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Milli Mass Unit
The milli mass unit or (mmu) is used as a unit of mass by some scientific authors even though this unit is not defined by the IUPAP red book nor by the IUPAC green book. It is a short form of the more formally correct "milli unified atomic mass unit" (mu) and equivalent to of the unified atomic mass unit (u). A more modern name is the millidalton (mDa) since the "unified atomic mass unit" is more and more displaced by the unit dalton. (1 Da = 1 u) Since 1961 the unified atomic mass unit "u" has been defined as the mass of C. Before that the atomic mass unit "amu" was defined as the mass of O (physics) and as the mass of O (chemistry). Thus the publication date in literature ought to be heeded when reading about the milli mass unit as its name does not reveal whether it refers to the old amu or the newer u. The mass excess is usually indicated in mu or mmu. In mass spectrometry the mass accuracy of a mass analyzer is often indicated in mu, even though a more correct unit woul ...
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Units Of Mass
Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different elementary particles, theoretically with the same amount of matter, have nonetheless different masses. Mass in modern physics has multiple definitions which are conceptually distinct, but physically equivalent. Mass can be experimentally defined as a measure of the body's inertia, meaning the resistance to acceleration (change of velocity) when a net force is applied. The object's mass also determines the strength of its gravitational attraction to other bodies. The SI base unit of mass is the kilogram (kg). In physics, mass is not the same as weight, even though mass is often determined by measuring the object's weight using a spring scale, rather than balance scale comparing it directly with known masses. An object on the Moon would weigh less t ...
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IUPAP Red Book
The International Union of Pure and Applied Physics (IUPAP ) is an international non-governmental organization whose mission is to assist in the worldwide development of physics, to foster international cooperation in physics, and to help in the application of physics toward solving problems of concern to humanity. It was established in 1922 and the first General Assembly was held in 1923 in Paris. The Union is domiciled in Geneva, Switzerland. IUPAP carries out this mission by: sponsoring international meetings; fostering communications and publications; encouraging research and education; fostering the free circulation of scientists; promoting international agreements on the use of symbols, units, nomenclature and standards; and cooperating with other organizations on disciplinary and interdisciplinary problems. IUPAP is a member of the International Science Council. IUPAP is the lead organization promoting the adoption of the International Year of Basic Sciences for Sustainab ...
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IUPAC Green Book
''Quantities, Units and Symbols in Physical Chemistry'', also known as the ''Green Book'', is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants, tables listing the properties of elementary particles, chemical elements, and nuclides, and information about conversion factors that are commonly used in physical chemistry. The ''Green Book'' is published by the International Union of Pure and Applied Chemistry (IUPAC) and is based on published, citeable sources. Information in the ''Green Book'' is synthesized from recommendations made by IUPAC, the International Union of Pure and Applied Physics (IUPAP) and the International Organization for Standardization (ISO), including recommendations listed in the IUPAP Red Book ''Symbols, Units, Nomenclature and Fundamental Constants in Physics'' and in the ISO 31 standards. History, list of editions, and translations to non-English languages The third edition of ...
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Unified Atomic Mass Unit
The dalton or unified atomic mass unit (symbols: Da or u) is a non-SI unit of mass widely used in physics and chemistry. It is defined as of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at rest. The atomic mass constant, denoted ''m''u, is defined identically, giving . This unit is commonly used in physics and chemistry to express the mass of atomic-scale objects, such as atoms, molecules, and elementary particles, both for discrete instances and multiple types of ensemble averages. For example, an atom of helium-4 has a mass of . This is an intrinsic property of the isotope and all helium-4 atoms have the same mass. Acetylsalicylic acid (aspirin), , has an average mass of approximately . However, there are no acetylsalicylic acid molecules with this mass. The two most common masses of individual acetylsalicylic acid molecules are , having the most common isotopes, and , in which one carbon is carbon-13. The molecular mass ...
