Pigment Yellow 13
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Pigment Yellow 13
Pigment Yellow 13 is an organic compound and an azo compound. It is a widely used yellow pigment. It is also classified as a diarylide pigment, being derived from 3,3'-dichlorobenzidine. It is closely related to Pigment Yellow 12 Pigment Yellow 12 is an organic compound and an azo compound. It is a widely used yellow pigment. It is also classified as a diarylide pigment, being derived from 3,3'-dichlorobenzidine. It is closely related to Pigment Yellow 13, wherein the t ..., wherein the two xylyl groups are replaced by phenyl.{{cite encyclopedia, authors=K. Hunger. W. Herbst , title=Pigments, Organic, encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry, publisher=Wiley-VCH, place=Weinheim, year=2012, doi=10.1002/14356007.a20_371, isbn=978-3527306732 References Pigments Organic pigments Shades of yellow Diarylide pigments ...
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Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living t ...
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Azo Compound
Azo compounds are organic compounds bearing the functional group diazenyl (, in which R and R′ can be either aryl or alkyl groups). IUPAC defines azo compounds as: "Derivatives of diazene (diimide), , wherein both hydrogens are substituted by hydrocarbyl groups, e.g. azobenzene or diphenyldiazene." The more stable derivatives contain two aryl groups. The group is called an ''azo group'' (, ). Many textile and leather articles are dyed with azo dyes and pigments. Aryl azo compounds Aryl azo compounds are usually stable, crystalline species. Azobenzene is the prototypical aromatic azo compound. It exists mainly as the ''trans'' isomer, but upon illumination, converts to the ''cis'' isomer. Aromatic azo compounds can be synthesized by azo coupling, which entails an electrophilic substitution reaction where an aryl diazonium cation is attacked by another aryl ring, especially those substituted with electron-donating groups: :ArN2+ + Ar'H -> ArN=NAr' + H+ Since diazoniu ...
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Diarylide Pigment
Diarylide pigments are organic compounds that are used as pigments in inks and related materials. They often are yellow or yellow-green. To some extent, these organic compounds have displaced cadmium sulfide from the market. They exist as yellow powders of low solubility in water.K. Hunger. W. Herbst "Pigments, Organic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim, 2012. Production The formation of these pigments involves the reaction of diazotized aromatic diamines (derivatives of benzidine) with coupling components, typically derivatives of acetoacetanilide. By varying both of these components, a wide variety of pigments have been produced. A related family of organic pigments are the simpler arylides, which arise from the coupling of monodiazonium salts with the same coupling partners. The molecular structures of these molecules is more conjugated than represented in the images shown below. The pigments' colors can range from yellow to ...
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3,3'-Dichlorobenzidine
3,3'-Dichlorobenzidine is an organic compound with the formula (C6H3Cl(NH2))2. The pure compound is pale yellow, but commercial samples are often colored. It is barely soluble in water and is often supplied as a wet paste. It is widely used in the production of diarylide yellow pigments used in the production of printing inks. Its use in the production of dyes has been largely discontinued because of concerns about carcinogenicity. Preparation and reactions 3,3'-Dichlorobenzidine is prepared in two steps from 2-nitrochlorobenzene. The first step involves reduction with zinc in base to afford 2,2'-dichlorodiphenylhydrazine. This intermediate undergoes the benzidine rearrangement to afford 3,3'-dichlorobenzidine. Aqueous solutions of 3,3'-dichlorobenzidine degrade in light to monochloro derivative. It undergoes chlorination (for example in water treatment plants) to give the tetrachloro derivative. The most widely practiced reaction of 3,3'-dichlorobenzidine is its double diazot ...
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Pigment Yellow 12
Pigment Yellow 12 is an organic compound and an azo compound. It is a widely used yellow pigment. It is also classified as a diarylide pigment, being derived from 3,3'-dichlorobenzidine. It is closely related to Pigment Yellow 13, wherein the two phenyl groups are replaced by 2,4-xylyl In organic chemistry, xylene or xylol (; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula . They are derived from the substitution of two hydrogen atoms with methyl groups in a benzene ring; which hydrogens are sub ....{{cite encyclopedia, authors=K. Hunger. W. Herbst , title=Pigments, Organic, encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry, publisher=Wiley-VCH, place=Weinheim, year=2012, doi=10.1002/14356007.a20_371, isbn=978-3527306732 References Pigments Organic pigments Shades of yellow Diarylide pigments ...
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Pigments
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compounds. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic, organic, and special pigments were marketed worldwide. Estimated at around US$14.86 billion in 2018 and will rise at over 4.9% CAGR from 2019 to 2026. The global demand for pigments was roughly US$20.5 billion in 2009. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each year. Physical principles Lik ...
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Organic Pigments
Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product of decay, or is composed of organic compounds * Organic compound, a compound that contains carbon ** Organic chemistry, chemistry involving organic compounds Farming, certification and products * Organic farming, agriculture conducted according to certain standards, especially the use of stated methods of fertilization and pest control * Organic certification, accreditation process for producers of organically-farmed products * Organic horticulture, the science and art of growing fruits, vegetables, flowers, or ornamental plants by following the essential principles of organic agriculture * Organic products, "organics": ** Organic food, food produced from organic farming methods and often certified organic according to organic farming sta ...
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Shades Of Yellow
Varieties of the color yellow may differ in hue, chroma (also called saturation, intensity, or colorfulness) or lightness (or value, tone, or brightness), or in two or three of these qualities. Variations in value are also called tints and shades, a tint being a yellow or other hue mixed with white, a shade being mixed with black. A large selection of these various colors is shown below. Computer web color yellow Yellow (RGB) (X11 yellow) (color wheel yellow) The color box at right shows the most intense yellow representable in 8-bit RGB color model; yellow is a ''secondary'' color in an additive RGB space. This color is also called color wheel yellow. It is at precisely 60 degrees on the HSV color wheel, also known as the RGB color wheel ( Image of RGB color wheel:). Its complementary color is blue. Yellow (CMYK) (process yellow) (canary yellow) Process yellow (also called pigment yellow or printer's yellow), also known as canary yellow, is one of the three co ...
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