Phase-change Material
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Phase-change Material
A phase change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat or cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other. The phase transition may also be between non-classical states of matter, such as the conformity of crystals, where the material goes from conforming to one crystalline structure to conforming to another, which may be a higher or lower energy state. The energy released/absorbed by phase transition from solid to liquid, or vice versa, the heat of fusion is generally much higher than the sensible heat. Ice, for example, requires 333.55 J/g to melt, but then water will rise one degree further with the addition of just 4.18 J/g. Water/ice is therefore a very useful phase change material and has been used to store winter cold to cool buildings in summer since at least the time of the Achaemenid Empire. By melting and soli ...
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Thermal Conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials like Rockwool or Styrofoam. Correspondingly, materials of high thermal conductivity are widely used in heat sink applications, and materials of low thermal conductivity are used as thermal insulation. The reciprocal of thermal conductivity is called thermal resistivity. The defining equation for thermal conductivity is \mathbf = - k \nabla T, where \mathbf is the heat flux, k is the thermal conductivity, and \nabla T is the temperature gradient. This is known as Fourier's Law for heat conduction. Although commonly expressed as a scalar, the most general form of th ...
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Cooling Tower
A cooling tower is a device that rejects waste heat to the atmosphere through the cooling of a coolant stream, usually a water stream to a lower temperature. Cooling towers may either use the evaporation of water to remove process heat and cool the working fluid to near the wet-bulb air temperature or, in the case of ''dry cooling towers'', rely solely on air to cool the working fluid to near the dry-bulb air temperature using radiators. Common applications include cooling the circulating water used in oil refineries, petrochemical and other chemical plants, thermal power stations, nuclear power stations and HVAC systems for cooling buildings. The classification is based on the type of air induction into the tower: the main types of cooling towers are natural draft and induced draft cooling towers. Cooling towers vary in size from small roof-top units to very large hyperboloid structures (as in the adjacent image) that can be up to tall and in diameter, or rectangu ...
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Chiller
A chiller is a machine that removes heat from a liquid coolant via a vapor-compression refrigeration, vapor-compression, adsorption refrigeration, or absorption refrigerator, absorption refrigeration cycles. This liquid can then be circulated through a heat exchanger to cool equipment, or another process stream (such as air or process water). As a necessary by-product, refrigeration creates waste heat that must be exhausted to ambience, or for greater efficiency, recovered for heating purposes. Vapor compression chillers may use any of a number of different types of compressors. Most common today are the hermetic scroll, semi-hermetic screw, or centrifugal compressors. The condensing side of the chiller can be either air or water cooled. Even when liquid cooled, the chiller is often cooled by an induced or forced draft cooling tower. Absorption and adsorption chillers require a heat source to function. Chilled water is used to Air conditioning, cool and dehumidify air in mid- to ...
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Steam Car
A steam car is a car (automobile) propelled by a steam engine. A steam engine is an external combustion engine (ECE) in which the fuel is combusted outside of the engine, unlike an internal combustion engine (ICE) in which fuel is combusted inside the engine. ECEs have a lower thermal efficiency, but carbon monoxide production is more readily regulated. Steam-powered automobiles were popular with early buyers. Steam was safe, reliable, and familiar. People had decades of experience with it in trains and boats, and even in experimental road vehicles. However, early steam cars required constant care and attention—and up to 30 minutes to start. Automated quick-firing boilers solved these problems, but not before more efficient gasoline engines dominated the market and made steam cars obsolete. The first experimental steam-powered cars were built in the 18th and 19th centuries, but it was not until after Richard Trevithick had developed the use of high-pressure steam around 1800 ...
