Manganese Monosilicide
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Manganese Monosilicide
Manganese monosilicide (MnSi) is an intermetallic compound, a silicide of manganese. It occurs in cosmic dust as the mineral brownleeite. MnSi has a cubic crystal lattice with no inversion center; therefore its crystal structure is helical, with right-hand and left-hand chiralities. MnSi is a paramagnetic metal that turns into a ferromagnet at cryogenic temperatures below 29 K. In the ferromagnetic state, the spatial arrangement of electron spins in MnSi changes with magnetic field, forming helical, conical, skyrmion, and regular ferromagnetic phases. Crystal structure and magnetism Manganese monosilicide is a non-stoichiometric compound, meaning that the 1:1 Mn:Si composition, lattice constant and many other properties vary depending on the synthesis and processing history of the crystal. MnSi has a cubic crystal lattice with no inversion center; therefore its crystal structure is helical, with right-hand and left-hand chiralities. At low temperatures and magnetic fields ...
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Zone Melting
Zone melting (or zone refining, or floating-zone method, or floating-zone technique) is a group of similar methods of purifying crystals, in which a narrow region of a crystal is melted, and this molten zone is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it as it moves through the ingot. The impurities concentrate in the melt, and are moved to one end of the ingot. Zone refining was invented by John Desmond Bernal and further developed by William G. Pfann William G. Pfann (1966) ''Zone Melting'', 2nd edition, John Wiley & Sons in Bell Labs as a method to prepare high purity materials, mainly semiconductors, for manufacturing transistors. Its first commercial use was in germanium, refined to one atom of impurity per ten billion,”Zone melting”, entry in ''The World Book Encyclopedia'', Volume 21, W-X-Y-Z, 1973, page 501. but the process can be extended to virtually any solute–solvent ...
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