|
Petroselinic Acid
Petroselinic acid is a fatty acid that occurs naturally in several animal and vegetable fats and oils. It is a white powder and is commercially available. In chemical terms, petroselinic acid is classified as a monounsaturated omega-12 fatty acid, abbreviated with a lipid number of 18:1 cis-6. It has the formula CH3(CH2)10CH=CH(CH2)4COOH. The term "petroselinic" means related to, or derived from, oil of ''Petroselinum'', parsley. Despite its name, petroselinic acid does not contain any selenium. Petroselinic acid is a positional isomer of oleic acid. Occurrence Petroselinic was first isolated from parsley seed oil in 1909. Petroselinic acid occurs in high amounts in plants in Apiaceae, Araliaceae, Griselinia (Griseliniaceae) and in Garryaceae. In Picramniaceae, petroselinic acid is accompanied by tariric acid. In addition, petroselinic acid has been found in minor amounts in several fats of plant and animal origin, including in human sources. The occurrence of petroselinic ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methanol
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a light, volatile, colourless, flammable liquid with a distinctive alcoholic odour similar to that of ethanol (potable alcohol). A polar solvent, methanol acquired the name wood alcohol because it was once produced chiefly by the destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide. Methanol consists of a methyl group linked to a polar hydroxyl group. With more than 20 million tons produced annually, it is used as a precursor to other commodity chemicals, including formaldehyde, acetic acid, methyl tert-butyl ether, methyl benzoate, anisole, peroxyacids, as well as a host of more specialised chemicals. Occurrence Small amounts of methanol are present in normal, healthy hu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Griselinia
''Griselinia'' is a genus of seven species of shrubs and trees, with a highly disjunct distribution native to New Zealand and South America. It is a classic example of the Antarctic flora. It is the sole genus in the family Griseliniaceae; in the past it was often placed in Cornaceae but differs from that in many features. Description Small dioecious trees or shrubs up to 20 m with erect branches, or shrubs up to 2 m with climbing or scandent branches. The leaves are evergreen, thick and leathery, smooth and glossy above, often paler below. The flowers are very small, with five sepals and stamens and a single stigma, borne on terminal or axillary racemes or panicles. Petals 2–3 mm long. However, the female flower of ''G.lucida'' has no petals. The fruit is a small red or purple oval berry 5–10 mm long. Chemical characteristics Petroselinic acid occurs as the major fatty acid in the species, indicating a relationship to the Apiaceae and the Araliaceae ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Argentation Chromatography
Argentation chromatography is chromatography using a stationary phase that contains silver salts. Silver-containing stationary phases are well suited for separating organic compounds on the basis of the number and type of alkene groups. The technique is employed for gas chromatography and various types of liquid chromatography, including thin layer chromatography Thin-layer chromatography (TLC) is a chromatography technique used to separate non-volatile mixtures. Thin-layer chromatography is performed on a sheet of an inert substrate such as glass, plastic, or aluminium foil, which is coated with a t .... Analytes containing alkene groups elute more slowly that the analogous compounds lacking alkenes. Separations are also sensitive to the type of alkene. The technique is especially useful in the analysis of fats and fatty acids, which are well known to exist in both saturated and unsaturated (alkene-containing) forms. Theory Silver ions form alkene complexes. The binding ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gas Chromatography
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. In preparative chromatography, GC can be used to prepare pure compounds from a mixture. Gas chromatography is also sometimes known as vapor-phase chromatography (VPC), or gas–liquid partition chromatography (GLPC). These alternative names, as well as their respective abbreviations, are frequently used in scientific literature. Gas chromatography is the process of separating compounds in a mixture by injecting a gaseous or liquid sample into a mobile phase, typically called the carrier gas, and passing the gas through a stationary phase. The mobile phase is usually an inert gas or an unreactive gas such as helium, argon, nitrogen or hydrogen. The stationary phase is a microscopic la ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Saponification
