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Potassium Dithionite
Potassium dithionite or potassium hydrosulfite is a potassium salt of dithionous acid. The compound has UN number UN 1929. As a dithionite, it is closely related to sodium dithionite, which is a commonly used reducing agent and bleaching agent Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to .... See also * List of UN numbers 1901 to 2000 References Dithionites Potassium compounds {{inorganic-compound-stub ...
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Dithionous Acid
Dithionous acid is a sulfur oxoacid with the chemical formula H2S2O4. It is unstable in pure form, but its salts, known as dithionites, are stable. It was initially assumed that the ''C''2 symmetric structure HOS(=O)-S(=O)OH is the most stable among molecules with the formula using ab initio calculations. The reason for this is the existence of intermolecular hydrogen bonds. It is now known that dithionous acid spontaneously decomposes to SO2 and S(OH)2. Sodium dithionite is a white powder used as a reductant and a bleaching agent. It is also used to reduce the nitro group to an amino group In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent such a ... in organic reactions. References Sulfur oxoacids Dithionites {{inorganic-compound-stub ...
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UN Number
A UN number (United Nations number) is a four-digit number that identifies hazardous materials, and articles (such as explosives, flammable liquids, oxidizers, toxic liquids, etc.) in the framework of international trade and transport. Some hazardous substances have their own UN numbers (e.g. acrylamide has UN 2074), while sometimes groups of chemicals or products with similar properties receive a common UN number (e.g. flammable liquids, not otherwise specified, have UN 1993). A chemical in its solid state may receive a different UN number than the liquid phase if its hazardous properties differ significantly; substances with different levels of purity (or concentration in solution) may also receive different UN numbers. Hazard identifiers Associated with each UN number is a hazard identifier, which encodes the general hazard class and subdivision (and, in the case of explosives, their compatibility group). If a substance poses several dangers, then subsidiary risk identifiers ma ...
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Sodium Dithionite
Sodium dithionite (also known as sodium hydrosulfite) is a white crystalline powder with a sulfurous odor. Although it is stable in dry air, it decomposes in hot water and in acid solutions. Structure The structure has been examined by Raman spectroscopy and single-crystal X-ray diffraction. The dithionite dianion has C symmetry, with almost eclipsed with a 16° O-S-S-O torsional angle. In the dihydrated form (), the dithionite anion has gauche 56° O-S-S-O torsional angle. A weak S-S bond is indicated by the S-S distance of 239 pm, which is elongated by ca. 30 pm relative to a typical S-S bond. Because this bond is fragile, the dithionite anion dissociates in solution into the O2sup>− radicals, as has been confirmed by EPR spectroscopy. It is also observed that 35S undergoes rapid exchange between S2O42− and SO2 in neutral or acidic solution, consistent with the weak S-S bond in the anion. Preparation Sodium dithionite is produced industrially by reduction of sulfur d ...
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Reducing Agent
In chemistry, a reducing agent (also known as a reductant, reducer, or electron donor) is a chemical species that "donates" an electron to an (called the , , , or ). Examples of substances that are commonly reducing agents include the Earth metals, formic acid, oxalic acid, and sulfite compounds. In their pre-reaction states, reducers have extra electrons (that is, they are by themselves reduced) and oxidizers lack electrons (that is, they are by themselves oxidized). This is commonly expressed in terms of their oxidation states. An agent's oxidation state describes its degree of loss of electrons, where the higher the oxidation state then the fewer electrons it has. So initially, prior to the reaction, a reducing agent is typically in one of its lower possible oxidation states; its oxidation state increases during the reaction while that of the oxidizer decreases. Thus in a redox reaction, the agent whose oxidation state increases, that "loses/Electron donor, donates electrons ...
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Bleaching Agent
Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to a dilute solution of sodium hypochlorite, also called "liquid bleach". Many bleaches have broad spectrum bactericidal properties, making them useful for disinfecting and sterilizing. They are used in swimming pool sanitation to control bacteria, viruses, and algae, and in many places where sterile conditions are required. They are also used in many industrial processes, notably in the bleaching of wood pulp. Bleaches also have other minor uses like removing mildew, killing weeds, and increasing the longevity of cut flowers. Bleaches work by reacting with many colored organic compounds, such as natural pigments, and turning them into colorless ones. While most bleaches are oxidizing agents (chemicals that can remove electrons from other ...
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