Procyanidin B5
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Procyanidin B5
Procyanidin B5 is a B type proanthocyanidin. Procyanidin B5 is an epicatechin-(4β → 6)-epicatechin dimer. Natural occurrences It can be found in grape seeds, in '' Hibiscus cannabinus'' (kenaf) root and bark, and in black chokeberries (''Aronia melanocarpa ''Aronia melanocarpa'', called the black chokeberry, is a species of shrubs in the rose family native to eastern North America, ranging from Canada to the central United States, from Newfoundland west to Ontario and Minnesota, south as far as ...''). ; Presence in food It is found in cocoa beans and chocolate.Rapid Reversed Phase Ultra-Performance Liquid Chromatography Analysis of the Major Cocoa Polyphenols and Inter-relationships of Their Concentrations in Chocolate. Karen A. Cooper, Esther Campos-Gimenez, Diego Jimenez-Alvarez, Kornel Nagy, Jennifer L. Donovan and Gary Williamson, J. Agric. Food Chem., 2007, 55, pages 2841−2847, References Procyanidin dimers Chocolate {{Aromatic-stub ...
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B Type Proanthocyanidin
B type proanthocyanidins are a specific type of proanthocyanidin, which are a class of flavanoids. They are oligomers of flavan-3-ols. Dimeric B type proanthocyanidins These molecules have the molecular formula C30H26O12 (molar mass : 578.52 g/mol, exact mass : 578.142426). Molecules with 4→8 bonds The 4-8 bond can be in the alpha or in the beta position. * Procyanidin B1 or epicatechin-(4β→8)-catechin * Procyanidin B2 or (−)-epicatechin-(4β→8)-(−)-epicatechin * Procyanidin B3 or catechin-(4α→8)-catechin * Procyanidin B4 or catechin-(4α→8)-epicatechin Molecules with 4→6 bonds * Procyanidin B5 or epicatechin-(4β→6)-epicatechin * Procyanidin B6 or catechin-(4α→6)-catechin * Procyanidin B8 or catechin-(4α→6)-epicatechin Chemistry B-type procyanidin (catechin dimer) can be converted to A-type procyanidin by radical oxidation. Dimeric proanthocyanidins can also be synthesized with procyanidin-rich grape seed extracts reacted with flavan-3-ol ...
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Epicatechin
Catechin is a flavan-3-ol, a type of secondary metabolite providing antioxidant roles in plants. It belongs to the subgroup of polyphenols called flavonoids. The name of the catechin chemical family derives from ''catechu'', which is the tannic juice or boiled extract of ''Mimosa catechu'' (''Acacia catechu'' L.f). Chemistry Catechin possesses two benzene rings (called the A- and B-rings) and a dihydropyran heterocycle (the C-ring) with a hydroxyl group In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy g ... on carbon 3. The A-ring is similar to a resorcinol moiety while the B-ring is similar to a catechol moiety. There are two chirality (chemistry), chiral centers on the molecule on carbons 2 and 3. Therefore, it has four diastereoisomers. Two of the isomers are in trans configura ...
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Hibiscus Cannabinus
Kenaf tymology: Persian ''Hibiscus cannabinus'', is a plant in the family Malvaceae also called Deccan hemp and Java jute. ''Hibiscus cannabinus'' is in the genus ''Hibiscus'' and is native to Africa, though its exact origin is unknown. The name also applies to the fibre obtained from this plant. Kenaf is one of the allied fibres of jute and shows similar characteristics. Common names *Europe: **English: Deccan hemp, Java jute, wild stockrose ** French: chanvre de Bombay, chanvre du Deccan, chanvre de Guinée, chanvre de Gambo, chanvre de roselle, jute de Java, jute de Siam, kénaf, ketmie à feuilles de chanvre (Belgium), roselle **German: Ambari, Dekkanhanf, Gambohanf, Hanfeibisch, Javajute, Kenaf, Rosellahanf, Roselle, Siamjute **Portuguese: cânhamo rosella, juta-de-java, juta-do-sião, quenafe **Spanish: cáñamo de la India, cáñamo de gambo, cáñamo Rosella, pavona encendida, yute de Java, yute de Siam *Americas: **Brazilian Portuguese: papoula-de-são-francisco, cânh ...
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Aronia Melanocarpa
''Aronia melanocarpa'', called the black chokeberry, is a species of shrubs in the rose family native to eastern North America, ranging from Canada to the central United States, from Newfoundland west to Ontario and Minnesota, south as far as Arkansas, Alabama, and Georgia. This plant has been introduced and is cultivated in Europe. It is a branching shrub with glossy dark green leaves that take on a red color in the autumn; it grows well in the sun and part-shade, often to heights of six feet or more, forming clumps by means of stems rising from the roots. Its flowers are white or pink, appearing at the end of spring and producing black fruits in September. The plants are relatively easy to clone and root, with summer being the optimal time to take cuttings. Some birds eat the berries. When raw, the fruits are astringent An astringent (sometimes called adstringent) is a chemical that shrinks or constricts body tissues. The word derives from the Latin ''adstringere'', which ...
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Procyanidin Dimers
Proanthocyanidin dimers are a specific type of proanthocyanidin, which are a class of flavanoids. They are oligomers of flavan-3-ols. * Dimeric B-type proanthocyanidins * Dimeric A-type proanthocyanidin A type proanthocyanidins are a specific type of proanthocyanidins, which are a class of flavonoid. Proanthocyanidins fall under a wide range of names in the nutritional and scientific vernacular, including oligomeric proanthocyanidins, flavonoids, ...s {{Chemistry index Dimers ...
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