Saponification is a process of converting esters into soaps and alcohols by the action of aqueous alkali (for example, aqueous sodium hydroxide solutions). Soaps are salts of fatty acids, which in turn are carboxylic acids with long carbon chains. Sodium stearate is a typical soap. Saponification of fats Vegetable oils and animal fats are the traditional materials that are saponified. These greasy materials, triesters called triglycerides, are mixtures derived from diverse fatty acids. Triglycerides can be converted to soap in either a one- or a two-step process. In the traditional one-step process, the triglyceride is treated with a strong base (e.g. lye), which cleaves the ester bond, releasing fatty acid salts (soaps) and glycerol. This process is also the main industrial method for producing glycerol. In some soap-making, the glycerol is left in the soap. If necessary, soaps may be precipitated by salting it out with sodium chloride. Fat in a corpse converts into adipoce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triglyceride
A triglyceride (TG, triacylglycerol, TAG, or triacylglyceride) is an ester derived from glycerol and three fatty acids (from ''tri-'' and ''glyceride''). Triglycerides are the main constituents of body fat in humans and other vertebrates, as well as vegetable fat. They are also present in the blood to enable the bidirectional transference of adipose fat and blood glucose from the liver, and are a major component of human skin oils. Many types of triglycerides exist. One specific classification focuses on saturated and unsaturated types. Saturated fats have ''no'' C=C groups; unsaturated fats feature one or more C=C groups. Unsaturated fats tend to have a lower melting point than saturated analogues; as a result, they are often liquid at room temperature. Chemical structure Triglycerides are tri-esters consisting of a glycerol bound to three fatty acid molecules. Alcohols have a hydroxyl (HO–) group. Organic acids have a carboxyl (–COOH) group. Alcohols and organ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ester
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. Nitrate esters, such as nitroglycerin, are known for their explosive properties. '' Nomenclature Etymology Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Garryales
The Garryales are a small order of dicotyledons, including only two families and three genera. Description Garryales are woody plants that are either hairless or have very fine hairs. Members of the family Garryaceae are evergreen, whereas those of the Eucommiaceae are deciduous and produce latex. All members are dioecious. Taxonomy These belong among the asterids. Under the Cronquist system, the Garryaceae were placed among the Cornales. The Eucommiaceae were given their own order and placed among the Hamamelidae. The Oncothecaceae family has been associated with Garryales, though the link is not strong enough to prove they are related. Subdivisions The order is made up of two families which, between them, contain three genera. These are: * Family Garryaceae **'' Garrya'' **'' Aucuba'' * Family Eucommiaceae **''Eucommia'' Distribution Species in the order are spread between North America and Asia. The various ''Garrya'' species are found in North America, in southern and w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Apiales
The Apiales are an order of flowering plants. The families are those recognized in the APG III system. This is typical of the newer classifications, though there is some slight variation and in particular, the Torriceliaceae may also be divided. Under this definition, well-known members include carrots, celery, parsley, and ''Hedera helix'' (English ivy). The order Apiales is placed within the asterid group of eudicots as circumscribed by the APG III system. Within the asterids, Apiales belongs to an unranked group called the campanulids, and within the campanulids, it belongs to a clade known in phylogenetic nomenclature as Apiidae. In 2010, a subclade of Apiidae named Dipsapiidae was defined to consist of the three orders: Apiales, Paracryphiales, and Dipsacales. Taxonomy Under the Cronquist system, only the Apiaceae and Araliaceae were included here, and the restricted order was placed among the rosids rather than the asterids. The Pittosporaceae were placed within the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tariric Acid
Tariric acid is an acetylenic fatty acid that can be found in the tallow-wood tree, ''Ximenia americana''. Léon-Albert Arnaud (1853–1915) was the first scientist to describe the chemical make-up of tariric acid, an extraction from the glucoside of the " tariri plant" found in Guatemala. Occurrence Tariric acid has been found in several oils and fats of plant origin. It was first isolated in 1892 from the seed oil of a species of '' Picramnia''. It appears in '' Picramnia camboita'' from Brazil, '' Picramnia carpinterae'' from Guatemala, and '' Picramnia lindeniana'' from Mexico. Tariric acid also occurs in the herb ''Marrubium vulgare'' (White horehound), where it is conjectured to have an anti-fungal role. It was found to stimulate lipid accumulation by adipocytes in vitro.Anna Ohtera, Yusaku Miyamae, Naomi Nakai, Atsushi Kawachi, Kiyokazu Kawada, Junkyu Han, Hiroko Isoda, Mohamed Neffati, Toru Akita, Kazuhiro Maejima, Seiji Masuda, Taiho Kambe, Naoki Mori, Kazuhiro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
_GOJFEQ.png "Click for more on -> Argentation Chromatography"){kind=spacer}
