Rawmill
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Rawmill
A raw mill is the equipment used to grind raw materials into "rawmix" during the manufacture of cement. Rawmix is then fed to a cement kiln, which transforms it into clinker, which is then ground to make cement in the cement mill. The raw milling stage of the process effectively defines the chemistry (and therefore physical properties) of the finished cement, and has a large effect upon the efficiency of the whole manufacturing process. History The history of the development of the technology of raw material grinding defines the early history of cement technology. Other stages of cement manufacture used existing technology in the early days. Early hydraulic materials such as hydraulic limes, natural cements and Parker's Roman cement were all based on "natural" raw materials, burned "as-dug". Because these natural blends of minerals occur only rarely, manufacturers were interested in making a fine-grained artificial mixture of readily available minerals such as limestone and ...
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Cement Kiln
Cement kilns are used for the pyroprocessing stage of manufacture of portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates. Over a billion tonnes of cement are made per year, and cement kilns are the heart of this production process: their capacity usually defines the capacity of the cement plant. As the main energy-consuming and greenhouse-gas–emitting stage of cement manufacture, improvement of kiln efficiency has been the central concern of cement manufacturing technology. Emissions from cement kilns are a major source of greenhouse gas emissions, accounting for around 2.5% of non-natural carbon emissions worldwide. The manufacture of cement clinker A typical process of manufacture consists of three stages: * grinding a mixture of limestone and clay or shale to make a fine "rawmix" (see Rawmill); * heating the rawmix to sintering temperature (up to 1450 °C) in a cement k ...
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James Frost (cement Maker)
James Frost (1780?-1840?) was a British cement manufacturer who invented processes that led to the eventual development of Portland cement. Biography Frost was born in Finchley, Middlesex, England. He set up a plant making Roman cement at Harwich in 1807, supplying it for government work. He began experimenting with formulations for "artificial" cements that would provide a cheaper alternative to Roman cement. He appears to have produced a prototype cement at Harwich in 1810. However, it was not until 1822 that he was granted a patent for what he called "British Cement". In October 1825, he leased land at Swanscombe, Kent, and set up a plant to manufacture both Roman cement and the new product. The key innovation in his work was the "wet" grinding of raw materials, which became fundamental to the early development of Portland cement. He ground the soft local chalk together with alluvial clay from the Medway estuary and added water in a washmill to produce a thin slurry fro ...
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Fluorine
Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reactive, as it reacts with all other elements except for the light inert gases. Among the elements, fluorine ranks 24th in universal abundance and 13th in terrestrial abundance. Fluorite, the primary mineral source of fluorine which gave the element its name, was first described in 1529; as it was added to metal ores to lower their melting points for smelting, the Latin verb meaning 'flow' gave the mineral its name. Proposed as an element in 1810, fluorine proved difficult and dangerous to separate from its compounds, and several early experimenters died or sustained injuries from their attempts. Only in 1886 did French chemist Henri Moissan isolate elemental fluorine using low-temperature electrolysis, a process still employed for modern pr ...
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Periodic Table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of chemistry. It is a graphic formulation of the periodic law, which states that the properties of the chemical elements exhibit an approximate periodic dependence on their atomic numbers. The table is divided into four roughly rectangular areas called blocks. The rows of the table are called periods, and the columns are called groups. Elements from the same group of the periodic table show similar chemical characteristics. Trends run through the periodic table, with nonmetallic character (keeping their own electrons) increasing from left to right across a period, and from down to up across a group, and metallic character (surrendering electrons to other atoms) increasing in the opposite direction. The underlying reason for these trends is ...
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White Portland Cement
White Portland cement or white ordinary Portland cement (WOPC) is similar to ordinary, gray Portland cement in all aspects except for its high degree of whiteness. Obtaining this color requires substantial modification to the method of manufacture, and because of this, it is somewhat more expensive than the gray product. Uses White Portland cement is used in combination with white aggregates to produce white concrete for prestige construction projects and decorative work. White concrete usually takes the form of pre-cast cladding panels, since it is not economical to use white cement for structural purposes. White Portland cement is also used in combination with inorganic pigments to produce brightly colored concretes and mortars. Ordinary cement, when used with pigments, produces colors that may be attractive, but are somewhat dull. With white cement, bright reds, yellows and greens can be readily produced. Blue concrete can also be made, at some expense. The pigments may ...
