|
Periodic Systems Of Small Molecules
Periodic systems of molecules are charts of molecules similar to the periodic table of the elements. Construction of such charts was initiated in the early 20th century and is still ongoing. It is commonly believed that the periodic law, represented by the periodic chart, is echoed in the behavior of molecules, at least small molecules. For instance, if one replaces any one of the atoms in a triatomic molecule with a rare gas atom, there will be a drastic change in the molecule’s properties. Several goals could be accomplished by constructing an explicit representation of this periodic law as manifested in molecules: (1) a classification scheme for the vast number of molecules that exist, starting with small ones having just a few atoms, for use as a teaching aid and tool for archiving data, (2) forecasting data for molecular properties based on the classification scheme, and (3) a sort of unity with the periodic chart and the periodic system of fundamental particles. Physical p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Periodic Table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of chemistry. It is a graphic formulation of the periodic law, which states that the properties of the chemical elements exhibit an approximate periodic dependence on their atomic numbers. The table is divided into four roughly rectangular areas called blocks. The rows of the table are called periods, and the columns are called groups. Elements from the same group of the periodic table show similar chemical characteristics. Trends run through the periodic table, with nonmetallic character (keeping their own electrons) increasing from left to right across a period, and from down to up across a group, and metallic character (surrendering electrons to other atoms) increasing in the opposite direction. The underlying reason for these trends is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Core Charge
Core charge is the effective nuclear charge experienced by an outer shell electron. In other words, core charge is an expression of the attractive force experienced by the valence electrons to the core of an atom which takes into account the shielding effect of core electrons. Core charge can be calculated by taking the number of protons in the nucleus minus the number of core electrons, also called inner shell electrons, and is always a positive value in neutral atoms. Core charge is a convenient way of explaining trends in the periodic table. Since the core charge increases as you move across a row of the periodic table, the outer-shell electrons are pulled more and more strongly towards the nucleus and the atomic radius decreases. This can be used to explain a number of periodic trends such as atomic radius, first ionization energy (IE), electronegativity, and oxidizing. Core charge can also be calculated as 'atomic number' minus 'all electrons except those in the outer shell' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aufbau Principle
The aufbau principle , from the German ''Aufbauprinzip'' (building-up principle), also called the aufbau rule, states that in the ground state of an atom or ion, electrons fill subshells of the lowest available energy, then they fill subshells of higher energy. For example, the 1s subshell is filled before the 2s subshell is occupied. In this way, the electrons of an atom or ion form the most stable electron configuration possible. An example is the configuration for the phosphorus atom, meaning that the 1s subshell has 2 electrons, and so on. Electron behavior is elaborated by other principles of atomic physics, such as Hund's rule and the Pauli exclusion principle. Hund's rule asserts that if multiple orbitals of the same energy are available, electrons will occupy different orbitals singly and with the same spin before any are occupied doubly. If double occupation does occur, the Pauli exclusion principle requires that electrons that occupy the same orbital must have differ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Spin
In atomic physics, the electron magnetic moment, or more specifically the electron magnetic dipole moment, is the magnetic moment of an electron resulting from its intrinsic properties of spin (physics), spin and electric charge. The value of the electron magnetic moment is The electron magnetic moment has been measured to an accuracy of relative to the Bohr magneton. Magnetic moment of an electron The electron is a charged particle with charge −, where is the elementary charge, unit of elementary charge. Its angular momentum comes from two types of rotation: Spin (physics), spin and orbital motion. From classical electrodynamics, a rotating distribution of electric charge produces a magnetic dipole, so that it behaves like a tiny bar magnet. One consequence is that an external magnetic field exerts a Magnetic moment#Torque on a moment, torque on the electron magnetic moment that depends on the orientation of this dipole with respect to the field. If the electron is visuali ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Model
Atomic theory is the scientific theory that matter is composed of particles called atoms. Atomic theory traces its origins to an ancient philosophical tradition known as atomism. According to this idea, if one were to take a lump of matter and cut it into ever smaller pieces, one would eventually reach a point where the pieces could not be further cut into anything smaller. Ancient Greek philosophers called these hypothetical ultimate particles of matter ''atomos'', a word which meant "uncut". In the early 1800s, the scientist John Dalton noticed that chemical substances seemed to combine and break down into other substances by weight in proportions that suggested that each chemical element is ultimately made up of tiny indivisible particles of consistent weight. Shortly after 1850, certain physicists developed the kinetic theory of gases and of heat, which mathematically modelled the behavior of gases by assuming that they were made of particles. In the early 20th century, Al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solar System
