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Mesoporous Material
A mesoporous material (or super nanoporous ) is a nanoporous material containing pores with diameters between 2 and 50 nm, according to IUPAC nomenclature. For comparison, IUPAC defines microporous material as a material having pores smaller than 2 nm in diameter and macroporous material as a material having pores larger than 50 nm in diameter. Typical mesoporous materials include some kinds of silica and alumina that have similarly-sized mesopores. Mesoporous oxides of niobium, tantalum, titanium, zirconium, cerium and tin have also been reported. However, the flagship of mesoporous materials is mesoporous carbon, which has direct applications in energy storage devices. Mesoporous carbon has porosity within the mesopore range and this significantly increases the specific surface area. Another very common mesoporous material is activated carbon which is typically composed of a carbon framework with both mesoporosity and microporosity depending on the condit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mesoporous Carbon TEM
A mesoporous material (or super nanoporous ) is a Nanoporous materials, nanoporous material containing wiktionary:pore, pores with diameters between 2 and 50 nm, according to International Union of Pure and Applied Chemistry, IUPAC nomenclature. For comparison, IUPAC defines microporous material as a material having pores smaller than 2 nm in diameter and macroporous material as a material having pores larger than 50 nm in diameter. Typical mesoporous materials include some kinds of Mesoporous silica, silica and Aluminium oxide, alumina that have similarly-sized mesopores. Mesoporous oxides of niobium, tantalum, titanium, zirconium, cerium and tin have also been reported. However, the flagship of mesoporous materials is mesoporous carbon, which has direct applications in energy storage devices. Mesoporous carbon has porosity within the mesopore range and this significantly increases the specific surface area. Another very common mesoporous material is activated ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
John Wiley & Sons
John Wiley & Sons, Inc., commonly known as Wiley (), is an American Multinational corporation, multinational Publishing, publishing company that focuses on academic publishing and instructional materials. The company was founded in 1807 and produces books, Academic journal, journals, and encyclopedias, in print and electronically, as well as online products and services, training materials, and educational materials for undergraduate, graduate, and continuing education students. History The company was established in 1807 when Charles Wiley opened a print shop in Manhattan. The company was the publisher of 19th century American literary figures like James Fenimore Cooper, Washington Irving, Herman Melville, and Edgar Allan Poe, as well as of legal, religious, and other non-fiction titles. The firm took its current name in 1865. Wiley later shifted its focus to scientific, Technology, technical, and engineering subject areas, abandoning its literary interests. Wiley's son Joh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mesoporous Material
A mesoporous material (or super nanoporous ) is a nanoporous material containing pores with diameters between 2 and 50 nm, according to IUPAC nomenclature. For comparison, IUPAC defines microporous material as a material having pores smaller than 2 nm in diameter and macroporous material as a material having pores larger than 50 nm in diameter. Typical mesoporous materials include some kinds of silica and alumina that have similarly-sized mesopores. Mesoporous oxides of niobium, tantalum, titanium, zirconium, cerium and tin have also been reported. However, the flagship of mesoporous materials is mesoporous carbon, which has direct applications in energy storage devices. Mesoporous carbon has porosity within the mesopore range and this significantly increases the specific surface area. Another very common mesoporous material is activated carbon which is typically composed of a carbon framework with both mesoporosity and microporosity depending on the condit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silicon Dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a synthetic product. Examples include fused quartz, fumed silica, opal, and aerogels. It is used in structural materials, microelectronics, and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored. Silicon dioxide is a common fundamental constituent of glass. Structure In the majority of silicon dioxides, the silicon atom shows tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a li ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nanoporous
Nanoporous materials consist of a regular organic or inorganic bulk phase in which a porous structure is present. Nanoporous materials exhibit pore diameters that are most appropriately quantified using units of nanometers. The diameter of pores in nanoporous materials is thus typically 100 nanometers or smaller. Nanoporous materials include subsets of mesoporous (with typical pores having sizes between 2 and 50 nanometers) and microporous materials (typical pores with diameters <2nm). Pores may be open or closed, and pore connectivity and void fraction vary considerably, as with other porous materials. Open pores are pores that connect to the surface of the material whereas closed pores are pockets of void space within a bulk material. Open pores are useful for molecular separation techniques, adsorption, and catalysis studies. Closed pores are mainly used in thermal insulators and for structural applications. Most nanoporous materials ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Characterisation Of Pore Space In Soil
