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Pressure Oxidation
Pressure oxidation is a process for extracting gold from refractory ore. The most common refractory ores are pyrite and arsenopyrite, which are sulfide ores that trap the gold within them. Refractory ores require pre-treatment before the gold can be adequately extracted. The pressure oxidation process is used to prepare such ores for conventional gold extraction processes such as cyanidation. It is performed in an autoclave at high pressure and temperature, where high-purity oxygen mixes with a slurry of ore. When the original sulfide minerals are oxidized at high temperature and pressure, it completely releases the trapped gold. Pressure oxidation has a very high gold recovery rate, normally at least 10% higher than roasting. The oxidation of the iron sulfide minerals produces sulfuric acid, soluble compounds such as ferric sulfate, and solids such as iron sulfate or jarosite. The iron-based solids produced pose an environmental challenge, as they can release acid and heav ...
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Gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile metal in a pure form. Chemically, gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements and is solid under standard conditions. Gold often occurs in free elemental ( native state), as nuggets or grains, in rocks, veins, and alluvial deposits. It occurs in a solid solution series with the native element silver (as electrum), naturally alloyed with other metals like copper and palladium, and mineral inclusions such as within pyrite. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides). Gold is resistant to most acids, though it does dissolve in aqua regia (a mixture of nitric acid and hydrochloric acid), forming a soluble tetrachloroaurate anion. Gold is ...
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Gold Extraction
Gold extraction refers to the processes required to extract gold from its ores. The great majority of gold is extracted from dilute ores using a combination of chemical processes. About 2000 tons are obtained from the earth annually, plus another 300 tons from recycling. Types of ore Gold occurs principally as a native metal, i.e., gold itself. Sometimes it is alloyed to a greater or lesser extent with silver, which is called electrum. Native gold can occur as sizeable nuggets, as fine grains or flakes in alluvial deposits, or as grains or microscopic particles (known as colour) embedded in rock minerals. Other forms of gold are the minerals calaverite (AuTe), aurostibnite (AuSb2), and maldonite (Au2Bi). These latter three, although rarer that native gold, can be slow to react with cyanide and thus difficult to process. Still other gold-containing ores include various tellurides ( sylvanite, nagyagite, petzite, and krennerite). Certain contaminants in ores can interfere wit ...
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Pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), luster and pale brass-yellow hue give it a superficial resemblance to gold, hence the well-known nickname of ''fool's gold''. The color has also led to the nicknames ''brass'', ''brazzle'', and ''Brazil'', primarily used to refer to pyrite found in coal. The name ''pyrite'' is derived from the Greek language, Greek (), 'stone or mineral which strikes fire', in turn from (), 'fire'. In ancient Roman times, this name was applied to several types of stone that would create sparks when struck against steel; Pliny the Elder described one of them as being brassy, almost certainly a reference to what we now call pyrite. By Georgius Agricola's time, , the term had become a generic term for all of the pyrite group, sulfide minerals. Pyrite is usua ...
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Arsenopyrite
Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite which can lead to acid mine drainage. The crystal habit, hardness, density, and garlic odour when struck are diagnostic. Arsenopyrite in older literature may be referred to as ''mispickel'', a name of German origin. Arsenopyrite also can be associated with significant amounts of gold. Consequently, it serves as an indicator of gold bearing reefs. Many arsenopyrite gold ores ...
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Gold Cyanidation
Gold cyanidation (also known as the cyanide process or the MacArthur-Forrest process) is a hydrometallurgical technique for extracting gold from low-grade ore by converting the gold to a water-soluble coordination complex. It is the most commonly used leaching process for gold extraction. Cyanidation is also widely used in the extraction of silver, usually after froth flotation. Production of reagents for mineral processing to recover gold represents more than 70% of cyanide consumption globally. Other metals are recovered from the process include copper, zinc, and silver, but gold is the main driver of this technology. Due to the highly poisonous nature of cyanide, the process is controversial and its use is even banned in some parts of the world. Cyanide can be safely used in the gold mining industry. A key feature for safe use of cyanide is to ensure adequate pH control at an alkaline pH level above 10.5. At industrial scale, pH control is mainly achieved using lime, as an ...
