismuth is both the most Diamagnetism, diamagnetic element and one of the least Thermal conductivity, thermally conductive metals known. Bismuth was long considered the element with the highest atomic mass whose nuclei do not spontaneously decay. However, in 2003 it was discovered to be extremely weakly radioactive. The ...
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Lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the ...
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Solder
Solder (; NA: ) is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics. Soft solder typically has a melting point range of , and is commonly used in electronics, plumbing, and sheet metal work. Alloys that melt between are the most commonly used. Soldering performed using alloys with a melting point above is called "hard soldering", "silver soldering", or brazing. In specific proportions, some alloys are eutectic — that is, the alloy's melting point is the lowest possible for a mixture of those components, and co ...
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Heat Bath
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is also often used to refer to the thermal energy contained in a system as a component of its internal energy and that is reflected in the temperature of the system. For both uses of the term, heat is a form of energy. An example of formal vs. informal usage may be obtained from the right-hand photo, in which the metal bar is "conducting heat" from its hot end to its cold end, but if the metal bar is considered a thermodynamic system, then the energy flowing within the metal bar is called internal energy, not heat. The hot metal bar is also transferring heat to its surroundings, a correct statement for both the strict and loose meanings of ''heat''. Another example of informal usage is the term '' heat content'', used despite the fact that ph ...
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Valentin Rose The Elder
Valentin Rose the Elder (16 August 1736 – 28 April 1771) was a German pharmacist and chemist born in Neuruppin. He is remembered for creation of a fusible alloy known as Rose metal, which is composed of lead, bismuth and tin. Beginning in 1761, he was owner and manager of a laboratory and pharmacy in Berlin known as ''Zum Weißen Schwan'' (At the White Swan). After his death in 1771, famed chemist Martin Heinrich Klaproth (1743–1817) became manager of the establishment. His son, also named Valentin Rose, was a noted pharmacist. Mineralogists Heinrich Rose and Gustav Rose were his grandsons; the classicist Valentin Rose and the surgeon Edmund Rose Edmund Rose (October 10, 1836 – May 31, 1914) was a German surgeon who was a native of Berlin. He studied medicine in Berlin and Würzburg, and subsequently was an assistant to surgeon Robert Ferdinand Wilms in Berlin from 1860 until 1864. F ... were his great-grandsons. References Rose, Heinrichat '' Allgemeine Deutsche Biog ...
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Heinrich Rose
Heinrich Rose (6 August 1795 – 27 January 1864) was a German mineralogist and analytical chemist. He was the brother of the mineralogist Gustav Rose and a son of Valentin Rose. Rose's early works on phosphorescence were noted in the Quarterly Journal of Science in 1821, and on the strength of these works, he was elected privatdozent at the University of Berlin from 1822, then Professor from 1832. In 1846 Rose rediscovered the chemical element niobium, proving conclusively that it was different from tantalum. This confirmed that Charles Hatchett had discovered niobium in 1801 in columbite ore. Hatchett had named the new element "columbium", from the ore in which niobium and tantalum coexist. The element was eventually assigned the name niobium by the IUPAC in 1950 after Niobe, the daughter of Tantalus in Greek mythology. In 1845 Rose published the discovery of a new element pelopium, which he had found in the mineral tantalite. After subsequent research pelopium was ident ...
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Fusible Alloys
Fusion, or synthesis, is the process of combining two or more distinct entities into a new whole. Fusion may also refer to: Science and technology Physics *Nuclear fusion, multiple atomic nuclei combining to form one or more different atomic nuclei and subatomic particles **Fusion power, power generation using controlled nuclear fusion reactions **Cold fusion, a hypothesized type of nuclear reaction that would occur at or near room temperature *Heat fusion, a welding process for joining two pieces of a thermoplastic material *Melting, or transitioning from solid to liquid form Biology and medicine * Binaural fusion, the cognitive process of combining the auditory information received by both ears * Binocular fusion, the cognitive process in binocular vision of combining the visual information received by both eyes * Cell fusion, a process in which several uninuclear cells combine to form a multinuclear cell * Gene fusion, a genetic event and molecular biology technique * Lipid ...
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Bismuth Compounds
Bismuth compounds are compounds containing the element bismuth (Bi). Bismuth forms trivalent and pentavalent compounds, the trivalent ones being more common. Many of its chemical properties are similar to those of arsenic and antimony, although they are less toxic than derivatives of those lighter elements. Oxides and sulfides At elevated temperatures, the vapors of the metal combine rapidly with oxygen, forming the yellow trioxide, . Wiberg, p. 768. Greenwood, p. 553. When molten, at temperatures above 710 °C, this oxide corrodes any metal oxide and even platinum. Krüger, p. 185 On reaction with a base, it forms two series of oxyanions: , which is polymeric and forms linear chains, and . The anion in is a cubic octameric anion, , whereas the anion in is tetrameric. The dark red bismuth(V) oxide, , is unstable, liberating gas upon heating. The compound NaBiO3 is a strong oxidising agent. Greenwood, p. 578. Bismuth sulfide, , occurs naturally in bismuth ores. It i ...
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Lead Alloys
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the grou ...
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