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Napalm is an incendiary mixture of a gelling agent and a volatile petrochemical (usually gasoline (petrol) or diesel fuel). The name is a portmanteau of two of the constituents of the original thickening and gelling agents: coprecipitated aluminium salts of naphthenic acid and palmitic acid. Napalm B is the more modern version of napalm (utilizing polystyrene derivatives) and, although distinctly different in its chemical composition, is often referred to simply as "napalm". A team led by chemist Louis Fieser originally developed napalm for the US Chemical Warfare Service in 1942 in a secret laboratory at Harvard University. Of immediate first interest was its viability as an incendiary device to be used in fire bombing campaigns during World War II; its potential to be coherently projected into a solid stream that would carry for distance (instead of the bloomy fireball of pure gasoline) resulted in widespread adoption in infantry flamethrowers as well. Napalm bur ...
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F100 Napalm
Formula One (also known as Formula 1 or F1) is the highest class of international racing for open-wheel single-seater formula racing cars sanctioned by the Fédération Internationale de l'Automobile (FIA). The World Drivers' Championship, which became the FIA Formula One World Championship in 1981, has been one of the premier forms of racing around the world since its inaugural season in 1950. The word ''formula'' in the name refers to the set of rules to which all participants' cars must conform. A Formula One season consists of a series of races, known as ''Grands Prix'', which take place worldwide on both purpose-built circuits and closed public roads. A points system is used at Grands Prix to determine two annual World Championships: one for drivers, the other for constructors. Each driver must hold a valid Super Licence, the highest class of racing licence issued by the FIA. The races must run on tracks graded "1" (formerly "A"), the highest grade-rating issued ...
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Flamethrower
A flamethrower is a ranged incendiary device designed to project a controllable jet of fire. First deployed by the Byzantine Empire in the 7th century AD, flamethrowers saw use in modern times during World War I, and more widely in World War II as a tactical siege weapon against fortifications. Most military flamethrowers use liquid fuel, typically either gasoline or diesel, but commercial flamethrowers are generally blowtorches using gaseous fuels such as propane; gases are safer in peacetime applications, because their flames have less mass flow rate and dissipate faster, and often are easier to extinguish when necessary. The military use of flamethrowers is restricted through the Protocol on Incendiary Weapons. Apart from the military applications, flamethrowers have peacetime applications where there is a need for controlled burning, such as in sugarcane harvesting and other land-management tasks. Various forms are designed for an operator to carry, while others a ...
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Triethylaluminium
Triethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name it has the formula Al2( C2H5)6 (abbreviated as Al2Et6 or TEA), as it exists as a dimer. This colorless liquid is pyrophoric. It is an industrially important compound, closely related to trimethylaluminium. Structure and bonding The structure and bonding in Al2R6 and diborane are analogous (R = alkyl). Referring to Al2Me6, the Al-C(terminal) and Al-C(bridging) distances are 1.97 and 2.14 Å, respectively. The Al center is tetrahedral. The carbon atoms of the bridging ethyl groups are each surrounded by five neighbors: carbon, two hydrogen atoms and two aluminium atoms. The ethyl groups interchange readily intramolecularly. At higher temperatures, the dimer cracks into monomeric AlEt3. Synthesis and reactions Triethylaluminium can be formed via several routes. The discovery of an efficient route was a significant technological achievement. The multistep process uses aluminium m ...
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Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ...
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Carbon Monoxide
Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest molecule of the oxocarbon family. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds, when insufficient oxygen or heat is present to produce carbon dioxide. There are also numerous environmental and biological sources that generate and emit a significant amount of carbon monoxide. It is important in the production of many compounds, including drugs, fragrances, and fuels. Upon emission into the atmosphere, carbon monoxide affects several processes that contribute to climate change. Carbon monoxide has important biological roles across phylogenetic ...
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Deoxygenation
Deoxygenation is a chemical reaction involving the removal of oxygen atoms from a molecule. The term also refers to the removal of molecular oxygen (O2) from gases and solvents, a step in air-free technique and gas purifiers. As applied to organic compounds, deoxygenation is a component of fuels production as well a type of reaction employed in organic synthesis, e.g. of pharmaceuticals. Deoxygenation of C-O bonds With replacement by H2 The main examples involving the replacement of an oxo group by two hydrogen atoms (A=O → AH2) are hydrogenolysis. Typical examples use metal catalysts and H2 as the reagent. Conditions are typically more forcing than hydrogenation. Stoichiometric reactions that effect deoxygenation include the Wolff–Kishner reduction for aryl ketones. The replacement of a hydroxyl group by hydrogen (A-OH → A-H) is the point of the Barton–McCombie deoxygenation and the Markó–Lam deoxygenation. Biomass valorization Deoxygenation is an important ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A ...
