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Pinitol
Pinitol is a cyclitol, a cyclic polyol. It is a known anti-diabetic agent isolated from ''Sutherlandia frutescens'' leaves. Gall plant tannins can be differentiated by their content of pinitol. It was first identified in the sugar pine (''Pinus lambertiana''). It is also found in other plants, such as in the pods of the carob tree. Certain variants of the bacteria ''Pseudomonas putida'' have been used in organic synthesis, the first example being the oxidation of benzene, employed by Steven Ley in the synthesis of (±)-pinitol. Glycosides Ciceritol is a pinitol digalactoside that can be isolated from seeds of chickpea, lentil and white lupin ''Lupinus albus'', commonly known as the white lupin or field lupine, is a member of the genus ''Lupinus'' in the family Fabaceae. It is a traditional pulse cultivated in the Mediterranean region. Description The white lupin is annual, more .... A cyclitol derivative can be found in the marine sponge '' Petrosia'' sp. Biosynthesis ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pinitol Biosynthesis
Pinitol is a cyclitol, a cyclic polyol. It is a known anti-diabetic agent isolated from ''Sutherlandia frutescens'' leaves. Gall plant tannins can be differentiated by their content of pinitol. It was first identified in the sugar pine ('' Pinus lambertiana''). It is also found in other plants, such as in the pods of the carob tree. Certain variants of the bacteria '' Pseudomonas putida'' have been used in organic synthesis, the first example being the oxidation of benzene, employed by Steven Ley in the synthesis of (±)-pinitol. Glycosides Ciceritol is a pinitol digalactoside that can be isolated from seeds of chickpea, lentil and white lupin. A cyclitol derivative can be found in the marine sponge ''Petrosia ''Petrosia'' is a genus of sponges belonging to the family Petrosiidae. The genus has almost cosmopolitan distribution In biogeography, cosmopolitan distribution is the term for the range of a taxon that extends across all or most of the wor ...'' sp. Biosy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclitol
In organic chemistry, a cyclitol is a cycloalkane containing at least three hydroxyl, each attached to a different ring carbon atom. The general formula for an unsubstituted cyclitol is or where 3 ≤ ''x'' ≤ ''n''. The name is also used for compounds that can be viewed as result of substituting various functional groups for the hydrogen atoms in such a molecule, as well as similar molecules with one or more double bonds in the ring. Cyclitols and their derivatives are some of the compatible solutes which are formed in a plant as a response to salt or water stress. Some cyclitols (e.g. quinic or shikimic acid) are parts of hydrolysable tannins. Isomerism and nomenclature Unsubstituted cyclitols with the same ring size and number of hydroxyls may exist in several structural isomers, depending on the position of the hydroxyls along the ring. For example, cyclohexanetriol exists in three distinct isomers (1,2,3-, 1,2,4-, and 1,3,5-). Furthermore, the hydrogen and the hydroxyl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
White Lupin
''Lupinus albus'', commonly known as the white lupin or field lupine, is a member of the genus '' Lupinus'' in the family Fabaceae. It is a traditional pulse cultivated in the Mediterranean region. Description The white lupin is annual, more or less pubescent plant, 30 to 120 cm high, has a wide distribution in the Mediterranean region. White lupine is widely spread as wild plants throughout the southern Balkans, the Italian mainland region of Apulia, the islands of Sicily, Corsica, and Sardinia, and the Aegean Sea, as well as in Lebanon, Israel, Palestine, and western Anatolia. It occurs in meadows, pastures, and grassy slopes, predominantly on sandy and acid soils. It is cultivated over all the Mediterranean region and also in Egypt, Sudan, Ethiopia, Syria, Central and Western Europe, USA and South America, Tropical and Southern Africa, Russia, and Ukraine. The ancient culture of white lupin under the local name "hanchcoly" was practiced until recently in We ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lentil
The lentil (''Lens culinaris'' or ''Lens esculenta'') is an edible legume. It is an annual plant known for its lens-shaped seeds. It is about tall, and the seeds grow in pods, usually with two seeds in each. As a food crop, the largest producer is Canada, producing 45% of the world’s total lentils. In cuisines of the Indian subcontinent, where lentils are a staple, split lentils (often with their hulls removed) known as dal are often cooked into a thick curry/gravy that is usually eaten with rice or '' rotis''. Botanical description Name Many different names in different parts of the world are used for the crop lentil. The first use of the word ''lens'' to designate a specific genus was in the 16th century by the botanist Tournefort. The word "lens" for the lentil is of classical Roman/Latin origin: McGee points out that a prominent Roman family took the name " Lentulus", just as the family name "Cicero" was derived from the chickpea, '' Cicer arietinum'', or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chickpea
The chickpea or chick pea (''Cicer arietinum'') is an annual legume of the family Fabaceae, subfamily Faboideae. Its different types are variously known as gram" or Bengal gram, garbanzo or garbanzo bean, or Egyptian pea. Chickpea seeds are high in protein. It is one of the earliest cultivated legumes, and 9500-year-old remains have been found in the Middle East. The chickpea is a key ingredient in Mediterranean and Middle Eastern cuisines, used in hummus, and, when ground into flour, falafel. It also is important in Indian cuisine, used in salads, soups and stews, and curry, in chana masala, and in other meal products like channa. In 2019, India was responsible for 70% of global chickpea production. Etymology The name "chickpea," earlier "chiche pease," is modelled on Middle French ', where ''chiche'' comes from Latin '. "Chich" was used by itself in English from the 14th to the 18th centuries.''Oxford English Dictionary'', 3rd edition, December 201''s.v.''/ref> The word ', fr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Digalactoside