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Autoclave (industrial)
An autoclave is a machine used to carry out industrial and scientific processes requiring elevated temperature and pressure in relation to ambient pressure and/or temperature. Autoclaves are used before surgical procedures to perform sterilization and in the chemical industry to cure coatings and vulcanize rubber and for hydrothermal synthesis. Industrial autoclaves are used in industrial applications, especially in the manufacturing of composites. Many autoclaves are used to sterilize equipment and supplies by subjecting them to pressurized saturated steam at for around 30-60 minutes at a pressure of 15 psi (103 kPa or 1.02 atm) depending on the size of the load and the contents. The autoclave was invented by Charles Chamberland in 1879, although a precursor known as the steam digester was created by Denis Papin in 1679. The name comes from Greek ''auto-'', ultimately meaning self, and Latin ''clavis'' meaning key, thus a self-locking device. Uses Sterilization autoclav ...
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Roasting (metallurgy)
Roasting is a process of heating a sulfide ore to a high temperature in the presence of air. It is a step in the processing of certain ores. More specifically, roasting is often a metallurgical process involving gas–solid reactions at elevated temperatures with the goal of purifying the metal component(s). Often before roasting, the ore has already been partially purified, e.g. by froth flotation. The concentrate is mixed with other materials to facilitate the process. The technology is useful in making certain ores usable but it can also be a serious source of air pollution. Roasting consists of thermal gas–solid reactions, which can include oxidation, reduction, chlorination, sulfation, and pyrohydrolysis. In roasting, the ore or ore concentrate is treated with very hot air. This process is generally applied to sulfide minerals. During roasting, the sulfide is converted to an oxide, and sulfur is released as sulfur dioxide, a gas. For the ores Cu2S (chalcocite) and ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released may boi ...
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Jarosite
Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments. Physical properties Jarosite has a trigonal crystal structure and is brittle, with basal cleavage, a hardness of 2.5-3.5, and a specific gravity of 3.15-3.26. It is translucent to opaque with a vitreous to dull luster, and is colored dark yellow to yellowish-brown. It can sometimes be confused with limonite or goethite with which it commonly occurs in the gossan (oxidized cap over an ore body). Jarosite is an iron analogue of the potassium aluminium sulfate, alunite. Solid solution series The alunite supergroup includes the alunite, jarosite, beudantite, crandallite and florencite subgroups. The aluni ...
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Scorodite
Scorodite is a common hydrated iron arsenate mineral, with the chemical formula FeAsO4·2H2O. It is found in hydrothermal deposits and as a secondary mineral in gossans worldwide. Scorodite weathers to limonite. Scorodite was discovered in the Schwarzenberg, Saxony district, Erzgebirge, Saxony, Germany. Named from the Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ... ''Scorodion'', "garlicky". When heated it smells of garlic, which gives it the name. References Further reading * Palache, C., H. Berman, and C. Frondel (1951) Dana's system of mineralogy, (7th edition), v. II, pp. 763–767 External links Webmineral dataMineral Da ...
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Pueblo Viejo Mine
The Pueblo Viejo mine is a gold mine located in the north-central region of the Dominican Republic in the Sánchez Ramírez Province. It is the largest gold mine in Latin America and fifth largest in the world. It is also the first exploited mine by the Spaniards in America. The mine produced 581,000 ounces of gold in 2018 and 6.55 million ounces of gold in reserve. The mine, run by the Pueblo Viejo Dominicana Corporation, is 60% owned by Barrick Gold and 40% owned by Newmont Goldcorp Newmont Corporation is a gold mining company based in Greenwood Village, Colorado, United States. It is the world's largest gold mining corporation. Incorporated in 1921, it owns gold mines in Nevada, Colorado, Ontario, Quebec, Mexico, the Domin .... It was formerly operated by the Dominican mining group Rosario Dominicana, S. A., which had exploited Pueblo Viejo from 1975 to 1999 when it went bankrupt. Gold is recovered from the ore using a pressure oxidation process, performed in four autoclave ...
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Dominican Republic
The Dominican Republic ( ; es, República Dominicana, ) is a country located on the island of Hispaniola in the Greater Antilles archipelago of the Caribbean region. It occupies the eastern five-eighths of the island, which it shares with Haiti, making Hispaniola one of only two Caribbean islands, along with Saint Martin, that is shared by two sovereign states. The Dominican Republic is the second-largest nation in the Antilles by area (after Cuba) at , and third-largest by population, with approximately 10.7 million people (2022 est.), down from 10.8 million in 2020, of whom approximately 3.3 million live in the metropolitan area of Santo Domingo, the capital city. The official language of the country is Spanish. The native Taíno people had inhabited Hispaniola before the arrival of Europeans, dividing it into five chiefdoms. They had constructed an advanced farming and hunting society, and were in the process of becoming an organized civilization. The Taínos also in ...
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