The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar System" and "solar system" structures in theinaming guidelines document. The name is commonly rendered in lower case ('solar system'), as, for example, in the ''Oxford English Dictionary'' an''Merriam-Webster's 11th Collegiate Dictionary''. is the gravity, gravitationally bound system of the Sun and the objects that orbit it. It Formation and evolution of the Solar System, formed 4.6 billion years ago from the gravitational collapse of a giant interstellar molecular cloud. The solar mass, vast majority (99.86%) of the system's mass is in the Sun, with most of the Jupiter mass, remaining mass contained in the planet Jupiter. The four inner Solar System, inner system planets—Mercury (planet), Mercury, Venus, Earth and Mars—are terrest ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arnold Sommerfeld
Arnold Johannes Wilhelm Sommerfeld, (; 5 December 1868 – 26 April 1951) was a German theoretical physicist who pioneered developments in atomic and quantum physics, and also educated and mentored many students for the new era of theoretical physics. He served as doctoral supervisor for many Nobel Prize winners in physics and chemistry (only J. J. Thomson's record of mentorship is comparable to his). He introduced the second quantum number (azimuthal quantum number) and the third quantum number (magnetic quantum number). He also introduced the fine-structure constant and pioneered X-ray wave theory. Early life and education Sommerfeld was born in 1868 to a family with deep ancestral roots in Prussia. His mother Cäcilie Matthias (1839–1902) was the daughter of a Potsdam builder. His father Franz Sommerfeld (1820–1906) was a physician from a leading family in Königsberg, where Arnold's grandfather had resettled from the hinterland in 1822 for a career as Court Postal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Niels Bohr
Niels Henrik David Bohr (; 7 October 1885 – 18 November 1962) was a Danish physicist who made foundational contributions to understanding atomic structure and quantum theory, for which he received the Nobel Prize in Physics in 1922. Bohr was also a philosopher and a promoter of scientific research. Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been supplanted by other models, its underlying principles remain valid. He conceived the principle of complementarity: that items could be separately analysed in terms of contradictory properties, like behaving as a wave or a stream of particles. The notion of complementarity dominated Bohr's thinking in both science and philosophy. Bohr founded the Institute of Theoretical Physics at the University of Cope ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Descriptor
Molecular descriptors play a fundamental role in chemistry, pharmaceutical sciences, environmental protection policy, and health researches, as well as in quality control, being the way molecules, thought of as real bodies, are transformed into numbers, allowing some mathematical treatment of the chemical information contained in the molecule. This was defined by Todeschini and Consonni as: "''The molecular descriptor is the final result of a logic and mathematical procedure which transforms chemical information encoded within a symbolic representation of a molecule into a useful number or the result of some standardized experiment.''" By this definition, the molecular descriptors are divided into two main categories: experimental measurements, such as log P, molar refractivity, dipole moment, polarizability, and, in general, additive physico-chemical properties, and theoretical molecular descriptors, which are derived from a symbolic representation of the molecule and can be fur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reduced Potential Curve
Reduction, reduced, or reduce may refer to: Science and technology Chemistry * Reduction (chemistry), part of a reduction-oxidation (redox) reaction in which atoms have their oxidation state changed. ** Organic redox reaction, a redox reaction that takes place with organic compounds ** Ore reduction: see smelting Computing and algorithms * Reduction (complexity), a transformation of one problem into another problem * Reduction (recursion theory), given sets A and B of natural numbers, is it possible to effectively convert a method for deciding membership in B into a method for deciding membership in A? * Bit Rate Reduction, an audio compression method * Data reduction, simplifying data in order to facilitate analysis * Graph reduction, an efficient version of non-strict evaluation * L-reduction, a transformation of optimization problems which keeps the approximability features * Partial order reduction, a technique for reducing the size of the state-space to be searched by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Grimm's Hydride Displacement Law
Grimm's Hydride Displacement Law is an early hypothesis, formulated in 1925, to describe bioisosterism, the ability of certain chemical groups to function as or mimic other chemical groups. :“Atoms anywhere up to four places in the periodic system before an inert gas change their properties by uniting with one to four hydrogen atoms, in such a manner that the resulting combinations behave like pseudoatoms, which are similar to elements in the groups one to four places respectively, to their right.” According to Grimm, each vertical column (of Table below) would represent a group of isosteres. References # Grimm, H. G. ''Structure and Size of the Non-metallic Hydrides'' ''Z. Electrochem.'' 1925, ''31'', 474–480. # Grimm, H. G. ''On the Systematic Arrangement of Chemical Compounds from the Perspective of Research on Atomic Composition; and on Some Challenges in Experimental Chemistry.'' ''Naturwissenschaften'' 1929, ''17'', 557–564. # Patani, G. A.; LaVoie, E. J. ''Bioi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