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Dalton (unit)
The dalton or unified atomic mass unit (symbols: Da or u) is a non-SI unit of mass widely used in physics and chemistry. It is defined as of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at rest. The atomic mass constant, denoted ''m''u, is defined identically, giving . This unit is commonly used in physics and chemistry to express the mass of atomic-scale objects, such as atoms, molecules, and elementary particles, both for discrete instances and multiple types of ensemble averages. For example, an atom of helium-4 has a mass of . This is an intrinsic property of the isotope and all helium-4 atoms have the same mass. Acetylsalicylic acid (aspirin), , has an average mass of approximately . However, there are no acetylsalicylic acid molecules with this mass. The two most common masses of individual acetylsalicylic acid molecules are , having the most common isotopes, and , in which one carbon is carbon-13. The molecular mass ...
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Mass Excess
The mass excess of a nuclide is the difference between its actual mass and its mass number in daltons. It is one of the predominant methods for tabulating nuclear mass. The mass of an atomic nucleus is well approximated (less than 0.1% difference for most nuclides) by its mass number, which indicates that most of the mass of a nucleus arises from mass of its constituent protons and neutrons. Thus, the mass excess is an expression of the nuclear binding energy, relative to the binding energy per nucleon of carbon-12 (which defines the dalton). If the mass excess is negative, the nucleus has more binding energy than 12C, and vice versa. If a nucleus has a large excess of mass compared to a nearby nuclear species, it can radioactively decay, releasing energy. Energy scale of nuclear reactions The 12C standard provides a convenient unit (the dalton) in which to express nuclear mass for defining the mass excess. However, its usefulness arises in the calculation of nuclear reaction kinema ...
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Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated accordin ...
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Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated accordin ...
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Thomson (unit)
The thomson (symbol: Th) is a unit that has appeared infrequently in scientific literature relating to the field of mass spectrometry as a unit of mass-to-charge ratio. The unit was proposed by Cooks and Rockwood naming it in honour of J. J. Thomson who measured the mass-to-charge ratio of electrons and ions. Definition The thomson is defined as : 1~\mathrm = 1~\frac \approx 1.036426 \times 10^\,\mathrm where Da is the symbol for the unit dalton (also called the unified atomic mass unit, symbol u), and ''e'' is the elementary charge which is the unit of electric charge in the system of Hartree atomic units. For example, the ion C7H72+ has a mass of 91 Da. Its charge number is +2, and hence its charge is 2''e''. The ion will be observed at 45.5 Th in a mass spectrum. The thomson allows for negative values for negatively charged ions. For example, the benzoate anion would be observed at −121 Th since the charge is −''e''. Use The thomson has been used by some m ...
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Mass-to-charge Ratio
The mass-to-charge ratio (''m''/''Q'') is a physical quantity relating the ''mass'' (quantity of matter) and the ''electric charge'' of a given particle, expressed in units of kilograms per coulomb (kg/C). It is most widely used in the electrodynamics of charged particles, e.g. in electron optics and ion optics. It appears in the scientific fields of electron microscopy, cathode ray tubes, accelerator physics, nuclear physics, Auger electron spectroscopy, cosmology and mass spectrometry. The importance of the mass-to-charge ratio, according to classical electrodynamics, is that two particles with the same mass-to-charge ratio move in the same path in a vacuum, when subjected to the same electric and magnetic fields. On rare occasions, the thomson has been used as its unit in the field of mass spectrometry. Some disciplines use the charge-to-mass ratio (''Q''/''m'') instead, which is the multiplicative inverse of the mass-to-charge ratio. The CODATA recommended value for an ...
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Parts Per Million
In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they are pure numbers with no associated units of measurement. Commonly used are parts-per-million (ppm, ), parts-per-billion (ppb, ), parts-per-trillion (ppt, ) and parts-per-quadrillion (ppq, ). This notation is not part of the International System of Units (SI) system and its meaning is ambiguous. Overview Parts-per notation is often used describing dilute solutions in chemistry, for instance, the relative abundance of dissolved minerals or pollutants in water. The quantity "1 ppm" can be used for a mass fraction if a water-borne pollutant is present at one-millionth of a gram per gram of sample solution. When working with aqueous solutions, it is common to assume that the density of water is 1.00 g/mL. Therefore, it is common to equat ...
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