Porod's Law
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Porod's Law
In X-ray or neutron small-angle scattering (SAS), Porod's law, discovered by Günther Porod, describes the asymptote of the scattering intensity ''I(q)'' for large scattering wavenumbers ''q''. Context Porod's law is concerned with wave numbers ''q'' that are small compared to the scale of usual Bragg diffraction; typically q\lesssim1\text^. In this range, the sample must not be described at an atomistic level; one rather uses a continuum description in terms of an electron density or a neutron scattering length density. In a system composed of distinct mesoscopic particles, all small-angle scattering can be understood as arising from surfaces or interfaces. Normally, SAS is measured in order to detect correlations between different interfaces, and in particular, between remote surface segments of one and the same particle. This allows conclusions about the size and shape of the particles, and their correlations. Porod's ''q'' is relatively large on the usual scale of SAS. In thi ...
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Small-angle Scattering
Small-angle scattering (SAS) is a scattering technique based on deflection of collimated radiation away from the straight trajectory after it interacts with structures that are much larger than the wavelength of the radiation. The deflection is small (0.1-10°) hence the name ''small-angle''. SAS techniques can give information about the size, shape and orientation of structures in a sample. SAS is a powerful technique for investigating large-scale structures from 10 Å up to thousands and even several tens of thousands of angstroms. The most important feature of the SAS method is its potential for analyzing the inner structure of disordered systems, and frequently the application of this method is a unique way to obtain direct structural information on systems with random arrangement of density inhomogeneities in such large-scales. Currently, the SAS technique, with its well-developed experimental and theoretical procedures and wide range of studied objects, is a self-contained b ...
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Günther Porod
Günther Porod (; 1919 in Faak am See near Villach – 1984 in Graz) was an Austrian physicist. He is best known for his work on the small-angle X-ray scattering method, done in collaboration with his teacher Otto Kratky, and in particular for Porod's law, which describes the asymptote of the scattering intensity ''I(q)'' for large scattering wave numbers ''q''. In polymer physics, the worm-like chain model, introduced in a 1949 paper, is sometimes called the Kratky–Porod model. In 1965 Porod was appointed as professor of experimental physics at the university of Graz. In 1978, he was awarded the Erwin Schrödinger-Preis. See also *Lyman G. Parratt Lyman G. Parratt (May 17, 1908 - June 29, 1995) was an American physicist. He is known for various research using x-rays. Parratt was born in Salt Lake City. In 1954, Parratt used x-rays to explore the surface of copper-coated glass, thereby creat ..., American x-ray physicist with somewhat similar name. References {{ ...
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Wavenumber
In the physical sciences, the wavenumber (also wave number or repetency) is the ''spatial frequency'' of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). It is analogous to temporal frequency, which is defined as the number of wave cycles per unit time (''ordinary frequency'') or radians per unit time (''angular frequency''). In multidimensional systems, the wavenumber is the magnitude of the ''wave vector''. The space of wave vectors is called ''reciprocal space''. Wave numbers and wave vectors play an essential role in optics and the physics of wave scattering, such as X-ray diffraction, neutron diffraction, electron diffraction, and elementary particle physics. For quantum mechanical waves, the wavenumber multiplied by the reduced Planck's constant is the ''canonical momentum''. Wavenumber can be used to specify quantities other than spatial frequency. For example, in optical spectroscopy, it is often used ...
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Bragg Diffraction
In physics and chemistry , Bragg's law, Wulff–Bragg's condition or Laue–Bragg interference, a special case of Laue diffraction, gives the angles for coherent scattering of waves from a crystal lattice. It encompasses the superposition of wave fronts scattered by lattice planes, leading to a strict relation between wavelength and scattering angle, or else to the wavevector transfer with respect to the crystal lattice. Such law had initially been formulated for X-rays upon crystals. However, It applies to all sorts of quantum beams, including neutron and electron waves at atomic distances, as well as visible light at artificial periodic microscale lattices. History Bragg diffraction (also referred to as the Bragg formulation of X-ray diffraction) was first proposed by Lawrence Bragg and his father, William Henry Bragg, in 1913 in response to their discovery that crystalline solids produced surprising patterns of reflected X-rays (in contrast to that of, say, a liquid). They ...
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Surface Roughness
Surface roughness, often shortened to roughness, is a component of surface finish (surface texture). It is quantified by the deviations in the direction of the normal vector of a real surface from its ideal form. If these deviations are large, the surface is rough; if they are small, the surface is smooth. In surface metrology, roughness is typically considered to be the high-frequency, short-wavelength component of a measured surface. However, in practice it is often necessary to know both the amplitude and frequency to ensure that a surface is fit for a purpose. Roughness plays an important role in determining how a real object will interact with its environment. In tribology, rough surfaces usually wear more quickly and have higher friction coefficients than smooth surfaces. Roughness is often a good predictor of the performance of a mechanical component, since irregularities on the surface may form nucleation sites for cracks or corrosion. On the other hand, roughness may pr ...