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Amédée Bollée
Amédée-Ernest Bollée (11 January 1844 – 20 January 1917) was a French bellfounder and inventor who specialized in steam cars. After 1867 he was known as "Amédée père" to distinguish him from his similarly named son, Amédée-Ernest-Marie Bollée (1867–1926). Biography Bollée was the eldest son of Ernest-Sylvain Bollée, a bellfounder and inventor who moved to Le Mans in 1842. He became seriously ill in the 1860s and was obliged to delegate the day-to-day running of his businesses to his three sons. Amédée-Ernest was given charge of the bell foundry, while Ernest-Jules (1846–1922) supervised the hydraulic ram business and the youngest son, Auguste-Sylvain Bollée (1847–1906) assumed control of the ''Éolienne Bollée'' wind-turbine factory. Steam vehicles ''L'Obéissante'' Amédée père manufactured his first steam vehicle ''L'Obéissante'' (''The Obedient'') in 1873 and made the first road trip between Paris and Le Mans in 18 hours. The ''L'Obéissante' ...
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Richard Trevithick
Richard Trevithick (13 April 1771 – 22 April 1833) was a British inventor and mining engineer. The son of a mining captain, and born in the mining heartland of Cornwall, Trevithick was immersed in mining and engineering from an early age. He was an early pioneer of steam-powered road and rail transport, and his most significant contributions were the development of the first high-pressure steam engine and the first working railway steam locomotive. The world's first locomotive-hauled railway journey took place on 21 February 1804, when Trevithick's unnamed steam locomotive hauled a train along the tramway of the Penydarren Ironworks, in Merthyr Tydfil, Wales. Turning his interests abroad Trevithick also worked as a mining consultant in Peru and later explored parts of Costa Rica. Throughout his professional career he went through many ups and downs and at one point faced financial ruin, also suffering from the strong rivalry of many mining and steam engineers of the day. Durin ...
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Thermal Storage
Thermal energy storage (TES) is achieved with widely different technologies. Depending on the specific technology, it allows excess thermal energy to be stored and used hours, days, months later, at scales ranging from the individual process, building, multiuser-building, district, town, or region. Usage examples are the balancing of energy demand between daytime and nighttime, storing summer heat for winter heating, or winter cold for summer air conditioning (Seasonal thermal energy storage). Storage media include water or ice-slush tanks, masses of native earth or bedrock accessed with heat exchangers by means of boreholes, deep aquifers contained between impermeable strata; shallow, lined pits filled with gravel and water and insulated at the top, as well as eutectic solutions and phase-change materials. Other sources of thermal energy for storage include heat or cold produced with heat pumps from off-peak, lower cost electric power, a practice called peak shaving; heat fro ...
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Ionic Liquid
An ionic liquid (IL) is a salt in the liquid state. In some contexts, the term has been restricted to salts whose melting point is below a specific temperature, such as . While ordinary liquids such as water and gasoline are predominantly made of electrically neutral molecules, ionic liquids are largely made of ions. These substances are variously called liquid electrolytes, ionic melts, ionic fluids, fused salts, liquid salts, or ionic glasses. Ionic liquids have many potential applications. They are powerful solvents and can be used as electrolytes. Salts that are liquid at near-ambient temperature are important for electric battery applications, and have been considered as sealants due to their very low vapor pressure. Any salt that melts without decomposing or vaporizing usually yields an ionic liquid. Sodium chloride (NaCl), for example, melts at into a liquid that consists largely of sodium cations () and chloride anions (). Conversely, when an ionic liquid is cooled, ...
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Octadecane
Octadecane is an alkane hydrocarbon with the chemical formula CH3(CH2)16CH3. Properties Octadecane is distinguished by being the alkane with the lowest carbon number In organic chemistry, the carbon number of a compound is the number of carbon atoms in each molecule.Nava Dayan, Lambros Kromidas (ed.) ''Formulating, Packaging, and Marketing of Natural Cosmetic Products'' John Wiley & Sons, 2011; ; page 218 Th ... that is unambiguously solid at room temperature and pressure. References External links Phytochemical and Ethnobotanical Databases Alkanes {{hydrocarbon-stub ...
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Alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane () or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula , and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote ''any'' saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes) or ...
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Ester
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. Nitrate esters, such as nitroglycerin, are known for their explosive properties. '' Nomenclature Etymology Th ...
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