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Pozzolan
Pozzolans are a broad class of Silicon_dioxide, siliceous and aluminium oxide, aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2) at ordinary temperature to form compounds possessing cementitious properties. The quantification of the capacity of a pozzolan to react with calcium hydroxide and water is given by measuring its pozzolanic activity. ''Pozzolana'' are naturally occurring pozzolans of volcanic origin. History Mixtures of Calcination, calcined lime and finely ground, active aluminosilicate materials were pioneered and developed as inorganic binders in the Ancient world. Architectural remains of the Minoan civilization on Crete have shown evidence of the combined use of Calcium hydroxide, slaked lime and additions of finely ground potsherds for waterproof Cement render, renderings in baths, cisterns and aqueducts. Evidence o ...
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Pozzolana
Pozzolana or pozzuolana ( , ), also known as pozzolanic ash ( la, pulvis puteolanus), is a natural siliceous or siliceous- aluminous material which reacts with calcium hydroxide in the presence of water at room temperature (cf. pozzolanic reaction). In this reaction insoluble calcium silicate hydrate and calcium aluminate hydrate compounds are formed possessing cementitious properties. The designation pozzolana is derived from one of the primary deposits of volcanic ash used by the Romans in Italy, at Pozzuoli. The modern definition of pozzolana encompasses any volcanic material (pumice or volcanic ash), predominantly composed of fine volcanic glass, that is used as a pozzolan. Note the difference with the term pozzolan, which exerts no bearing on the specific origin of the material, as opposed to pozzolana, which can only be used for pozzolans of volcanic origin, primarily composed of volcanic glass. Historical use Pozzolanas such as Santorin earth were used in the Eastern Me ...
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Cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic, often lime or calcium silicate based, which can be characterized as hydraulic or the less common non-hydraulic, depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster). Hydraulic cements (e.g., Portland cement) set and become adhesive through a chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble and so are quite durable in wa ...
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Pozzolanic Activity
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, also ...
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Fly Ash
Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK) plurale tantum: coal combustion residuals (CCRs)is a coal combustion product that is composed of the particulates (fine particles of burned fuel) that are driven out of coal-fired boilers together with the flue gases. Ash that falls to the bottom of the boiler's combustion chamber (commonly called a firebox) is called bottom ash. In modern coal-fired power plants, fly ash is generally captured by electrostatic precipitators or other particle filtration equipment before the flue gases reach the chimneys. Together with bottom ash removed from the bottom of the boiler, it is known as coal ash. Depending upon the source and composition of the coal being burned, the components of fly ash vary considerably, but all fly ash includes substantial amounts of silicon dioxide (SiO2) (both amorphous and crystalline), aluminium oxide (Al2O3) and calcium oxide (CaO), the main mineral compounds in coal-bearing rock strata. The u ...
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Concrete
Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminum combined. Globally, the ready-mix concrete industry, the largest segment of the concrete market, is projected to exceed $600 billion in revenue by 2025. This widespread use results in a number of environmental impacts. Most notably, the production process for cement produces large volumes of greenhouse gas emissions, leading to net 8% of global emissions. Other environmental concerns include widespread illegal sand mining, impacts on the surrounding environment such as increased surface runoff or urban heat island effect, and potential public health implications from toxic ingredients. Significant research and development is ...
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Silica Fume
Silica fume, also known as microsilica, (CAS number 69012-64-2, EINECS number 273-761-1) is an amorphous (non-crystalline) polymorph of silicon dioxide, silica. It is an ultrafine powder collected as a by-product of the silicon and ferrosilicon alloy production and consists of spherical particles with an average particle diameter of 150 nm. The main field of application is as pozzolanic material for high performance concrete. It is sometimes confused with fumed silica (also known as pyrogenic silica, CAS number 112945-52-5). However, the production process, particle characteristics and fields of application of fumed silica are all different from those of silica fume. History The first testing of silica fume in Portland-cement-based concretes was carried out in 1952. The biggest drawback to exploring the properties of silica fume was a lack of material with which to experiment. Early research used an expensive additive called fumed silica, an amorphous form of silica made ...