A galactoside is a glycoside containing galactose. The H of the OH group on carbon-1 of galactose is replaced by an organic moiety. Depending on whether the glycosidic bond lies "above" or "below" the plane of the galactose molecule, galactosides are classified as α-galactosides or β-galactosides. A β-galactoside is a type of galactoside in which the glycosidic bond lies above the plane of the galactose residue. The most commonly recognized and used β-galactoside in biochemistry is lactose Lactose is a disaccharide sugar synthesized by galactose and glucose subunits and has the molecular formula C12H22O11. Lactose makes up around 2–8% of milk (by mass). The name comes from ' (gen. '), the Latin word for milk, plus the suffix '' - .... However, other chemicals, such as ONPG, are known, but these are typically synthesized for biochemical assays. Galactosides play significant roles in metabolic processes of many organisms and are hydrolyzed by a class of enzymes call ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ciceritol
Ciceritol is a cyclitol. It is a pinitol digalactoside that can be isolated from seeds of chickpea, lentil and white lupin ''Lupinus albus'', commonly known as the white lupin or field lupine, is a member of the genus ''Lupinus'' in the family Fabaceae. It is a traditional pulse cultivated in the Mediterranean region. Description The white lupin is annual, more .... References Cyclitols Galactosides {{organic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steven Ley
Steven Victor Ley (born 10 December 1945) is Professor of Organic Chemistry in the Department of Chemistry at the University of Cambridge, and is a Fellow of Trinity College, Cambridge. He was President of the Royal Society of Chemistry (2000–2002) and was made a CBE in January 2002, in the process. In 2011, he was included by ''The Times'' in the list of the "100 most important people in British science". Education Ley was educated at Stamford and Loughborough University of Technology where he was awarded a Bachelor of Science and PhD. Research Ley's main research field are the total synthesis of biomolecules. His group has published extensively on this topic, and has completed the synthesis of more than 140 natural target compounds, with notable examples including indanamycin, routiennocin, avermectin B1a, okadaic acid, spongistatin, thapsigargin, epothilone A, antascomicin B, bengazole A and rapamycin. His total synthesis of azadirachtin, completed in 2007, is widely reg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzene
Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon. Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline. It is used primarily as a precursor to the manufacture of chemicals with more complex structure, such as ethylbenzene and cumene, of which billions of kilograms are produced annually. Although benzene is a major industrial chemical, it finds limited use in consumer items because of its toxicity. History Discovery The word "''benzene''" derives from "''gum benzoin''" (benzoin res ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Synthesis
Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds. Organic molecules are often more complex than inorganic compounds, and their synthesis has developed into one of the most important branches of organic chemistry. There are several main areas of research within the general area of organic synthesis: ''total synthesis'', ''semisynthesis'', and ''methodology''. Total synthesis A total synthesis is the complete chemical synthesis of complex organic molecules from simple, commercially available petrochemical or natural precursors. Total synthesis may be accomplished either via a linear or convergent approach. In a ''linear'' synthesis—often adequate for simple structures—several steps are performed one after another until the molecule is complete; the chemical compounds made in each step are called synthetic intermediates. Most often, each step in a synthesis refers to a separate rea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pseudomonas Putida
''Pseudomonas putida'' is a Gram-negative, rod-shaped, saprotrophic soil bacterium. Based on 16S rRNA analysis, ''P. putida'' was taxonomically confirmed to be a ''Pseudomonas'' species (''sensu stricto'') and placed, along with several other species, in the ''P. putida'' group, to which it lends its name. However, phylogenomic analysis of complete genomes from the entire ''Pseudomonas'' genus clearly showed that the genomes that were named as ''P. putida'' did not form a monophyletic clade, but were dispersed and formed a wider evolutionary group (the putida group) that included other species as well, such as ''P. alkylphenolia, P. alloputida, P. monteilii, P. cremoricolorata, P. fulva, P. parafulva, P. entomophila, P. mosselii, P. plecoglossicida'' and several genomic species (new species which are currentely not validely defined as new species. A variety of ''P. putida'', called multiplasmid hydrocarbon-degrading ''Pseudomonas'', is the first patented organism in th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ceratonia Siliqua
The carob ( ; ''Ceratonia siliqua'') is a flowering evergreen tree or shrub in the Caesalpinioideae sub-family of the legume family, Fabaceae. It is widely cultivated for its edible fruit pods, and as an ornamental tree in gardens and landscapes. The carob tree is native to the Mediterranean region and the Middle East. Portugal is the largest producer of carob, followed by Italy and Morocco. In the Mediterranean Basin, extended to the southern Atlantic coast of Portugal (i.e. the Algarve region) and the Atlantic northwestern Moroccan coast, carob pods were often used as animal feed and in times of famine, as "the last source of umanfood in hard times". The ripe, dried, and sometimes toasted pod is often ground into carob powder, which was sometimes used as an ersatz cocoa powder, especially in the 1970s natural food movement. The powder and chips can be used as a chocolate alternative in most recipes. Description The carob tree grows up to tall. The crown is broad ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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