|
Plutonium(III) Chloride
Plutonium(III) chloride is a chemical compound with the formula PuCl3. This ionic plutonium salt can be prepared by reacting the metal with hydrochloric acid. Structure Plutonium atoms in crystalline PuCl3 are 9 coordinate, and the structure is tricapped trigonal prismatic. It crystallizes as the trihydrate, and forms lavender-blue solutions in water.John H. Burns, J. R. Peterson, J. N. Stevenson: "Crystallographic Studies of some Transuranic Trihalides: 239PuCl3, 244CmBr3, 249BkBr3 and 249CfBr3", ''Journal of Inorganic and Nuclear Chemistry'' 1975, ''37 (3)'', 743–749; . Safety As with all plutonium compounds, it is subject to control under the Nuclear Non-Proliferation Treaty The Treaty on the Non-Proliferation of Nuclear Weapons, commonly known as the Non-Proliferation Treaty or NPT, is an international treaty whose objective is to prevent the spread of nuclear weapons and weapons technology, to promote cooperation .... Due to the radioactivity of plutonium, all o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium Tetrachloride
Plutonium is a radioactive decay, radioactive chemical element with the Symbol (chemistry), symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating plutonium(IV) oxide, when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoricity, pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a Deuterium, deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which subsequently Beta decay, beta-decayed to form th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium Tribromide
Plutonium(III) bromide is an inorganic salt of bromine and plutonium with the formula PuBr3. This radioactive green solid has few uses, however its crystal structure is often used as a structural archetype in crystallography. Crystal structure The PuBr3 crystal structure was first published in 1948 by William Houlder Zachariasen. The compound forms orthorhombic crystals, a type of square antiprism, within which the Pu atoms adopt an 8-coordinate bicapped trigonal prismatic arrangement. Its Pearson symbol is oS16 with the corresponding space group No. 63 (in International Union of Crystallography classification) or Cmcm (in Hermann–Mauguin notation In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann (who introduced it in 1928) and the French mineralogis ...). The majority of trivalent chloride and bromide salts of lanthanide and actini ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Samarium(III) Chloride
Samarium(III) chloride, also known as samarium trichloride, is an inorganic compound of samarium and chloride. It is a pale yellow salt that rapidly absorbs water to form a hexahydrate, SmCl3.6H2O. The compound has few practical applications but is used in laboratories for research on new compounds of samarium. Structure Like several related chlorides of the lanthanides and actinides, SmCl3 crystallises in the UCl3 motif. The Sm3+ centres are nine-coordinate, occupying trigonal prismatic sites with additional chloride ligands occupying the three square faces. Preparation and reactions SmCl3 is prepared by the " ammonium chloride" route, which involves the initial synthesis of (NH4)2 mCl5 This material can be prepared from the common starting materials at reaction temperatures of 230 °C from samarium oxide: ::10 NH4Cl + Sm2O3 → 2 (NH4)2 mCl5 + 6 NH3 + 3 H2O The pentachloride is then heated to 350-400 °C resulting in evolution of ammonium chloride and leaving ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a proton, H+, and an anion, A-. The dissociation of a strong acid in solution is effectively complete, except in its most concentrated solutions .... It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. History In the early tenth century, the Persian physician and alchemist Abu Bakr al-Razi ( 865–925, Latin: Rhazes) conducted experiments with sal ammoniac (ammonium chloride) and vitriol (hydrated sulfates of various metals), which he distilled together, thus producing the gas hydrogen chloride. In doing so, al-Razi may have stumbled upon a primitive method ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 ( half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tricapped Trigonal Prismatic
In chemistry, the tricapped trigonal prismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triaugmented triangular prism (a trigonal prism with an extra atom attached to each of its three rectangular faces). It is very similar to the capped square antiprismatic molecular geometry In chemistry, the capped square antiprismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a gyroelongated square pyramid. The gyro ..., and there is some dispute over the specific geometry exhibited by certain molecules. Examples * is usually considered to have a tricapped trigonal prismatic geometry, although its geometry is sometimes described as capped square antiprismatic instead. * (Ln = La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy) * {{MolecularGeometry Stere ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Journal Of Inorganic And Nuclear Chemistry
''Polyhedron'' is a peer-reviewed scientific journal covering the field of inorganic chemistry. It was established in 1955 as the ''Journal of Inorganic and Nuclear Chemistry'' and is published by Elsevier. Abstracting and indexing ''Polyhedron'' is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2020 impact factor The impact factor (IF) or journal impact factor (JIF) of an academic journal is a scientometric index calculated by Clarivate that reflects the yearly mean number of citations of articles published in the last two years in a given journal, as i ... of 3.052. References External links * {{Official Website, http://www.journals.elsevier.com/polyhedron/ Inorganic chemistry journals Elsevier academic journals Publications established in 1955 English-language journals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 ( half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Non-Proliferation Treaty
The Treaty on the Non-Proliferation of Nuclear Weapons, commonly known as the Non-Proliferation Treaty or NPT, is an international treaty whose objective is to prevent the spread of nuclear weapons and weapons technology, to promote cooperation in the peaceful uses of nuclear energy, and to further the goal of achieving nuclear disarmament and general and complete disarmament. Between 1965 and 1968, the treaty was negotiated by the Eighteen Nation Committee on Disarmament, a United Nations-sponsored organization based in Geneva, Switzerland. Opened for signature in 1968, the treaty entered into force in 1970. As required by the text, after twenty-five years, NPT Parties met in May 1995 and agreed to extend the treaty indefinitely. More countries are parties to the NPT than any other arms limitation and disarmament agreement, a testament to the treaty's significance. As of August 2016, 191 states have become parties to the treaty, though North Korea, which acceded in 1985 but nev ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium(III) Compounds
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since urani ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Materials
Nuclear material refers to the metals uranium, plutonium, and thorium, in any form, according to the IAEA. This is differentiated further into "source material", consisting of natural and depleted uranium, and "special fissionable material", consisting of enriched uranium (U-235), uranium-233, and plutonium-239. Uranium ore concentrates are considered to be a "source material", although these are not subject to safeguards under the Nuclear Non-Proliferation Treaty. According to the Nuclear Regulatory Commission(NRC), there are four different types of regulated nuclear materials: special nuclear material, source material, byproduct material and radium. Special nuclear materials have plutonium, uranium-233 or uranium with U233 or U235 that has a content found more than in nature. Source material is thorium or uranium that has a U235 content equal to or less than what is in nature. Byproduct material is radioactive material that is not source or special nuclear material. It can be a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chlorides
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167 pm) is much larger than ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
