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Nonextensive Entropy
Entropy is considered to be an extensive property, i.e., that its value depends on the amount of material present. Constantino Tsallis has proposed a nonextensive entropy (Tsallis entropy), which is a generalization of the traditional Boltzmann–Gibbs entropy. The rationale behind the theory is that Gibbs-Boltzmann entropy leads to systems that have a strong dependence on initial conditions. In reality most materials behave quite independently of initial conditions. Nonextensive entropy leads to nonextensive statistical mechanics, whose typical functions are power laws, instead of the traditional exponentials. See also * Tsallis entropy In physics, the Tsallis entropy is a generalization of the standard Boltzmann–Gibbs entropy. Overview The concept was introduced in 1988 by Constantino Tsallis as a basis for generalizing the standard statistical mechanics and is identical in f ... Statistical mechanics Entropy and information Thermodynamic entropy Information ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names ''thermodynamic function'' and ''heat-potential''. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of hea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Extensive Property
Physical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes. According to IUPAC, an intensive quantity is one whose magnitude is independent of the size of the system, whereas an extensive quantity is one whose magnitude is additive for subsystems. The terms ''intensive and extensive quantities'' were introduced into physics by German writer Georg Helm in 1898, and by American physicist and chemist Richard C. Tolman in 1917. An intensive property does not depend on the system size or the amount of material in the system. It is not necessarily homogeneously distributed in space; it can vary from place to place in a body of matter and radiation. Examples of intensive properties include temperature, ''T''; refractive index, ''n''; density, ''ρ''; and hardness, ''η''. By contrast, extensive properties such as the mass, volume and entropy of syst ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Constantino Tsallis
Constantino Tsallis (; el, Κωνσταντίνος Τσάλλης ; born 4 November 1943) is a naturalized Brazilian physicist of Greek descent, working in Rio de Janeiro at Centro Brasileiro de Pesquisas Físicas (CBPF), Brazil. Biography Tsallis was born in Greece, and grew up in Argentina, where he studied physics at Instituto Balseiro, in Bariloche. In 1974, he received a ''Doctorat d'État ès Sciences Physiques'' degree from the University of Paris-Sud. He moved to Brazil in 1975 with his wife and daughter. Tsallis is an External Professor of the Santa Fe Institute. In 2011 he gave a talk ''From Nonlinear Statistical Mechanics to Nonlinear Quantum Mechanics — Concepts and Applications'' at the international symposium on subnuclear physics held in Vatican City. Research Tsallis is credited with introducing the notion of what is known as Tsallis entropy and Tsallis statistics in his 1988 paper "Possible generalization of Boltzmann–Gibbs statistics" published in the '' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tsallis Entropy
In physics, the Tsallis entropy is a generalization of the standard Boltzmann–Gibbs entropy. Overview The concept was introduced in 1988 by Constantino Tsallis as a basis for generalizing the standard statistical mechanics and is identical in form to Havrda–Charvát structural α-entropy, introduced in 1967 within information theory. In scientific literature, the physical relevance of the Tsallis entropy has been debated. However, from the years 2000 on, an increasingly wide spectrum of natural, artificial and social complex systems have been identified which confirm the predictions and consequences that are derived from this nonadditive entropy, such as nonextensive statistical mechanics, which generalizes the Boltzmann–Gibbs theory. Among the various experimental verifications and applications presently available in the literature, the following ones deserve a special mention: # The distribution characterizing the motion of cold atoms in dissipative optical lattices pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boltzmann's Entropy Formula
In statistical mechanics, Boltzmann's equation (also known as the Boltzmann–Planck equation) is a probability equation relating the entropy S, also written as S_\mathrm, of an ideal gas to the multiplicity (commonly denoted as \Omega or W), the number of real microstates corresponding to the gas's macrostate: where k_\mathrm B is the Boltzmann constant (also written as simply k) and equal to 1.380649 × 10−23 J/K, and \log is the natural logarithm function. In short, the Boltzmann formula shows the relationship between entropy and the number of ways the atoms or molecules of a certain kind of thermodynamic system can be arranged. History The equation was originally formulated by Ludwig Boltzmann between 1872 and 1875, but later put into its current form by Max Planck in about 1900. To quote Planck, "the logarithmic connection between entropy and probability was first stated by L. Boltzmann in his kinetic theory of gases". A 'microstate' is a state specified in term ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Initial Conditions
In mathematics and particularly in dynamic systems, an initial condition, in some contexts called a seed value, is a value of an evolving variable at some point in time designated as the initial time (typically denoted ''t'' = 0). For a system of order ''k'' (the number of time lags in discrete time, or the order of the largest derivative in continuous time) and dimension ''n'' (that is, with ''n'' different evolving variables, which together can be denoted by an ''n''-dimensional coordinate vector), generally ''nk'' initial conditions are needed in order to trace the system's variables forward through time. In both differential equations in continuous time and difference equations in discrete time, initial conditions affect the value of the dynamic variables (state variables) at any future time. In continuous time, the problem of finding a closed form solution for the state variables as a function of time and of the initial conditions is called the initial value prob ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Power Law
In statistics, a power law is a Function (mathematics), functional relationship between two quantities, where a Relative change and difference, relative change in one quantity results in a proportional relative change in the other quantity, independent of the initial size of those quantities: one quantity varies as a Exponentiation, power of another. For instance, considering the area of a square in terms of the length of its side, if the length is doubled, the area is multiplied by a factor of four. Empirical examples The distributions of a wide variety of physical, biological, and man-made phenomena approximately follow a power law over a wide range of magnitudes: these include the sizes of craters on the moon and of solar flares, the foraging pattern of various species, the sizes of activity patterns of neuronal populations, the frequencies of words in most languages, frequencies of family names, the species richness in clades of organisms, the sizes of power outages, volcanic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Exponential Function
The exponential function is a mathematical function denoted by f(x)=\exp(x) or e^x (where the argument is written as an exponent). Unless otherwise specified, the term generally refers to the positive-valued function of a real variable, although it can be extended to the complex numbers or generalized to other mathematical objects like matrices or Lie algebras. The exponential function originated from the notion of exponentiation (repeated multiplication), but modern definitions (there are several equivalent characterizations) allow it to be rigorously extended to all real arguments, including irrational numbers. Its ubiquitous occurrence in pure and applied mathematics led mathematician Walter Rudin to opine that the exponential function is "the most important function in mathematics". The exponential function satisfies the exponentiation identity e^ = e^x e^y \text x,y\in\mathbb, which, along with the definition e = \exp(1), shows that e^n=\underbrace_ for positive i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy And Information
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names ''thermodynamic function'' and ''heat-potential''. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of heat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Entropy
In classical thermodynamics, entropy is a property of a thermodynamic system that expresses the direction or outcome of spontaneous changes in the system. The term was introduced by Rudolf Clausius in the mid-nineteenth century from the Greek word τρoπή (''transformation'') to explain the relationship of the internal energy that is available or unavailable for transformations in form of heat and work. Entropy predicts that certain processes are irreversible or impossible, despite not violating the conservation of energy. The definition of entropy is central to the establishment of the second law of thermodynamics, which states that the entropy of isolated systems cannot decrease with time, as they always tend to arrive at a state of thermodynamic equilibrium, where the entropy is highest. Entropy is therefore also considered to be a measure of disorder in the system. Ludwig Boltzmann explained the entropy as a measure of the number of possible microscopic configurations of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
