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Protoactinium
Protactinium (formerly protoactinium) is a chemical element with the symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds in which protactinium is usually present in the oxidation state +5, but it can also assume +4 and even +3 or +2 states. Concentrations of protactinium in the Earth's crust are typically a few parts per trillion, but may reach up to a few parts per million in some uraninite ore deposits. Because of its scarcity, high radioactivity and high toxicity, there are currently no uses for protactinium outside scientific research, and for this purpose, protactinium is mostly extracted from spent nuclear fuel. The element was first identified in 1913 by Kazimierz Fajans and Oswald Helmuth Göhring and named ''brevium'' because of the short half-life of the specific isotope studied, i.e. protactinium-234. A more stable isotope of protactinium, 231Pa, ...
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Actinide
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Since ''actinoid'' literally means ''actinium-like'' (cf. ''humanoid'' or ''android''), it has been argued for semantic reasons that actinium cannot logically be an actinoid, but IUPAC acknowledges its inclusion based on common usage. All the actinides are f-block elements, except the final one (lawrencium) which is a d-block element. Actinium has sometimes been considered d-block instead of lawrencium, but the class ...
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Lise Meitner
Elise Meitner ( , ; 7 November 1878 – 27 October 1968) was an Austrian-Swedish physicist who was one of those responsible for the discovery of the element protactinium and nuclear fission. While working at the Kaiser Wilhelm Institute on radioactivity, she discovered the radioactive isotope protactinium-231 in 1917. In 1938, Meitner and her nephew, the physicist Otto Robert Frisch, discovered nuclear fission. She was praised by Albert Einstein as the "German Marie Curie". Completing her doctoral research in 1905, Meitner became the second woman from the University of Vienna to earn a doctorate in physics. She spent most of her scientific career in Berlin, Germany, where she was a physics professor and a department head at the Kaiser Wilhelm Institute; she was the first woman to become a full professor of physics in Germany. She lost these positions in the 1930s because of the anti-Jewish Nuremberg Laws of Nazi Germany, and in 1938 she fled to Sweden, where she lived for many ...
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Oswald Helmuth Göhring
Oswald Helmuth Göhring, also known as Otto Göhring, (1889 - 1915) was a German chemist who, with his teacher Kasimir Fajans, co-discovered the chemical element protactinium in 1913. Discovery of protactinium Protactinium was first identified in 1913 by Kasimir Fajans and Oswald Helmuth Göhring at the University of Karlsruhe. The new element was called brevium due to the short half-life of the isotope specific studied, Protactinium-234 (234 Pa). Fajans and Göhring also worked to identify as many isotopes of the new element as possible, and also to publicize their discovery—a process that was hampered by the onset of World War I. In 1914, Göhring was conscripted into the army. Presumably he perished during the war; he is listed as the author of no further scientific articles or publications after 1915. A stable isotope of this element was discovered in 1918, and thus the name was changed to protoactinium, and then in 1949 to its present name, protactinium. Publications ...
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Chemical Element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler substances by any chemical reaction. The number of protons in the nucleus is the defining property of an element, and is referred to as its atomic number (represented by the symbol ''Z'') – all atoms with the same atomic number are atoms of the same element. Almost all of the baryonic matter of the universe is composed of chemical elements (among rare exceptions are neutron stars). When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds. Only a minority of elements, such as silver and gold, are found uncombined as relatively pure native element minerals. Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is primarily a mixture o ...
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University Of Glasgow
, image = UofG Coat of Arms.png , image_size = 150px , caption = Coat of arms Flag , latin_name = Universitas Glasguensis , motto = la, Via, Veritas, Vita , mottoeng = The Way, The Truth, The Life , established = , type = Public research universityAncient university , endowment = £225.2 million , budget = £809.4 million , rector = Rita Rae, Lady Rae , chancellor = Dame Katherine Grainger , principal = Sir Anton Muscatelli , academic_staff = 4,680 (2020) , administrative_staff = 4,003 , students = () , undergrad = () , postgrad = () , city = Glasgow , country = Scotland, UK , colours = , website = , logo ...
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Frederick Soddy
Frederick Soddy FRS (2 September 1877 – 22 September 1956) was an English radiochemist who explained, with Ernest Rutherford, that radioactivity is due to the transmutation of elements, now known to involve nuclear reactions. He also proved the existence of isotopes of certain radioactive elements. In 1921 he received the Nobel Prize in Chemistry "for his contributions to our knowledge of the chemistry of radioactive substances, and his investigations into the origin and nature of isotopes". Soddy was a polymath who mastered chemistry, nuclear physics, statistical mechanics, finance and economics. Biography Soddy was born at 6 Bolton Road, Eastbourne, England, the son of Benjamin Soddy, corn merchant, and his wife Hannah Green. He went to school at Eastbourne College, before going on to study at University College of Wales at Aberystwyth and at Merton College, Oxford, where he graduated in 1898 with first class honours in chemistry. He was a researcher at Oxford from 189 ...
