|
Pentanol
An amyl alcohol is any of eight alcohols with the formula C5H12O. A mixture of amyl alcohols (also called amyl alcohol) can be obtained from fusel alcohol. Amyl alcohol is used as a solvent and in esterification, by which is produced amyl acetate and other important products. The name ''amyl alcohol'' without further specification applies to the normal (straight-chain) form, 1-pentanol. These are the 8 alcohols that are structural isomers with molecular formula C5H12O: : Three of these alcohols, 2-methyl-1-butanol, 2-pentanol, and 3-methyl-2-butanol (methyl isopropyl carbinol), are therefore optically active. The most important amyl alcohol is isoamyl alcohol, the chief one generated by fermentation in the production of alcoholic beverages and a constituent of fusel oil Fusel alcohols or fuselol, also sometimes called fusel oils in Europe, are mixtures of several higher alcohols (those with more than two carbons, chiefly amyl alcohol) produced as a by-product of alcoholic fer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pentan-2-ol
2-Pentanol (IUPAC name: pentan-2-ol; also called ''sec''-amyl alcohol) is an organic chemical compound. It is used as a solvent and an intermediate in the manufacturing of other chemicals. 2-Pentanol is a component of many mixtures of amyl alcohols sold industrially. 2-Pentanol is chiral and thus can be obtained as either of two stereoisomers designated as (R)-(−)-2-pentanol and (S)-(+)-2-pentanol. 2-Pentanol has been detected in fresh bananas by gas chromatography–mass spectrometry, at an abundance of 14.26±2.63 ppm. Reactions 2-Pentanol can be manufactured by hydration of pentene Pentenes are alkenes with the chemical formula . Each contains one double bond within its molecular structure. Six different compounds are in this class, differing from each other by whether the carbon atoms are attached linearly or in a branched .... See also * ''sec''-Amyl acetate * 3-Pentanol References Alcohol solvents Alkanols {{alcohol-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
1-Pentanol
1-Pentanol, (or ''n''-pentanol, pentan-1-ol), is an alcohol with five carbon atoms and the molecular formula C5H11OH.CRC Handbook of Chemistry and Physics 65Th Ed. 1-Pentanol is a colourless liquid with a distinctive aroma. It is the straight-chain form of amyl alcohol, one of 8 isomers with that formula. The hydroxyl group (OH) is the active site of many reactions. The ester formed from 1-pentanol and butyric acid is pentyl butyrate, which smells like apricot. The ester formed from 1-pentanol and acetic acid is amyl acetate (also called pentyl acetate), which smells like banana. In 2014, a study was conducted comparing the performance of diesel fuel blends with various proportions of pentanol as an additive. While gaseous emissions increased with higher concentrations of pentanol, particulate emissions decreased.Wei, Liangjie & Cheung, C.s & Huang, Zuohua. (2014). Effect of n-pentanol addition on the combustion, performance and emission characteristics of a direct-injecti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pentan-3-ol
3-Pentanol is one of the eight isomers of amyl alcohol. It is found naturally and has a role as a pheromone. See also * 2-Pentanol 2-Pentanol (IUPAC name: pentan-2-ol; also called ''sec''-amyl alcohol) is an organic chemical compound. It is used as a solvent and an intermediate in the manufacturing of other chemicals. 2-Pentanol is a component of many mixtures of amyl alcohol ... References Alkanols {{alcohol-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alcohols
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula . Simple monoalcohols that are the subject of this article include primary (), secondary () and tertiary () alcohols. The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix ''hydroxy-'' is used in its IUPAC name. The suffix ''-ol'' in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some compound ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isoamyl Alcohol
Isoamyl alcohol is a colorless liquid with the formula , specifically (H3C–)2CH–CH2–CH2–OH. It is one of several isomers of amyl alcohol (pentanol). It is also known as isopentyl alcohol, isopentanol, or (in the IUPAC recommended nomenclature) 3-methyl-butan-1-ol. An obsolete name for it was isobutyl carbinol. Isoamyl alcohol is an ingredient in the production of banana oil, an ester found in nature and also produced as a flavouring in industry. It is a common fusel alcohol, produced as a major by-product of ethanol fermentation. Occurrence Isoamyl alcohol is one of the components of the aroma of ''Tuber melanosporum'', the black truffle. The compound has also been identified as a chemical in the pheromone used by hornets to attract other members of the hive to attack. Isoamyl acetate is a component of the natural aroma of bananas, especially the Gros Michel variety. Extraction from fusel oil Isoamyl alcohol can be separated from fusel oil by either of two methods: sh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2-Methylbutan-2-ol
