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Perovskite Solar Cells 1
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as the perovskite structure. Many different cations can be embedded in this structure, allowing the development of diverse engineered materials. History The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856). Perovskite's notable crystal structure was first described by Victor Goldschmidt in 1926 in his work on tolerance factors. The crystal structure was later published in 1945 from X-ray diffraction data on barium titanate by Helen Dick Megaw. Occurrence Found in the Earth's mantle, perovskite's occurrence at Khibina Massif is restricted to the silica under-saturated ultramafic rocks and foidolites, due to the instability in a paragenesis w ...
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Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite *** Cassiterite ** Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite *** Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to mod ...
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Barium Titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and Piezoelectricity, piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics. Structure The solid exists in one of four polymorphs depending on temperature. From high to low temperature, these crystal symmetries of the four polymorphs are Cubic crystal system, cubic, Tetragonal crystal system, tetragonal, Orthorhombic crystal system, orthorhombic and Trigonal crystal system, rhombohedral crystal structure. All of these phases exhibit the ferroelectric effect apart from the cubic phase. The high temperature cubic phase is easiest to describe, as it consists of regular corner-sharing octahedral TiO6 units that define a cube with O vertices and Ti- ...
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Arkansas
Arkansas ( ) is a landlocked state in the South Central United States. It is bordered by Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, and Texas and Oklahoma to the west. Its name is from the Osage language, a Dhegiha Siouan language, and referred to their relatives, the Quapaw people. The state's diverse geography ranges from the mountainous regions of the Ozark and Ouachita Mountains, which make up the U.S. Interior Highlands, to the densely forested land in the south known as the Arkansas Timberlands, to the eastern lowlands along the Mississippi River and the Arkansas Delta. Arkansas is the 29th largest by area and the 34th most populous state, with a population of just over 3 million at the 2020 census. The capital and most populous city is Little Rock, in the central part of the state, a hub for transportation, business, culture, and government. The northwestern corner of the state, including the Fayetteville–Springdaleâ ...
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Magnet Cove Igneous Complex
The Magnet Cove igneous complex is a small alkalic ring complex lying to the west of the town of Magnet Cove in Hot Spring County, Arkansas.Geology of Titanium-Mineral Deposits, Eric R. Force, Geological Society of America, 1991,Google Books/ref> It and the adjacent town are so named due to the existence of magnetite and the terrain being a cove, a basin-shaped valley. The complex is of Mesozoic age, intruded into Paleozoic sediments. Mapping was conducted by the geologists Erickson and Blade in 1963. Units within the complex include carbonatite, nepheline syenite, phonolite, and ijolite. In addition to the magnetite which forms both massive lodestone and crystals, the complex is strewn with odd and rare minerals, and is the type locality for five mineral species. Over 100 different minerals have been identified from the area. There are many titanium minerals such as rutile, anatase, brookite, and perovskite, as well as some vanadium mineralization. Some rare-earth-bearing m ...
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Skarn
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals.Ray, G.E., and Webster, I.C.L. (1991): An Overview of Skarn Deposits; in Ore Deposits, Tectonics and Metallogeny in the Canadian Cordillera; McMillan, W.J., compiler, B. C. Ministry of Energy, Mines and Petroleum Resources, Paper 1991-4, pages 213-252.Meinert, L.D., 1992. Skarns and Skarn Deposits; Geoscience Canada, Vol. 19, No. 4, p. 145-162.Hammarstrom, J.M., Kotlyar, B.B., Theodore, T.G., Elliott, J.E., John, D.A., Doebrich, J.L., Nash, J.T., Carlson, R.R., Lee, G.K., Livo, K.E., Klein, D.P., 1995. Cu, Au, and Zn-Pb Skarn Deposits, Chapter 12; United States Geological Survey: Preliminary Compilation of Descriptive Geoenvironmental Mineral Deposit Models: https://pubs.usgs.gov/of/1995/ofr-95-0831/CHAP12.pdf. These minerals form as a res ...
