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Nikolai Menshutkin
Nikolai Aleksandrovich Menshutkin (russian: Николай Александрович Меншуткин; – ) was a Russian chemist who discovered the process of converting a tertiary amine to a quaternary ammonium salt via the reaction with an alkyl halide, now known as the Menshutkin reaction. Biography Menshutkin was born in a merchant family as the sixth son of Alexander Nikolaevitch Menshutkin. He graduated with honors from gymnasium in December 1857, but only by autumn 1858 managed to enroll to the Saint Petersburg State University, as he was still under the prescribed age of 16. He studied at the faculty of physics and mathematics and was nearly expelled in the autumn of 1861 due to some political disturbances. Nevertheless, by the spring of 1862 he attained the master's degree. During the last years he became interested in chemistry, which he studied under Dmitri Mendeleev. While he acquired a sufficient knowledge of theory he was lacking practice, as at that time the en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Saint Petersburg
Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), is the second-largest city in Russia. It is situated on the Neva River, at the head of the Gulf of Finland on the Baltic Sea, with a population of roughly 5.4 million residents. Saint Petersburg is the fourth-most populous city in Europe after Istanbul, Moscow and London, the most populous city on the Baltic Sea, and the world's northernmost city of more than 1 million residents. As Russia's Imperial capital, and a historically strategic port, it is governed as a federal city. The city was founded by Tsar Peter the Great on 27 May 1703 on the site of a captured Swedish fortress, and was named after apostle Saint Peter. In Russia, Saint Petersburg is historically and culturally associated with t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adolph Wilhelm Hermann Kolbe
Adolph Wilhelm Hermann Kolbe (27 September 1818 – 25 November 1884) was a major contributor to the birth of modern organic chemistry. He was a professor at Marburg and Leipzig. Kolbe was the first to apply the term synthesis in a chemical context, and contributed to the philosophical demise of vitalism through synthesis of the organic substance acetic acid from carbon disulfide, and also contributed to the development of structural theory. This was done via modifications to the idea of "radicals" and accurate prediction of the existence of secondary and tertiary alcohols, and to the emerging array of organic reactions through his Kolbe electrolysis of carboxylate salts, the Kolbe-Schmitt reaction in the preparation of aspirin and the Kolbe nitrile synthesis. After studies with Wöhler and Bunsen, Kolbe was involved with the early internationalization of chemistry through work in London (with Frankland). He was elected to the Royal Swedish Academy of Sciences, and won the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Saturated And Unsaturated Compounds
In chemistry, a saturated compound is a chemical compound (or ion) that resists the addition reactions, such as hydrogenation, oxidative addition, and binding of a Lewis acids and bases, Lewis base. The term is used in many contexts and for many classes of chemical compounds. Overall, saturated compounds are less reactive than unsaturated compounds. Saturation is derived from the Latin word ''saturare'', meaning 'to fill'. Organic chemistry Unsaturated compounds generally carry out typical addition reactions that are not possible with saturated compounds such as alkanes. A saturated organic compound has only single bonds between carbon atoms. An important class of saturated compounds are the alkanes. Many saturated compounds have functional groups, e.g., alcohols. Unsaturated organic compounds The concept of saturation can be described using various naming systems, formulas, and Analytical chemistry, analytical tests. For instance, IUPAC nomenclature of organic chemistry, IU ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Primary Alcohol
A primary alcohol is an alcohol in which the hydroxy group is bonded to a primary carbon atom. It can also be defined as a molecule containing a “–CH2OH” group. In contrast, a secondary alcohol has a formula “–CHROH” and a tertiary alcohol has a formula “–CR2OH”, where “R” indicates a carbon-containing group. Examples of primary alcohols include ethanol and 1-butanol. Methanol is also generally regarded as a primary alcohol, including the 1911 edition of the Encyclopædia Britannica,. See also * Alcohol (especially Nomenclature section for discussion on Secondary and Tertiary alcohols.) * Oxidation of primary alcohols to carboxylic acids The oxidation of primary alcohols to carboxylic acids is an important oxidation reaction in organic chemistry. When a primary alcohol is converted to a carboxylic acid, the terminal carbon atom increases its oxidation state by four. Oxidants able ... References {{organic-chem-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Esterification
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. Nitrate esters, such as nitroglycerin, are known for their explosive properties. '' Nomenclature Etymology The ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alcohol (chemistry)
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula . Simple monoalcohols that are the subject of this article include primary (), secondary () and tertiary () alcohols. The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix ''hydroxy-'' is used in its IUPAC name. The suffix ''-ol'' in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some compou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370,000 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Party Of Democratic Reform (Russia)
The Party of Democratic Reform (russian: Партия демократических реформ) was a liberal-monarchist political party in the Russian Empire, founded at the beginning of 1906 during the elections to the First Duma, from elements who found the Cadet programme too leftist Left-wing politics describes the range of political ideologies that support and seek to achieve social equality and egalitarianism, often in opposition to social hierarchy. Left-wing politics typically involve a concern for those in soci .... The party merged with the Party of Peaceful Renovation in 1907. References Political parties established in 1906 Political parties in the Russian Empire 1906 establishments in the Russian Empire Liberal parties in Russia {{Russia-party-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Duma Of The Russian Empire
The State Duma, also known as the Imperial Duma, was the lower house of the Governing Senate in the Russian Empire, while the upper house was the State Council. It held its meetings in the Taurida Palace in St. Petersburg. It convened four times between 27 April 1906 and the collapse of the Empire in February 1917. The first and the second dumas were more democratic and represented a greater number of national types than their successors. The third duma was dominated by gentry, landowners and businessmen. The fourth duma held five sessions; it existed until 2 March 1917, and was formally dissolved on 6 October 1917. History Coming under pressure from the Russian Revolution of 1905, on August 6, 1905 (O.S.), Sergei Witte (appointed by Nicholas II to manage peace negotiations with Japan after the Russo-Japanese War of 1904–1905) issued a manifesto about the convocation of the Duma, initially thought to be a purely advisory body, the so-called Bulygin-Duma. In the subsequent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alexander II Of Russia
Alexander II ( rus, Алекса́ндр II Никола́евич, Aleksándr II Nikoláyevich, p=ɐlʲɪˈksandr ftɐˈroj nʲɪkɐˈlajɪvʲɪtɕ; 29 April 181813 March 1881) was Emperor of Russia, Congress Poland, King of Poland and Grand Duke of Finland from 2 March 1855 until Assassination of Alexander II of Russia, his assassination in 1881. Alexander's most significant reform as emperor was the emancipation reform of 1861, emancipation of Serfdom in Russia, Russia's serfs in 1861, for which he is known as Alexander the Liberator ( rus, Алекса́ндр Освободи́тель, r=Aleksándr Osvobodytel, p=ɐlʲɪˈksandr ɐsvəbɐˈdʲitʲɪlʲ). The tsar was responsible for other reforms, including reorganizing the judicial system, setting up elected local judges, abolishing corporal punishment, promoting local self-government through the ''zemstvo'' system, imposing universal military service, ending some privileges of the nobility, and promoting university e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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