''tert''-Amyl alcohol (TAA) or 2-methylbutan-2-ol (2M2B), is a branched pentanol. Historically TAA has been used an anesthetic and more recently used as a recreational drug. TAA is mostly a positive allosteric modulator for GABAA receptors in the same way as ethanol. The psychotropic effects of TAA and ethanol are similar, though distinct. Impact on coordination and balance are proportionately more prominent with TAA, which is significantly more potent by weight than ethanol. TAA is a colorless liquid with a burning flavor and an unpleasant odor similar to paraldehyde with a hint of camphor. TAA remains as a liquid at room temperature making it a useful alternative solvent to ''tert''-butyl alcohol. Production TAA is primarily made by the hydration of 2-methyl-2-butene in the presence of an acidic catalyst. Natural occurrence Fusel alcohols like TAA are grain fermentation byproducts and therefore trace amounts of TAA are present in many alcoholic beverages. Traces of TAA have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isoamyl Alcohol
Isoamyl alcohol is a colorless liquid with the formula , specifically (H3C–)2CH–CH2–CH2–OH. It is one of several isomers of amyl alcohol (pentanol). It is also known as isopentyl alcohol, isopentanol, or (in the IUPAC recommended nomenclature) 3-methyl-butan-1-ol. An obsolete name for it was isobutyl carbinol. Isoamyl alcohol is an ingredient in the production of banana oil, an ester found in nature and also produced as a flavouring in industry. It is a common fusel alcohol, produced as a major by-product of ethanol fermentation. Occurrence Isoamyl alcohol is one of the components of the aroma of ''Tuber melanosporum'', the black truffle. The compound has also been identified as a chemical in the pheromone used by hornets to attract other members of the hive to attack. Isoamyl acetate is a component of the natural aroma of bananas, especially the Gros Michel variety. Extraction from fusel oil Isoamyl alcohol can be separated from fusel oil by either of two methods: sh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amyl Acetate
Amyl acetate (pentyl acetate) is an organic compound and an ester with the chemical formula CH3COO H2sub>4CH3 and the molecular weight 130.19g/mol. It is colorless and has a scent similar to bananas and apples. The compound is the condensation product of acetic acid and 1-pentanol. However, esters formed from other pentanol isomers (amyl alcohols), or mixtures of pentanols, are often referred to as amyl acetate. The symptoms of exposure to amyl acetate in humans are dermatitis, central nervous system depression, narcosis and irritation to the eyes and nose. Uses It is used as a flavoring agent, as a paint and lacquer solvent, and in the preparation of penicillin. It is an inactive ingredient in liquid bandages. It is used as a fuel in the Hefner lamp. See also *Isoamyl acetate, also known as banana oil. *Ester In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pentyl
Pentyl is a five-carbon alkyl group or substituent with chemical formula -C5H11. It is the substituent form of the alkane pentane. In older literature, the common non-systematic name amyl was often used for the pentyl group. Conversely, the name pentyl was used for several five-carbon branched alkyl groups, distinguished by various prefixes. The nomenclature has now reversed, with "amyl" being more often used to refer to the terminally branched group also called isopentyl, as in amobarbital. A cyclopentyl group is a ring with the formula -C5H9. The name is also used for the pentyl radical, a pentyl group as an isolated molecule. This free radical is only observed in extreme conditions. Its formula is often written "•" or "• " to indicate that it has one unsatisfied valence bond. Older "pentyl" groups The following names are still used sometimes: Pentyl radical The free radical pentyl was studied by J. Pacansky and A. Gutierrez in 1983. The radical was obtained by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fusel Oil
Fusel alcohols or fuselol, also sometimes called fusel oils in Europe, are mixtures of several higher alcohols (those with more than two carbons, chiefly amyl alcohol) produced as a by-product of alcoholic fermentation. The word ''Fusel'' is German language, German for "bad liquor". Whether fusel alcohol contributes to hangover symptoms is a matter of scientific debate. A Japanese study in 2003 concluded that "the fusel oil in whisky had no effect on the ethanol-induced emetic response" in the Asian house shrew. Additionally, consumption of fusel oils with ethanol suppressed subjects' subsequent taste aversion to alcohol, which suggested subjects' hangover symptoms were lessened, according to the journal. Usage Fusel oil and fusel-oil acetates are used in the lacquer industry as high boiling point solvents. Compounds Excessive concentrations of some alcohols other than ethanol may cause off-flavors, sometimes described as "spicy", "hot", or "solvent-like". Some beverage ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optical Isomerism
In chemistry, an enantiomer ( /ɪˈnænti.əmər, ɛ-, -oʊ-/ ''ih-NAN-tee-ə-mər''; from Ancient Greek ἐνάντιος ''(enántios)'' 'opposite', and μέρος ''(méros)'' 'part') – also called optical isomer, antipode, or optical antipode – is one of two stereoisomers that are non-superposable onto their own mirror image. Enantiomers are much like one's right and left hands, when looking at the same face, they cannot be superposed onto each other. No amount of reorientation will allow the four unique groups on the chiral carbon (see Chirality (chemistry)) to line up exactly. The number of stereoisomers a molecule has can be determined by the number of chiral carbons it has. Stereoisomers include both enantiomers and diastereomers. Diastereomers, like enantiomers, share the same molecular formula and are non-superposable onto each other however, they are not mirror images of each other. A molecule with chirality rotates plane-polarized light. A mixture of equals amou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
