Paul Lebeau
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Paul Lebeau
Paul Marie Alfred Lebeau (19 December 1868 – 18 November 1959) was a French chemist. He studied at the elite École supérieure de physique et de chimie industrielles de la ville de Paris (ESPCI). Together with his doctoral advisor Henri Moissan he was working on fluorine chemistry discovering several new compounds, like bromine trifluoride, oxygen difluoride, selenium tetrafluoride and sulfur hexafluoride. In 1899 he was able to obtain pure beryllium by electrolysis sodium fluoroberyllate (Na2 eF2. In World War I he improved the gas mask design used by the French army The French Army, officially known as the Land Army (french: Armée de Terre, ), is the land-based and largest component of the French Armed Forces. It is responsible to the Government of France, along with the other components of the Armed For .... References * 1868 births 1959 deaths 20th-century French chemists ESPCI Paris alumni Commandeurs of the Légion d'honneur Members of the French ...
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Boiscommun
Boiscommun () is a commune in the Loiret department in north-central France. Population See also *Communes of the Loiret department The following is the list of the 325 communes of the Loiret department of France. The communes cooperate in the following intercommunalities (as of 2020):Communes of Loiret {{Loiret-geo-stub ...
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Beryllium
Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form minerals. Notable gemstones high in beryllium include beryl ( aquamarine, emerald) and chrysoberyl. It is a relatively rare element in the universe, usually occurring as a product of the spallation of larger atomic nuclei that have collided with cosmic rays. Within the cores of stars, beryllium is depleted as it is fused into heavier elements. Beryllium constitutes about 0.0004 percent by mass of Earth's crust. The world's annual beryllium production of 220 tons is usually manufactured by extraction from the mineral beryl, a difficult process because beryllium bonds strongly to oxygen. In structural applications, the combination of high flexural rigidity, thermal stability, thermal conductivity and low density (1.85 times that of water) ma ...
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ESPCI Paris Alumni
ESPCI Paris (officially the École supérieure de physique et de chimie industrielles de la Ville de Paris; ''The City of Paris Industrial Physics and Chemistry Higher Educational Institution'') is a prestigious grande école founded in 1882 by the city of Paris, France. It educates undergraduate and graduate students in physics, chemistry and biology and conducts high-level research in those fields. It is ranked as the first French ''École d'Ingénieurs'' in the 2017 Shanghai Ranking. ESPCI Paris is a constituent college of Université PSL and a founding member of the ParisTech (Paris Institute of Technology) alliance. 5 researchers and alumni from ESPCI Paris have been awarded the Nobel Prize: * Pierre and Marie Curie (Physics, 1903), * Marie Curie - second Nobel Prize (Chemistry, 1911), * Frédéric Joliot-Curie (Chemistry, 1935), * Pierre-Gilles de Gennes (Physics, 1991), * Georges Charpak (Physics, 1992). Two thirds of the students enter the School following a competit ...
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1959 Deaths
Events January * January 1 - Cuba: Fulgencio Batista flees Havana when the forces of Fidel Castro advance. * January 2 - Lunar probe Luna 1 was the first man-made object to attain escape velocity from Earth. It reached the vicinity of Earth's Moon, and was also the first spacecraft to be placed in heliocentric orbit. * January 3 ** The three southernmost atolls of the Maldive Islands, Maldive archipelago (Addu Atoll, Huvadhu Atoll and Fuvahmulah island) United Suvadive Republic, declare independence. ** Alaska is admitted as the 49th U.S. state. * January 4 ** In Cuba, rebel troops led by Che Guevara and Camilo Cienfuegos enter the city of Havana. ** Léopoldville riots: At least 49 people are killed during clashes between the police and participants of a meeting of the ABAKO Party in Kinshasa, Léopoldville in the Belgian Congo. * January 6 ** Fidel Castro arrives in Havana. ** The International Maritime Organization is inaugurated. * January 7 – The United States reco ...
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1868 Births
Events January–March * January 2 – British Expedition to Abyssinia: Robert Napier leads an expedition to free captive British officials and missionaries. * January 3 – The 15-year-old Mutsuhito, Emperor Meiji of Japan, declares the ''Meiji Restoration'', his own restoration to full power, under the influence of supporters from the Chōshū and Satsuma Domains, and against the supporters of the Tokugawa shogunate, triggering the Boshin War. * January 5 – Paraguayan War: Brazilian Army commander Luís Alves de Lima e Silva, Duke of Caxias enters Asunción, Paraguay's capital. Some days later he declares the war is over. Nevertheless, Francisco Solano López, Paraguay's president, prepares guerrillas to fight in the countryside. * January 7 – The Arkansas constitutional convention meets in Little Rock. * January 9 – Penal transportation from Britain to Australia ends, with arrival of the convict ship ''Hougoumont'' in Western Aus ...
