Mayer Function
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Mayer Function
The Mayer f-function is an auxiliary function that often appears in the series expansion of thermodynamic quantities related to classical many-particle systems.Donald Allan McQuarrie, ''Statistical Mechanics'' (HarperCollins, 1976), page 228 It is named after chemist and physicist Joseph Edward Mayer. Definition Consider a system of classical particles interacting through a pair-wise potential :V(\mathbf,\mathbf) where the bold labels \mathbf and \mathbf denote the continuous degrees of freedom associated with the particles, e.g., :\mathbf=\mathbf_i for spherically symmetric particles and :\mathbf=(\mathbf_i,\Omega_i) for rigid non-spherical particles where \mathbf denotes position and \Omega the orientation parametrized e.g. by Euler angles. The Mayer f-function is then defined as :f(\mathbf,\mathbf)=e^-1 where \beta=(k_T)^ the inverse absolute temperature in units of (Temperature times the Boltzmann constant k_)−1 . See also *Virial coefficient *Cluster expansion *Excluded vol ...
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Thermodynamic
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a co ...
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Many-particle System
The many-body problem is a general name for a vast category of physical problems pertaining to the properties of microscopic systems made of many interacting particles. ''Microscopic'' here implies that quantum mechanics has to be used to provide an accurate description of the system. ''Many'' can be anywhere from three to infinity (in the case of a practically infinite, homogeneous or periodic system, such as a crystal), although three- and four-body systems can be treated by specific means (respectively the Faddeev and Faddeev–Yakubovsky equations) and are thus sometimes separately classified as few-body systems. In general terms, while the underlying physical laws that govern the motion of each individual particle may (or may not) be simple, the study of the collection of particles can be extremely complex. In such a quantum system, the repeated interactions between particles create quantum correlations, or entanglement. As a consequence, the wave function of the system is ...
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HarperCollins
HarperCollins Publishers LLC is one of the Big Five English-language publishing companies, alongside Penguin Random House, Simon & Schuster, Hachette, and Macmillan. The company is headquartered in New York City and is a subsidiary of News Corp. The name is a combination of several publishing firm names: Harper & Row, an American publishing company acquired in 1987—whose own name was the result of an earlier merger of Harper & Brothers (founded in 1817) and Row, Peterson & Company—together with Scottish publishing company William Collins, Sons (founded in 1819), acquired in 1989. The worldwide CEO of HarperCollins is Brian Murray. HarperCollins has publishing groups in the United States, Canada, the United Kingdom, Australia, New Zealand, Brazil, India, and China. The company publishes many different imprints, both former independent publishing houses and new imprints. History Collins Harper Mergers and acquisitions Collins was bought by Rupert Murdoch's News Corpora ...
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Joseph Edward Mayer
Joseph Edward Mayer (February 5, 1904, New York City – October 15, 1983) was a chemist who formulated the Mayer expansion in statistical field theory. He was professor of chemistry at the University of California San Diego from 1960 to 1972, and previously at Johns Hopkins University, Columbia University and the University of Chicago. He was married to Nobel Prize-winning physicist Maria Goeppert Mayer from 1930 until her death in 1972. He went to work with James Franck in Göttingen, Germany in 1929, where he met Maria, a student of Max Born. He was a member of the United States National Academy of Sciences (1946), the American Academy of Arts and Sciences (1958), and the American Philosophical Society (1970). Joseph Mayer was president of the American Physical Society from 1973 to 1975. Scientific contributions He developed the cluster expansion method and Mayer-McMillan solution theory. See also *Mayer f-function The Mayer f-function is an auxiliary function that often appe ...
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Euler Angles
The Euler angles are three angles introduced by Leonhard Euler to describe the Orientation (geometry), orientation of a rigid body with respect to a fixed coordinate system.Novi Commentarii academiae scientiarum Petropolitanae 20, 1776, pp. 189–207 (E478PDF/ref> They can also represent the orientation of a mobile frame of reference in physics or the orientation of a general Basis (linear algebra), basis in 3-dimensional linear algebra. Alternative forms were later introduced by Peter Guthrie Tait and George H. Bryan intended for use in aeronautics and engineering. Chained rotations equivalence Euler angles can be defined by elemental geometry or by composition of rotations. The geometrical definition demonstrates that three composed ''elemental rotations'' (rotations about the axes of a coordinate system) are always sufficient to reach any target frame. The three elemental rotations may be #Conventions by extrinsic rotations, extrinsic (rotations about the axes ''xyz'' of t ...
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