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Trass
Trass is the local name of a volcanic tuff occurring in the Eifel, where it is worked for hydraulic mortar. It is a grey or cream-coloured fragmental rock, largely composed of pumiceous dust, and may be regarded as a trachytic tuff. It much resembles the Italian pozzolana and is applied to like purposes. Mixed with lime and sand, or with Portland cement, it is extensively employed for hydraulic work, especially in the Netherlands; while the compact varieties have been used as a building material and as a fire-stone in ovens. Trass was formerly worked extensively in the Brohl valley and is now obtained from the valley of the Nette, near Andernach. See also *Pozzolan *Pozzolana *Pozzolanic reaction *Pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular vol ... References Natural m ...
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Metakaolin
Metakaolin is the anhydrous calcined form of the clay mineral kaolinite. Minerals that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume. Kaolinite sources The quality and reactivity of metakaolin is strongly dependent of the characteristics of the raw material used. Metakaolin can be produced from a variety of primary and secondary sources containing kaolinite: * High purity kaolin deposits * Kaolinite deposits or tropical soils of lower purity * Paper sludge waste (if containing kaolinite) * Oil sand tailings (if containing kaolinite) Forming metakaolin The T-O clay mineral kaolinite does not contain interlayer cations or interlayer water. The temperature of dehydroxylation depends on the structural layer stacking order. Disordered kaolinite dehydroxylates between 530 and 570 °C, ordered kaolinite between 570 a ...
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Hydraulic Lime
Hydraulic lime (HL) is a general term for calcium oxide, a variety of lime also called quicklime, that sets by hydration. This contrasts with calcium hydroxide, also called slaked lime or air lime that is used to make lime mortar, the other common type of lime mortar, which sets by carbonation (re-absorbing carbon dioxide (CO2) from the air). Hydraulic lime provides a faster initial set and higher compressive strength than air lime, and hydraulic lime will set in more extreme conditions, including under water. The terms 'hydraulic lime' and 'hydrated lime' are quite similar and may be confused but are not necessarily the same material. Hydrated lime is any lime which has been slaked whether it sets through hydration, carbonation, or both. Calcium reacts in the lime kiln with the clay minerals to produce silicates that enable some of the lime to set through hydration. Any unreacted calcium is slaked to calcium hydroxide which sets through carbonation. These are sometimes called 's ...
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Slag
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-products of recovering non-ferrous materials like copper, nickel, zinc and phosphorus). Within these general categories, slags can be further categorized by their precursor and processing conditions (e.g., Blast furnace (BF) slags, air-cooled blast furnace (ACBF) slag, basic oxygen furnace (BOF) slag, and electric arc furnace (EAF) slag) . Due to the large demand for these materials, slag production has also significantly increased throughout the years despite recycling (most notably in the iron and steelmaking industries) and upcycling efforts. The World Steel Association (WSA) estimates that 600 kg of by-products (~90 wt% is slags) are generated per tonne of steel produced. Composition Slag is usually a mixture of metal oxides and sili ...
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Portland Cement
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th century by Joseph Aspdin, and is usually made from limestone. It is a fine powder, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker, and adding 2 to 3 percent of gypsum. Several types of portland cement are available. The most common, called ordinary portland cement (OPC), is grey, but white Portland cement is also available. Its name is derived from its resemblance to Portland stone which was quarried on the Isle of Portland in Dorset, England. It was named by Joseph Aspdin who obtained a patent for it in 1824. His son William Aspdin is regarded as the inventor of "modern" portland cement due to his developments in the 1840s. The low cost and widespread availability of the limestone, shales ...
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Vitruvius
Vitruvius (; c. 80–70 BC – after c. 15 BC) was a Roman architect and engineer during the 1st century BC, known for his multi-volume work entitled ''De architectura''. He originated the idea that all buildings should have three attributes: , , and ("strength", "utility", and "beauty"). These principles were later widely adopted in Roman architecture. His discussion of perfect proportion in architecture and the human body led to the famous Renaissance drawing of the ''Vitruvian Man'' by Leonardo da Vinci. Little is known about Vitruvius' life, but by his own descriptionDe Arch. Book 1, preface. section 2. he served as an artilleryman, the third class of arms in the Roman military offices. He probably served as a senior officer of artillery in charge of ''doctores ballistarum'' (artillery experts) and ''libratores'' who actually operated the machines. As an army engineer he specialized in the construction of ''ballista'' and '' scorpio'' artillery war machines for sieges. ...
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