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Microstructurally Stable Nanocrystalline Alloys
Microstructurally stable nanocrystalline alloys are alloys that are designed to resist microstructural coarsening under various thermo-mechanical loading conditions. Many applications of metal materials require that they can maintain their structure and strength despite very high temperatures. Efforts to prevent deformations from long term stress, referred to as creep, consist of manipulating alloys to reduce coarsening and migration of individual grains within the metal. The small size of individual metal grains provides high interfacial surface energy which is what prompts coarsening, the increase in grain size, and eventually metallic softening. Nanocrystalline creep is considered to follow the Coble creep mechanism, the diffusion of atoms along grain boundaries at low stress levels and high temperatures. One method used to reduce coarsening, is by employing an alloy in which one component has good solubility with another. Since grain size decreases with high solute concentrat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Energy
In surface science, surface free energy (also interfacial free energy or surface energy) quantifies the disruption of intermolecular bonds that occurs when a surface is created. In solid-state physics, surfaces must be intrinsically less energetically favorable than the bulk of the material (the atoms on the surface have more energy compared with the atoms in the bulk), otherwise there would be a driving force for surfaces to be created, removing the bulk of the material (see sublimation). The surface energy may therefore be defined as the excess energy at the surface of a material compared to the bulk, or it is the work required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cut a bulk sample, creating two surfaces. There is "excess energy" as a result of the now-incomplete, unrealized bonding at the two surfaces. Cutting a solid body into pieces disrupts its bonds and increases the surface area, and th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nanocrystalline Material
A nanocrystalline (NC) material is a polycrystalline material with a crystallite size of only a few nanometers. These materials fill the gap between amorphous materials without any long range order and conventional coarse-grained materials. Definitions vary, but nanocrystalline material is commonly defined as a crystallite (grain) size below 100 nm. Grain sizes from 100–500 nm are typically considered "ultrafine" grains. The grain size of a NC sample can be estimated using x-ray diffraction. In materials with very small grain sizes, the diffraction peaks will be broadened. This broadening can be related to a crystallite size using the Scherrer equation (applicable up to ~50 nm), a Williamson-Hall plot, or more sophisticated methods such as the Warren-Averbach method or computer modeling of the diffraction pattern. The crystallite size can be measured directly using transmission electron microscopy. Synthesis Nanocrystalline materials can be prepared in several ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coble Creep
Coble creep, a form of diffusion creep, is a mechanism for deformation of crystalline solids. Contrasted with other diffusional creep mechanisms, Coble creep is similar to Nabarro–Herring creep in that it is dominant at lower stress levels and higher temperatures than creep mechanisms utilizing dislocation glide. Coble creep occurs through the diffusion of atoms in a material along grain boundaries. This mechanism is observed in polycrystals or along the surface in a single crystal, which produces a net flow of material and a sliding of the grain boundaries. Robert L. Coble first reported his theory of how materials creep across grain boundaries and at high temperatures in alumina. Here he famously noticed a different creep mechanism that was more dependent on the size of the grain. The strain rate in a material experiencing Coble creep is given by : \frac \equiv \dot_C = A_C\frac\fracD_0e^ = A_C\frac\fracD_, where : A_c is a geometric prefactor : \sigma is the applied stress ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
United States Army Research Laboratory
The U.S. Army Combat Capabilities Development Command Army Research Laboratory (DEVCOM ARL) is the U.S. Army's foundational research laboratory. ARL is headquartered at the Adelphi Laboratory Center (ALC) in Adelphi, Maryland. Its largest single site is at Aberdeen Proving Ground, Maryland. Other major ARL locations include Research Triangle Park, North Carolina, White Sands Missile Range, New Mexico, Graces Quarters, Maryland, and NASA's Glenn Research Center, Ohio and Langley Research Center, Virginia. ARL also has regional sites in Playa Vista, California (ARL West), Chicago (ARL Central), Austin, TX (ARL South), and Boston (ARL Northeast). DEVCOM ARL has three directorates: *Army Research Office, located in Research Triangle Park *Army Research Directorate *Research Business Directorate History Before the forming of the ARL, the United States Army had research facilities dating back to 1820 when the laboratory at Watertown Arsenal, Massachusetts, studied pyrotechnic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity (optics), opacity, and lustre (mineralogy), luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in Atomic ratio, atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dislocation Creep
Dislocation creep is a deformation mechanism in crystalline materials. Dislocation creep involves the movement of dislocations through the crystal lattice of the material, in contrast to diffusion creep, in which diffusion (of vacancies) is the dominant creep mechanism. It causes plastic deformation of the individual crystals, and thus the material itself. Dislocation creep is highly sensitive to the differential stress on the material. At low temperatures, it is the dominant deformation mechanism in most crystalline materials. Some of the mechanisms described below are speculative, and either cannot be or have not been verified by experimental microstructural observation. Principles Dislocations in crystals Dislocation creep takes place due to the movement of dislocations through a crystal lattice. Each time a dislocation moves through a crystal, part of the crystal shifts by one lattice point along a plane, relative to the rest of the crystal. The plane that separates the shif ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zener Pinning
Zener pinning is the influence of a dispersion of fine particles on the movement of low- and high-angle grain boundaries through a polycrystalline material. Small particles act to prevent the motion of such boundaries by exerting a pinning pressure which counteracts the driving force pushing the boundaries. Zener pinning is very important in materials processing as it has a strong influence on recovery, recrystallization and grain growth. Origin of the pinning force A boundary is an imperfection in the crystal structure and as such is associated with a certain quantity of energy. When a boundary passes through an incoherent particle then the portion of boundary that would be inside the particle essentially ceases to exist. In order to move past the particle some new boundary must be created, and this is energetically unfavourable. While the region of boundary near the particle is pinned, the rest of the boundary continues trying to move forward under its own driving force. This re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ball Mill
A ball mill is a type of grinder used to grind or blend materials for use in mineral dressing processes, paints, pyrotechnics, ceramics, and selective laser sintering. It works on the principle of impact and attrition: size reduction is done by impact as the balls drop from near the top of the shell. A ball mill consists of a hollow cylindrical shell rotating about its axis. The axis of the shell may be either horizontal or at a small angle to the horizontal. It is partially filled with balls. The grinding media are the balls, which may be made of steel (chrome steel), stainless steel, ceramic, or rubber. The inner surface of the cylindrical shell is usually lined with an abrasion-resistant material such as manganese steel or rubber lining. Less wear takes place in rubber lined mills. The length of the mill is approximately equal to its diameter. The general idea behind the ball mill is an ancient one, but it was not until the industrial revolution and the invention of s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