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Flame Tank
A flame tank is a type of tank equipped with a flamethrower, most commonly used to supplement combined arms attacks against fortifications, confined spaces, or other obstacles. The type only reached significant use in the Second World War, during which the United States, Soviet Union, Germany, Italy, Japan, and the United Kingdom (including members of the British Commonwealth) all produced flamethrower-equipped tanks. A number of production methods were used. The flamethrowers used were either modified versions of existing infantry flame weapons (Flammpanzer I and II) or specially designed (Flammpanzer III). They were mounted externally (Flammpanzer II), replaced existing machine gun mounts, or replaced the tank's main armament (Flammpanzer III). Fuel for the flame weapon was either carried inside the tank, in armoured external storage, or in some cases in a special trailer behind the tank ( Churchill Crocodile). Combat effectiveness In comparison to man-portable flamethrowe ...
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Bomb
A bomb is an explosive weapon that uses the Exothermic process, exothermic reaction of an explosive material to provide an extremely sudden and violent release of energy. Detonations inflict damage principally through ground- and atmosphere-transmitted mechanical stress (mechanics), stress, the impact and penetration of pressure-driven projectiles, pressure damage, and explosion-generated effects. Bombs have been utilized since the 11th century starting in East Asia. The term bomb is not usually applied to explosive devices used for civilian purposes such as construction or mining, although the people using the devices may sometimes refer to them as a "bomb". The military use of the term "bomb", or more specifically aerial bomb action, typically refers to airdropped, unpowered explosive weapons most commonly used by air forces and naval aviation. Other military explosive weapons not classified as "bombs" include shell (projectile), shells, depth charges (used in water), or lan ...
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Urban Combat
Urban warfare is combat conducted in urban areas such as towns and cities. Urban combat differs from combat in the open at both the operational and the tactical levels. Complicating factors in urban warfare include the presence of civilians and the complexity of the urban terrain. Urban combat operations may be conducted to capitalize on strategic or tactical advantages associated with the possession or the control of a particular urban area or to deny these advantages to the enemy. Fighting in urban areas negates the advantages that one side may have over the other in armor, heavy artillery, or air support. Ambushes laid down by small groups of soldiers with handheld anti-tank weapons can destroy entire columns of modern armor (as in the First Battle of Grozny), while artillery and air support can be severely reduced if the "superior" party wants to limit civilian casualties as much as possible, but the defending party does not (or even uses civilians as human shields). Some civ ...
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Flamethrowers
A flamethrower is a ranged incendiary device designed to project a controllable jet of fire. First deployed by the Byzantine Empire in the 7th century AD, flamethrowers saw use in modern times during World War I, and more widely in World War II as a tactical siege weapon against fortifications. Most military flamethrowers use liquid fuel, typically either gasoline or diesel, but commercial flamethrowers are generally blowtorches using gaseous fuels such as propane; gases are safer in peacetime applications, because their flames have less mass flow rate and dissipate faster, and often are easier to extinguish when necessary. The military use of flamethrowers is restricted through the Protocol on Incendiary Weapons. Apart from the military applications, flamethrowers have peacetime applications where there is a need for controlled burning, such as in sugarcane harvesting and other land-management tasks. Various forms are designed for an operator to carry, while others are ...
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Vietnam War
The Vietnam War (also known by #Names, other names) was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vietnam and South Vietnam. The north was supported by the Soviet Union, China, and other communist states, while the south was United States in the Vietnam War, supported by the United States and other anti-communism, anti-communist Free World Military Forces, allies. The war is widely considered to be a Cold War-era proxy war. It lasted almost 20 years, with direct U.S. involvement ending in 1973. The conflict also spilled over into neighboring states, exacerbating the Laotian Civil War and the Cambodian Civil War, which ended with all three countries becoming communist states by 1975. After the French 1954 Geneva Conference, military withdrawal from Indochina in 1954 – following their defeat in the First Indochina War – the Viet Minh to ...
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