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Ada Hitchins
Ada Florence Remfry Hitchins (26 June 1891 – 4 January 1972) was the principal research assistant of British chemist Frederick Soddy, who won the Nobel prize in 1921 for work on radioactive elements and the theory of isotopes. Hitchins isolated samples from uranium ores, taking precise and accurate measurements of atomic mass that provided the first experimental evidence for the existence of different isotopes. She also helped to discover the element protactinium, which Dmitri Mendeleev had predicted should occur in the periodic table between uranium and thorium. Education Ada Hitchins was born on 26 June 1891 in Tavistock, Devon, England, the daughter of William Hedley Hitchins, a supervisor of customs and excise, and his wife Annie Sarah Pearsons. The family lived for a time in Campbeltown, Scotland, where Hitchins attended high school, graduating in 1909. From there, she went to the University of Glasgow, obtaining her bachelor's degree in science, with honors, in 1913. ...
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First World War
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fighting occurring throughout Europe, the Middle East, Africa, the Pacific, and parts of Asia. An estimated 9 million soldiers were killed in combat, plus another 23 million wounded, while 5 million civilians died as a result of military action, hunger, and disease. Millions more died in genocides within the Ottoman Empire and in the 1918 influenza pandemic, which was exacerbated by the movement of combatants during the war. Prior to 1914, the European great powers were divided between the Triple Entente (comprising France, Russia, and Britain) and the Triple Alliance (containing Germany, Austria-Hungary, and Italy). Tensions in the Balkans came to a head on 28 June 1914, following the assassination of Archduke Franz Ferdina ...
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Nuclear Isomer
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state, higher energy levels than in the ground state of the same nucleus. "Metastable" describes nuclei whose excited states have Half-life, half-lives 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half life (ordinarily on the order of 10−12 seconds). The term "metastable" is usually restricted to isomers with half-lives of 10−9 seconds or longer. Some references recommend 5 × 10−9 seconds to distinguish the metastable half life from the normal "prompt" Induced gamma emission, gamma-emission half-life. Occasionally the half-lives are far longer than this and can last minutes, hours, or years. For example, the Isotopes of tantalum#Tantalum-180m, nuclear isomer survives so long (at least 1015 years) that it has never been observed to decay spontaneously. The half-life of a nuclear isomer can eve ...
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Uranium-235
Uranium-235 (235U or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nature as a primordial nuclide. Uranium-235 has a half-life of 703.8 million years. It was discovered in 1935 by Arthur Jeffrey Dempster. Its fission cross section for slow thermal neutrons is about 584.3±1 barns. For fast neutrons it is on the order of 1 barn. Most but not all neutron absorptions result in fission; a minority result in neutron capture forming uranium-236. Natural decay chain :\begin \ce \begin \ce \\ \ce \end \ce \\ \ce \begin \ce \\ \ce \end \ce \end Fission properties The fission of one atom of uranium-235 releases () inside the reactor. That corresponds to 19.54 TJ/ mol, or 83.14 TJ/kg.
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Actinium
Actinium is a chemical element with the symbol Ac and atomic number 89. It was first isolated by Friedrich Oskar Giesel in 1902, who gave it the name ''emanium''; the element got its name by being wrongly identified with a substance André-Louis Debierne found in 1899 and called actinium. Actinium gave the name to the actinide series, a group of 15 similar elements between actinium and lawrencium in the periodic table. Together with polonium, radium, and radon, actinium was one of the first non-primordial radioactive elements to be isolated. A soft, silvery-white radioactive metal, actinium reacts rapidly with oxygen and moisture in air forming a white coating of actinium oxide that prevents further oxidation. As with most lanthanides and many actinides, actinium assumes oxidation state +3 in nearly all its chemical compounds. Actinium is found only in traces in uranium and thorium ores as the isotope 227Ac, which decays with a half-life of 21.772 years, predominantly e ...
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Uranium-238
Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is ''fertile'', meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control. Around 99.284% of natural uranium's mass is uranium-238, which has a half-life of 1.41 seconds (4.468 years, or 4.468 billion years). Due to its natural abundance and half-life relative to other radioactive elements, 238U produces ~40% of the radioactive heat produced within th ...
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