Rayite
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Rayite
Rayite, a monoclinic mineral containing Lead-Silver-Thallium-Antimony, was found during microscopic and electron microprobe study of specimens from the complex, polymetallic sulphide-native metal sulpho-salt paragenesis of Rajpura- Dariba, Rajasthan, India. It is named after Dr. Santosh K. Ray of President College, Calcutta, India. It bears a striking resemblance to owyheeite in terms of its Lead/(Silver,Thallium)/Antimony ratio, yet its structural affinity lies with Semseyite. The average composition is Lead-47.06, Copper-0.03, Silver-4.54, Thallium-2.04, Antimony-27.42, Sulphur-19.59 by wt.% (total 100.68) suggesting an ideal formula of Pb8 Sb8 S21, where Ag > Tl. Meneghinite, Owyheeite, and Galena are related minerals. Occurrence It was found in the ores of precambrian polymetallic massive- sulfide deposit interbedded with kyanite-graphite schists, diopside-bearing calc-silicates, and meta-cherts in Rajpura- Dariba deposit, Udaipur Division, Udaipur District, Dariba Mine, ...
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Lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the ...
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Meneghinite
Meneghinite is a sulfosalt mineral with the chemical formula CuPb13 Sb7S24. In the orthorhombic crystal system, meneghinite has a Mohs hardness of , one perfect cleavage and a conchoidal fracture. It is a blackish lead-grey in colour and gives a black shining streak. Its lustre is metallic. Discovered in the Italian Province of Lucca in 1852, it is named after Giuseppe Meneghini (1811–1889) of the University of Pisa The University of Pisa ( it, Università di Pisa, UniPi), officially founded in 1343, is one of the oldest universities in Europe. History The Origins The University of Pisa was officially founded in 1343, although various scholars place ..., who first observed the species. The Bottino Mine in Lucca is the type locality. References Sulfosalt minerals Lead minerals Copper(I) minerals Antimony minerals Orthorhombic minerals Minerals in space group 62 {{sulfide-mineral-stub ...
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Pleochroism
Pleochroism (from Greek πλέων, ''pléōn'', "more" and χρῶμα, ''khrôma'', "color") is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light. Background Anisotropic crystals will have optical properties that vary with the direction of light. The direction of the electric field determines the polarization of light, and crystals will respond in different ways if this angle is changed. These kinds of crystals have one or two optical axes. If absorption of light varies with the angle relative to the optical axis in a crystal then pleochroism results. Anisotropic crystals have double refraction of light where light of different polarizations is bent different amounts by the crystal, and therefore follows different paths through the crystal. The components of a divided light beam follow different paths within the mineral and travel at different speeds. When the mineral is observed at some a ...
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Meneghinite
Meneghinite is a sulfosalt mineral with the chemical formula CuPb13 Sb7S24. In the orthorhombic crystal system, meneghinite has a Mohs hardness of , one perfect cleavage and a conchoidal fracture. It is a blackish lead-grey in colour and gives a black shining streak. Its lustre is metallic. Discovered in the Italian Province of Lucca in 1852, it is named after Giuseppe Meneghini (1811–1889) of the University of Pisa The University of Pisa ( it, Università di Pisa, UniPi), officially founded in 1343, is one of the oldest universities in Europe. History The Origins The University of Pisa was officially founded in 1343, although various scholars place ..., who first observed the species. The Bottino Mine in Lucca is the type locality. References Sulfosalt minerals Lead minerals Copper(I) minerals Antimony minerals Orthorhombic minerals Minerals in space group 62 {{sulfide-mineral-stub ...
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Galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite. Occurrence Galena is the main ore of lead, used since ancient times, since lead can be smelted from galena in an ordinary wood fire. Galena typically is found in hydrothermal veins in association with sphalerite, marcasite, chalcopyrite, cerussite, anglesite, dolomite, calcite, quartz, barite, and fluorite. It is also found in association with sphalerite in low-temperature lead-zinc deposits within limestone beds. Minor amounts are found in contact metamorphic zones, in pegmatites, and disseminated in sedimentary rock. In some deposits the galena contains up to 0.5% silver, a byproduct that ...