The pore space of soil contains the liquid and gas phases of soil, i.e., everything but the solid phase that contains mainly minerals of varying sizes as well as organic compounds. In order to understand porosity better a series of equations have been used to express the quantitative interactions between the three phases of soil. Macropores or fractures play a major role in infiltration rates in many soils as well as preferential flow patterns, hydraulic conductivity and evapotranspiration. Cracks are also very influential in gas exchange, influencing respiration within soils. Modeling cracks therefore helps understand how these processes work and what the effects of changes in soil cracking such as compaction, can have on these processes. The pore space of soil may contain the habitat of plants (rhizosphere) and microorganisms. Background Dry bulk density : \rho_ = \frac The dry bulk density of a soil greatly depends on the mineral assemblage making up the soil and on ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluid Catalytic Cracking
Fluid catalytic cracking (FCC) is the conversion process used in petroleum refineries to convert the high-boiling point, high-molecular weight hydrocarbon fractions of petroleum (crude oils) into gasoline, alkene gases, and other petroleum products. The cracking of petroleum hydrocarbons was originally done by thermal cracking, now virtually replaced by catalytic cracking, which yields greater volumes of high octane rating gasoline; and produces by-product gases, with more carbon-carbon double bonds (i.e. alkenes), that are of greater economic value than the gases produced by thermal cracking. The feedstock to the FCC conversion process usually is heavy gas oil (HGO), which is that portion of the petroleum (crude oil) that has an initial boiling-point temperature of or higher, at atmospheric pressure, and that has an average molecular weight that ranges from about 200 to 600 or higher; heavy gas oil also is known as "heavy vacuum gas oil" (HVGO). In the fluid catalytic cracking ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photovoltaics
Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially used for electricity generation and as photosensors. A photovoltaic system employs solar modules, each comprising a number of solar cells, which generate electrical power. PV installations may be ground-mounted, rooftop-mounted, wall-mounted or floating. The mount may be fixed or use a solar tracker to follow the sun across the sky. Photovoltaic technology helps to mitigate climate change because it emits much less carbon dioxide than fossil fuels. Solar PV has specific advantages as an energy source: once installed, its operation does not generate any pollution or any greenhouse gas emissions; it shows scalability in respect of power needs and silicon has large availability in the Earth's crust, although other materials required ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optics
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of optical instruments, instruments that use or Photodetector, detect it. Optics usually describes the behaviour of visible light, visible, ultraviolet, and infrared light. Light is a type of electromagnetic radiation, and other forms of electromagnetic radiation such as X-rays, microwaves, and radio waves exhibit similar properties. Most optical phenomena can be accounted for by using the Classical electromagnetism, classical electromagnetic description of light, however complete electromagnetic descriptions of light are often difficult to apply in practice. Practical optics is usually done using simplified models. The most common of these, geometric optics, treats light as a collection of Ray (optics), rays that travel in straight lines and bend when they pass through or reflect from surfaces. Physical optics is a more comprehensive mo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Catalysis
Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst. The rate increase occurs because the catalyst allows the reaction to occur by an alternative mechanism which may be much faster than the noncatalyzed mechanism. However the noncatalyzed mechanism does remain possible, so that the total rate (catalyzed plus noncatalyzed) can only increase in the presence of the catalyst and never decrease. Catalysis may be classified as either homogeneous, whose components are dispersed in the same phase (usual ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silanization
Silanization is the attachment of an organosilyl group to some chemical species. Almost always, silanization is the conversion of a silanol-terminated surface to a alkylsiloxy-terminated surface. This conversion confers hydrophobicity to a previously hydrophilic surface. This process is often used to modify the surface properties of glass, silicon, alumina, quartz, and metal oxide substrates, which all have an abundance of hydroxyl groups. Silanization differs from silylation, which usually refers to attachment of organosilicon groups to molecular substrates. Mechanism Silanization mechanisms vary with substrate and with silanization reagent. In the usual circumstance, surface MOH groups react as nucleophiles with silyl chlorides or silyl alkoxides. The stoichiometry for these reactions are shown: : : M is typically Si, but could be many other elements. The process is assumed to follow the pathways that apply to silylation of molecular substrates, such as alcohols. Properti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quaternary Ammonium Cations
In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure , where R is an alkyl group, an aryl group or organyl group. Unlike the ammonium ion () and the primary, secondary, or tertiary ammonium cations, the quaternary ammonium cations are permanently charged, independent of the pH of their solution. Quaternary ammonium salts or quaternary ammonium compounds (called quaternary amines in oilfield parlance) are salts of quaternary ammonium cations. Polyquats are a variety of engineered polymer forms which provide multiple quat molecules within a larger molecule. Quats are used in consumer applications including as antimicrobials (such as detergents and disinfectants), fabric softeners, and hair conditioners. As an antimicrobial, they are able to inactivate enveloped viruses (such as SARS-CoV-2). Quats tend to be gentler on surfaces than bleach-based disinfectants, and are generally fabric-safe. Synthesis Q ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