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Fresnel Equations
The Fresnel equations (or Fresnel coefficients) describe the reflection and transmission of light (or electromagnetic radiation in general) when incident on an interface between different optical media. They were deduced by Augustin-Jean Fresnel () who was the first to understand that light is a transverse wave, even though no one realized that the "vibrations" of the wave were electric and magnetic fields. For the first time, polarization could be understood quantitatively, as Fresnel's equations correctly predicted the differing behaviour of waves of the ''s'' and ''p'' polarizations incident upon a material interface. Overview When light strikes the interface between a medium with refractive index ''n''1 and a second medium with refractive index ''n''2, both reflection and refraction of the light may occur. The Fresnel equations give the ratio of the ''reflected'' wave's electric field to the incident wave's electric field, and the ratio of the ''transmitted'' wave's electri ...
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Fractal
In mathematics, a fractal is a geometric shape containing detailed structure at arbitrarily small scales, usually having a fractal dimension strictly exceeding the topological dimension. Many fractals appear similar at various scales, as illustrated in successive magnifications of the Mandelbrot set. This exhibition of similar patterns at increasingly smaller scales is called self-similarity, also known as expanding symmetry or unfolding symmetry; if this replication is exactly the same at every scale, as in the Menger sponge, the shape is called affine self-similar. Fractal geometry lies within the mathematical branch of measure theory. One way that fractals are different from finite geometric figures is how they scale. Doubling the edge lengths of a filled polygon multiplies its area by four, which is two (the ratio of the new to the old side length) raised to the power of two (the conventional dimension of the filled polygon). Likewise, if the radius of a filled sphere i ...
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Surface Fractal
A fractal landscape is a surface that is generated using a stochastic algorithm designed to produce fractal behavior that mimics the appearance of natural terrain. In other words, the result of the procedure is not a deterministic fractal surface, but rather a random surface that exhibits fractal behavior. Many natural phenomena exhibit some form of statistical self-similarity that can be modeled by Fractal_dimension#Fractal_surface_structures, fractal surfaces.''Advances in multimedia modeling: 13th International Multimedia Modeling'' by Tat-Jen Cham 2007 pag/ref> Moreover, variations in surface texture provide important visual cues to the orientation and slopes of surfaces, and the use of almost self-similar fractal patterns can help create natural looking visual effects. The modeling of the Earth's rough surfaces via fractional Brownian motion was first proposed by Benoit Mandelbrot. Because the intended result of the process is to produce a landscape, rather than a mathemati ...
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Volume Fractal
Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial units, imperial or United States customary units, US customary units (such as the gallon, quart, cubic inch). The definition of length (cubed) is interrelated with volume. The volume of a container is generally understood to be the capacity of the container; i.e., the amount of fluid (gas or liquid) that the container could hold, rather than the amount of space the container itself displaces. In ancient times, volume is measured using similar-shaped natural containers and later on, standardized containers. Some simple Three dimensional, three-dimensional shapes can have its volume easily calculated using arithmetic formulas. Volumes of more complicated shapes can be calculated with integral calculus if a formula exists for the shape's boundary. Zero-dimensional space, Zero-, One-dimensional space, one- and tw ...
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Ostrogradsky's Theorem
In vector calculus, the divergence theorem, also known as Gauss's theorem or Ostrogradsky's theorem, reprinted in is a theorem which relates the ''flux'' of a vector field through a closed surface (mathematics), surface to the ''divergence'' of the field in the volume enclosed. More precisely, the divergence theorem states that the surface integral of a vector field over a closed surface, which is called the "flux" through the surface, is equal to the volume integral of the divergence over the region inside the surface. Intuitively, it states that "the sum of all sources of the field in a region (with sinks regarded as negative sources) gives the net flux out of the region". The divergence theorem is an important result for the mathematics of physics and engineering, particularly in electrostatics and fluid dynamics. In these fields, it is usually applied in three dimensions. However, it Generalization, generalizes to any number of dimensions. In one dimension, it is equivalen ...
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Small-angle Scattering
Small-angle scattering (SAS) is a scattering technique based on deflection of collimated radiation away from the straight trajectory after it interacts with structures that are much larger than the wavelength of the radiation. The deflection is small (0.1-10°) hence the name ''small-angle''. SAS techniques can give information about the size, shape and orientation of structures in a sample. SAS is a powerful technique for investigating large-scale structures from 10 Å up to thousands and even several tens of thousands of angstroms. The most important feature of the SAS method is its potential for analyzing the inner structure of disordered systems, and frequently the application of this method is a unique way to obtain direct structural information on systems with random arrangement of density inhomogeneities in such large-scales. Currently, the SAS technique, with its well-developed experimental and theoretical procedures and wide range of studied objects, is a self-contained b ...
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