Nitrochlorobenzene
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Nitrochlorobenzene
Nitrochlorobenzene may refer to: * 2-Nitrochlorobenzene * 3-Nitrochlorobenzene * 4-Nitrochlorobenzene 4-Nitrochlorobenzene is the organic compound with the formula ClC6H4NO2. It is a pale yellow solid. 4-Nitrochlorobenzene is a common intermediate in the production of a number of industrially useful compounds, including common antioxidants found ... {{Short pages monitor ...
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2-Nitrochlorobenzene
2-Nitrochlorobenzene is an organic compound with the formula ClC6H4NO2. It is one of three isomeric nitrochlorobenzenes.Gerald Booth, "Nitro Compounds, Aromatic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim, 2005. It is a yellow crystalline solid that is important as a precursor to other compounds due to its two functional groups. Synthesis Nitrochlorobenzene is typically synthesized by nitration of chlorobenzene in the presence of sulfuric acid: :C6H5Cl + HNO3 → O2NC6H4Cl + H2O This reaction affords a mixture of isomers. Using an acid ratio of 30/56/14, the product mix is typically 34-36% 2-nitrochlorobenzene and 63-65% 4-nitrochlorobenzene, with only about 1% 3-nitrochlorobenzene. Reactions Alkylation and electrophilic aromatic substitution can occur at the chlorinated carbon center, and a diverse array of reactions can be carried out using the nitro group. 2-Nitrochlorobenzene can be reduced to the 2-chloroaniline with Fe/HCl mixture, th ...
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