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Loss On Ignition
Loss on ignition (LOI) is a test used in inorganic analytical chemistry and soil science, particularly in the analysis of minerals and the chemical makeup of soil. It consists of strongly heating ( "igniting") a sample of the material at a specified temperature, allowing volatile substances to escape, until its mass ceases to change. This may be done in air, or in some other reactive or inert atmosphere. The simple test typically consists of placing a few grams of the material in a tared, pre-ignited crucible and determining its mass, placing it in a temperature-controlled furnace for a set time, cooling it in a controlled (e.g. water-free, CO2-free) atmosphere, and redetermining the mass. The process may be repeated to show that mass-change is complete. A variant of the test in which mass-change is continually monitored as the temperature is changed, is thermogravimetry. Theory The loss on ignition is reported as part of an elemental or oxide analysis of a mineral. The volatile ...
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Fly Ash
Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK) plurale tantum: coal combustion residuals (CCRs)is a coal combustion product that is composed of the particulates (fine particles of burned fuel) that are driven out of coal-fired boilers together with the flue gases. Ash that falls to the bottom of the boiler's combustion chamber (commonly called a firebox) is called bottom ash. In modern coal-fired power plants, fly ash is generally captured by electrostatic precipitators or other particle filtration equipment before the flue gases reach the chimneys. Together with bottom ash removed from the bottom of the boiler, it is known as coal ash. Depending upon the source and composition of the coal being burned, the components of fly ash vary considerably, but all fly ash includes substantial amounts of silicon dioxide (SiO2) (both amorphous and crystalline), aluminium oxide (Al2O3) and calcium oxide (CaO), the main mineral compounds in coal-bearing rock strata. The u ...
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Bauxite
Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO(OH)), mixed with the two iron oxides goethite (FeO(OH)) and haematite (Fe2O3), the aluminium clay mineral kaolinite (Al2Si2O5(OH)4) and small amounts of anatase (TiO2) and ilmenite (FeTiO3 or FeO.TiO2). Bauxite appears dull in luster and is reddish-brown, white, or tan. In 1821, the French geologist Pierre Berthier discovered bauxite near the village of Les Baux in Provence, southern France. Formation Numerous classification schemes have been proposed for bauxite but, , there was no consensus. Vadász (1951) distinguished lateritic bauxites (silicate bauxites) from karst bauxite ores (carbonate bauxites): * The carbonate bauxites occur predominantly in Europe, Guyana, Suriname, and Jamaica above carbonate rocks (limestone and do ...
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Kaolin
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () octahedra. Rocks that are rich in kaolinite are known as kaolin () or china clay. Kaolin is occasionally referred to by the antiquated term lithomarge, from the Ancient Greek ''litho-'' and Latin ''marga'', meaning 'stone of marl'. Presently the name lithomarge can refer to a compacted, massive form of kaolin. The name ''kaolin'' is derived from Gaoling (), a Chinese village near Jingdezhen in southeastern China's Jiangxi Province. The name entered English in 1727 from the French version of the word: , following François Xavier d'Entrecolles's reports on the making of Jingdezhen porcelain. Kaolinite has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g). It is a soft, earthy, usu ...
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Millscale
Mill scale, often shortened to just scale, is the flaky surface of hot rolled steel, consisting of the mixed iron oxides iron(II) oxide (FeO), iron(III) oxide (), and iron(II,III) oxide (, magnetite). Mill scale is formed on the outer surfaces of plates, sheets or profiles when they are being produced by rolling red hot iron or steel billets in rolling mills. Mill scale is bluish-black in color. It is usually less than thick, and initially adheres to the steel surface and protects it from atmospheric corrosion provided no break occurs in this coating. Because it is electrochemically cathodic to steel, any break in the mill scale coating will cause accelerated corrosion of steel exposed at the break. Mill scale is thus a boon for a while until its coating breaks due to handling of the steel product or due to any other mechanical cause. Mill scale becomes a nuisance when the steel is to be processed. Any paint applied over it is wasted, since it will come off with the scale as ...
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