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Carbonate Rock
Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). Calcite can be either dissolved by groundwater or precipitated by groundwater, depending on several factors including the water temperature, pH, and dissolved ion concentrations. Calcite exhibits an unusual characteristic called retrograde solubility in which it becomes less soluble in water as the temperature increases. When conditions are right for precipitation, calcite forms mineral coatings that cement the existing rock grains together or it can fill fractures. Karst topography and caves develop in carbonate rocks because of their solubility in dilute acidic groundwater. Cooling groundwater or mixing of different groundwaters will also create conditions suitable for cave ...
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Contact Metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as ''prograde metamorphism'', while decreasing temperature and pressure characterize ''retrograde metamorphism''. Metamorphic petrology is the study of metamorphism. Metamorphic petrologists re ...
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Euhedral And Anhedral
Euhedral crystals (also known as idiomorphic or automorphic crystals) are those that are well-formed, with sharp, easily recognised faces. The opposite is anhedral (also known as ''xenomorphic'' or ''allotriomorphic''): a rock with an anhedral texture is composed of mineral grains that have no well-formed crystal faces or cross-section shape in thin section. Anhedral crystal growth occurs in a competitive environment with no free space for the formation of crystal faces. An intermediate texture with some crystal face-formation is termed subhedral. Crystals that grow from cooling liquid magma typically do not form smooth faces or sharp crystal outlines. As magma cools, the crystals grow and eventually touch each other, preventing crystal faces from forming properly or at all. When snowflakes crystallize, they do not touch each other. Thus, snowflakes form euhedral, six-sided twinned crystals. In rocks, the presence of euhedral crystals may signify that they formed early in the ...
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Feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three endmembers: * potassium feldspar (K-spar) ...
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Paragenesis
Paragenesis is a petrologic concept meaning an ''equilibrium sequence of mineral phases''. It is used in studies of igneous and metamorphic rock genesis and importantly in studies of the hydrothermal deposition of ore minerals and the rock alteration (vein metasomatism) associated with ore mineral deposits. The concept and application of paragenesis, from the Greek for ''born beside'', was first applied by August Breithaupt in 1849 in his work ''Die Paragenesis der Mineralien''. The paragenetic sequence in mineral formation is an important concept in deciphering the detailed geologic history of ore deposits and metamorphic events. The sequence is worked out through detailed microscopic studies in polished ore mineral section, petrologic thin section In optical mineralogy and petrography, a thin section (or petrographic thin section) is a thin slice of a rock or mineral sample, prepared in a laboratory, for use with a polarizing petrographic microscope, electron microscope a ...
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Foidolite
Foidolite () is a rare phaneritic (coarse-grained) intrusive igneous rock in which more than 60% (by volume) of light-coloured minerals are feldspathoids. Crystals of alkali feldspar, plagioclase, biotite, amphibole, pyroxene, and/or olivine may be present within the rock. The volcanic equivalents are termed foidite and ''phonolitic or tephritic foidites''. Some foidolites are a potential source of aluminium. See also *QAPF diagram A QAPF diagram is a double ternary diagram which is used to classify igneous rocks based on mineralogic composition. The acronym QAPF stands for "Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". These are the mineral groups used f ... References External linksFoidolite(at University of Manitoba) - Retrieved 2009-05-15 Igneous rocks {{petrology-stub ...
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Ultramafic
Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed of usually greater than 90% mafic minerals (dark colored, high magnesium and iron content). The Earth's mantle is composed of ultramafic rocks. Ultrabasic is a more inclusive term that includes igneous rocks with low silica content that may not be extremely enriched in Fe and Mg, such as carbonatites and ultrapotassic igneous rocks. Intrusive ultramafic rocks Intrusive ultramafic rocks are often found in large, layered ultramafic intrusions where differentiated rock types often occur in layers. Such cumulate rock types do not represent the chemistry of the magma from which they crystallized. The ultramafic intrusives include the dunites, peridotites and pyroxenites. Other rare varieties include troctolite which has a greater percenta ...
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