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Plutonium(III) Bromide
Plutonium(III) bromide is an inorganic salt of bromine and plutonium with the formula PuBr3. This radioactive green solid has few uses, however its crystal structure is often used as a structural archetype in crystallography. Crystal structure The PuBr3 crystal structure was first published in 1948 by William Houlder Zachariasen. The compound forms orthorhombic crystals, a type of square antiprism, within which the Pu atoms adopt an 8-coordinate bicapped trigonal prismatic arrangement. Its Pearson symbol is oS16 with the corresponding space group No. 63 (in International Union of Crystallography classification) or Cmcm (in Hermann–Mauguin notation In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann (who introduced it in 1928) and the French mineralogis ...). The majority of trivalent chloride and bromide salts of lanthanide and acti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexahydrate
In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understood. Chemical nature Inorganic chemistry Hydrates are inorganic salts "containing water molecules combined in a definite ratio as an integral part of the crystal" that are either bound to a metal center or that have crystallized with the metal complex. Such hydrates are also said to contain ''water of crystallization'' or ''water of hydration''. If the water is heavy water in which the constituent hydrogen is the isotope deuterium, then the term ''deuterate'' may be used in place of ''hydrate''. A colorful example is cobalt(II) chloride, which turns from blue to red upon hydration, and can therefore be used as a water indicator. The notation "''hydrated compound''⋅''n''", where ''n'' is the number of water molecules per formula un ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromine
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek (bromos) meaning "stench", referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a native element in nature but it occurs in colourless soluble crystalline mineral halide salts, analogous to table salt. In fact, bromine and all the halogens are so reactive that they form bonds in pairs—never in single atoms. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Commercial ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 ( half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of Three-dimensional space (mathematics), three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive Translation (geometry), translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of the crystal are described by the con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystallography
Crystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics (condensed matter physics). The word "crystallography" is derived from the Greek word κρύσταλλος (''krystallos'') "clear ice, rock-crystal", with its meaning extending to all solids with some degree of transparency, and γράφειν (''graphein'') "to write". In July 2012, the United Nations recognised the importance of the science of crystallography by proclaiming that 2014 would be the International Year of Crystallography. denote a direction vector (in real space). * Coordinates in ''angle brackets'' or ''chevrons'' such as <100> denote a ''family'' of directions which are related by symmetry operations. In the cubic crystal system for example, would mean 00 10 01/nowiki> or the negative of any of those directions. * Miller indices in ''parentheses'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Houlder Zachariasen
William Houlder Zachariasen (5 February 1906 – 24 December 1979), more often known as W. H. Zachariasen, was a Norwegian-American physicist, specializing in X-ray crystallography and famous for his work on the structure of glass. Background Zachariasen was born in Langesund at Bamble in Telemark, Norway. He entered the University of Oslo in 1923, where he studied in the Mineralogical Institute. Zachariasen published his first article in 1925 when he was 19 years old, after having presented the contents of the article to the Norwegian Academy of Sciences in the preceding year. Over a span of 55 years he published over 200 scientific papers, many of which he was the sole author. In 1928 at the age of 22 he earned his PhD from the University of Oslo, becoming the youngest person ever to receive a PhD in Norway. His thesis advisor was the famous geochemist Victor Moritz Goldschmidt. In the years 1928–1929, as a postdoctoral fellow at Manchester University in the laboratory of Si ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bicapped Trigonal Prismatic
In chemistry, the bicapped trigonal prismatic molecular geometry describes the shape of compounds where eight atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a biaugmented triangular prism. This shape has C2v symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the square antiprism and the dodecahedron.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications It is very similar to the square antiprismatic molecular geometry, and there is some dispute over the specific geometry exhibited by certain molecules. One example of the bicapped trigonal prismatic molecular geometry is the ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven .... References ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pearson Symbol
The Pearson symbol, or Pearson notation, is used in crystallography as a means of describing a crystal structure, and was originated by W. B. Pearson. The symbol is made up of two letters followed by a number. For example: * Diamond structure, ''cF''8 * Rutile structure, ''tP''6 The two (italicised) letters specify the Bravais lattice. The lower-case letter specifies the crystal family, and the upper-case letter the centering type. The number at the end of the Pearson symbol gives the number of the atoms in the conventional unit cell.Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005 IR-3.4.4, pp. 49–51; IR-11.5, pp. 241–242. |
Hermann–Mauguin Notation
In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann (who introduced it in 1928) and the French mineralogist Charles-Victor Mauguin (who modified it in 1931). This notation is sometimes called international notation, because it was adopted as standard by the ''International Tables For Crystallography'' since their first edition in 1935. The Hermann–Mauguin notation, compared with the Schoenflies notation, is preferred in crystallography because it can easily be used to include translational symmetry elements, and it specifies the directions of the symmetry axes. Point groups Rotation axes are denoted by a number ''n'' — 1, 2, 3, 4, 5, 6, 7, 8 ... (angle of rotation ''φ'' = ). For improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, that shows rotation-reflection axes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plutonium(III) Compounds
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since urani ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Actinide Halides
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC nomenclature of inorganic chemistry, IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Since ''actinoid'' literally means ''actinium-like'' (cf. ''humanoid'' or ''android''), it has been argued for semantic reasons that actinium cannot logically be an actinoid, but IUPAC acknowledges its inclusion based on common usage. All the actinides are f-block elements, except the final one (lawrencium) which is a d-block element. Actinium has sometimes been considered d-b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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