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French Army
The French Army, officially known as the Land Army (french: Armée de Terre, ), is the land-based and largest component of the French Armed Forces. It is responsible to the Government of France, along with the other components of the Armed Forces. The current Chief of Staff of the French Army (CEMAT) is General , a direct subordinate of the Chief of the Defence Staff (CEMA). General Schill is also responsible to the Ministry of the Armed Forces for organization, preparation, use of forces, as well as planning and programming, equipment and Army future acquisitions. For active service, Army units are placed under the authority of the Chief of the Defence Staff (CEMA), who is responsible to the President of France for planning for, and use of forces. All French soldiers are considered professionals, following the suspension of French military conscription, voted in parliament in 1997 and made effective in 2001. , the French Army employed 118,600 personnel (including the Fo ...
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World War I
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fighting occurring throughout Europe, the Middle East, Africa, the Pacific, and parts of Asia. An estimated 9 million soldiers were killed in combat, plus another 23 million wounded, while 5 million civilians died as a result of military action, hunger, and disease. Millions more died in genocides within the Ottoman Empire and in the 1918 influenza pandemic, which was exacerbated by the movement of combatants during the war. Prior to 1914, the European great powers were divided between the Triple Entente (comprising France, Russia, and Britain) and the Triple Alliance (containing Germany, Austria-Hungary, and Italy). Tensions in the Balkans came to a head on 28 June 1914, following the assassination of Archduke Franz Ferdin ...
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Sulfur Hexafluoride
Sulfur hexafluoride or sulphur hexafluoride (British spelling) is an inorganic compound with the formula SF6. It is a colorless, odorless, non- flammable, and non-toxic gas. has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. Typical for a nonpolar gas, is poorly soluble in water but quite soluble in nonpolar organic solvents. It has a density of 6.12 g/L at sea level conditions, considerably higher than the density of air (1.225 g/L). It is generally transported as a liquefied compressed gas. is 23,500 times more potent than as a greenhouse gas but exists in relatively minor concentrations in the atmosphere. Its concentration in Earth's troposphere reached 10.63 parts per trillion (ppt) in 2021, rising at 0.39 ppt/year. The increase over the prior 40 years was driven in large part by the expanding electric power sector, including fugitive emissions from banks of gas contained in its med ...
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France
France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pacific and Indian Oceans. Its Metropolitan France, metropolitan area extends from the Rhine to the Atlantic Ocean and from the Mediterranean Sea to the English Channel and the North Sea; overseas territories include French Guiana in South America, Saint Pierre and Miquelon in the North Atlantic, the French West Indies, and many islands in Oceania and the Indian Ocean. Due to its several coastal territories, France has the largest exclusive economic zone in the world. France borders Belgium, Luxembourg, Germany, Switzerland, Monaco, Italy, Andorra, and Spain in continental Europe, as well as the Kingdom of the Netherlands, Netherlands, Suriname, and Brazil in the Americas via its overseas territories in French Guiana and Saint Martin (island), ...
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Selenium Tetrafluoride
Selenium tetrafluoride ( Se F4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas. Synthesis The first reported synthesis of selenium tetrafluoride was by Paul Lebeau in 1907, who treated selenium with fluorine: :Se + 2 F2 → SeF4 A synthesis involving more easily handled reagents entails the fluorination of selenium dioxide with sulfur tetrafluoride: :SF4 + SeO2 → SeF4 + SO2 An intermediate in this reaction is seleninyl fluoride (SeOF2). Other methods of preparation include fluorinating elemental selenium with chlorine trifluoride: :3 Se + 4 ClF3 → 3 SeF4 + 2 Cl2 Structure and bonding Selenium in SeF4 has an oxidation state of +4. Its shape in the gaseous phase is similar to that of SF4 ...
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Oxygen Difluoride
Oxygen difluoride is a chemical compound with the formula . As predicted by VSEPR theory, the molecule adopts a "bent" molecular geometry. It is strong oxidizer and has attracted attention in rocketry for this reason. With a boiling point of -144.75 °C, OF2 is the most volatile (isolable) triatomic compound. Preparation Oxygen difluoride was first reported in 1929; it was obtained by the electrolysis of molten potassium fluoride and hydrofluoric acid containing small quantities of water. The modern preparation entails the reaction of fluorine with a dilute aqueous solution of sodium hydroxide, with sodium fluoride as a side-product: : Structure and bonding Its powerful oxidizing properties are suggested by the oxidation number of +2 for the oxygen atom instead of its normal −2. Reactions Above 200 °C, decomposes to oxygen and fluorine by a radical mechanism. : reacts with many metals to yield oxides and fluorides. Nonmetals also react: phosphorus reacts with to form ...
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