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Udaipur
Udaipur () (ISO 15919: ''Udayapura''), historically named as Udayapura, is a city and municipal corporation in Udaipur district of the state of Rajasthan, India. It is the administrative headquarter of Udaipur district. It is the historic capital of the kingdom of Mewar in the former Rajputana Agency. It was founded in 1559 by Udai Singh II of the Sisodia clan of Rajput, when he shifted his capital from the city of Chittorgarh to Udaipur after Chittorgarh was besieged by Akbar. It remained as the capital city till 1818 when it became a British princely state, and thereafter the Mewar province became a part of Rajasthan when India gained independence in 1947. The city is located in the southernmost part of Rajasthan, near the Gujarat border. It is surrounded by the Aravali Range, which separates it from the Thar Desert. It is placed almost in the middle of two major Indian metro cities, around 660 km from Delhi and 800 km from Mumbai. Besides, connectivity with Gujar ...
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Silicates
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used for any salt of such anions, such as sodium metasilicate; or any ester containing the corresponding chemical group, such as tetramethyl orthosilicate. The name "silicate" is sometimes extended to any anions containing silicon, even if they do not fit the general formula or contain other atoms besides oxygen; such as hexafluorosilicate .Most commonly, silicates are encountered as silicate minerals. For diverse manufacturing, technological, and artistic needs, silicates are versatile materials, both natural (such as granite, gravel, and garnet) and artificial (such as Portland cement, ceramics, glass, and waterglass). Structural principles In all silicates, silicon atom occupies the center of an idealized tetrahedron whose corner ...
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Diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°. Formation Diopside is found in ultramafic (kimberlite and peridotite) igneous rocks, and diopside-rich augite is common in mafic rocks, such as olivine basalt and andesite. Diopside is also found in a variety of metamorphic rocks, such as in contact metamorphosed skarns developed from high silica dolomites. It is an important min ...
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Schists
Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes or plates. This texture reflects a high content of platy minerals, such as micas, talc, chlorite, or graphite. These are often interleaved with more granular minerals, such as feldspar or quartz. Schist typically forms during regional metamorphism accompanying the process of mountain building (orogeny) and usually reflects a medium grade of metamorphism. Schist can form from many different kinds of rocks, including sedimentary rocks such as mudstones and igneous rocks such as tuffs. Schist metamorphosed from mudstone is particularly common and is often very rich in mica (a ''mica schist''). Where the type of the original rock (the protolith) is discernible, the schist is usually given a name reflecting its protolith, such as ''schistose met ...
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Graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large scale (300 kton/year, in 1989) for uses in pencils, lubricants, and electrodes. Under high pressures and temperatures it converts to diamond. It is a weak conductor of heat and electricity. Types and varieties Natural graphite The principal types of natural graphite, each occurring in different types of ore deposits, are * Crystalline small flakes of graphite (or flake graphite) occurs as isolated, flat, plate-like particles with hexagonal edges if unbroken. When broken the edges can be irregular or angular; * Amorphous graphite: very fine flake graphite is sometimes called amorphous; * Lump graphite (or vein graphite) occurs in fissure veins or fractures and appears as massive platy intergrowths of fibrous or acicular crystalline ...
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Kyanite
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite. Kyanite is strongly anisotropic, in that its hardness varies depending on its crystallographic direction. In kyanite, this anisotropism can be considered an identifying characteristic, along with its characteristic blue color. Its name comes from the same origin as that of the color cyan, being derived from the Ancient Greek word κύανος. This is generally rendered into English as ''kyanos'' or ''kuanos'' and means "dark blue". Kyanite is used as a raw material in the manufacture of ceramics and abrasives, and it is an important index mineral used by geologists to trace metamorphic zones. Properties Kyanite is an aluminum silicate mine ...
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Sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH−) are the conjugate acids of sulfide. Chemical properties The sulfide ion, S2−, does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8 M ...
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