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Malvidin Acetyl-3O-glucoside
Malvidin is an O-methylated anthocyanidin, the 3',5'-methoxy derivative of delphinidin. As a primary plant pigment, its glycosides are highly abundant in nature. Natural occurrences Malvidin is responsible for the blue color found in petals of the ''Primula'' plants of the ''polyanthus'' group. Blue flowers of the blue pimpernel (''Anagallis monelli'') have also a higher concentration of malvidin. It is responsible primarily for the color of red wine, ''Vitis vinifera'' being one of its sources. It is also present in other berries, such as blueberries (''Vaccinium corymbosum'') or the saskatoon berries (''Amelanchier alnifolia''). Chemistry Slightly acidic and neutral solutions of malvidin are characteristically of a red color, while basic solutions of malvidin yield a blue color. The breakdown of malvidin releases syringic acid. Use as a marker in archaeology The breakdown of malvidin releases syringic acid as revealed in the examination of jars containing shedeh, a dri ...
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O-methylated Anthocyanidin
The O-methylated flavonoids or methoxyflavonoids are flavonoids with methylations on hydroxyl groups (methoxy bonds). O-methylation has an effect on the solubility of flavonoids. Enzymes O-methylated flavonoids formation implies the presence of specific O-methyltransferase (OMT) enzymes which accept a variety of substrates. Those enzymes mediate the O-methylation on a specific hydroxyl group, like on 4' (example in ''Catharanthus roseus'') or 3' (example in rice) positions. Those positions can be ortho, meta, para and there can be a special 3-O-methyltransferase for the 3-OH position. Calamondin orange ('' Citrus mitis'') exhibits all of those activities. Plant enzymes * Apigenin 4'-O-methyltransferase * 8-hydroxyquercetin 8-O-methyltransferase * Isoflavone 4'-O-methyltransferase * Isoflavone 7-O-methyltransferase * Isoliquiritigenin 2'-O-methyltransferase * Isoorientin 3'-O-methyltransferase * Kaempferol 4'-O-methyltransferase * Luteolin O-methyltransferase * Methylquercet ...
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Malvin
Malvin is a naturally occurring chemical of the anthocyanin family. Malvin reacts in the presence of H2O2 to form malvone. The ortho-benzoyloxyphenylacetic acid esters reaction product is dependant of the pH: it is obtained under acidic conditions whereas under neutral conditions, the reaction product is the 3-O-acyl-glucosyl-5-O-glucosyl-7-hydroxy coumarin. Natural occurrences It is a diglucoside of malvidin mainly found as a pigment in herbs like Malva (''Malva sylvestris''), ''Primula'' and ''Rhododendron''. ''M. sylvestris'' also contains malonylmalvin (malvidin 3-(6″-malonylglucoside)-5-glucoside).Malonated anthocyanins in malvaceae: Malonylmalvin from Malva sylvestris. Kosaku Takeda, Shigeki Enoki, Jeffrey B. Harborne and John Eagles, Phytochemistry, 1989, Volume 28, Issue 2, Pages 499–500, The characteristic floral jade coloration of ''Strongylodon macrobotrys'' has been shown to be an example of copigmentation, a result of the presence of malvin and saponarin ( ...
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List Of Phytochemicals In Food
While there is ample evidence to indicate the health benefits of diets rich in fruits, vegetables, legumes, whole grains and nuts, no specific food has been acknowledged by scientists and government regulatory authorities as providing a health benefit. Current medical research is focused on whether health effects could be due to specific essential nutrients or to phytochemicals which are not defined as essential. The following is a list of phytochemicals present in commonly consumed foods. Terpenoids (isoprenoids) Carotenoids ( tetraterpenoids) ''Carotenes'' orange pigments * α-Carotene – to vitamin A . * β-Carotene – to vitamin A . * γ-Carotene - to vitamin A, * δ-Carotene * ε-carotene * Lycopene . * Neurosporene * Phytofluene . * Phytoene . ''Xanthophylls'' yellow pigments * Canthaxanthin . * β-Cryptoxanthin to vitamin A . * Zeaxanthin . * Astaxanthin . * Lutein . * Rubixanthin . Triterpenoid * Saponins . * Oleanolic acid . * Ursolic acid . * Be ...
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Geranium
''Geranium'' is a genus of 422 species of annual, biennial, and perennial plants that are commonly known as geraniums or cranesbills. They are found throughout the temperate regions of the world and the mountains of the tropics, but mostly in the eastern part of the Mediterranean region. The palmately cleft leaves are broadly circular in form. The flowers have five petals and are coloured white, pink, purple or blue, often with distinctive veining. Geraniums will grow in any soil as long as it is not waterlogged. Propagation is by semiripe cuttings in summer, by seed, or by division in autumn or spring. Geraniums are eaten by the larvae of some Lepidoptera species including brown-tail, ghost moth, and mouse moth. At least several species of ''Geranium'' are gynodioecious. The species ''Geranium viscosissimum'' (sticky geranium) is considered to be protocarnivorous. Name The genus name is derived from the Greek (''géranos'') or (''geranós'') ' crane'. The English name ' ...
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Petunia Integrifolia Subsp
''Petunia'' is genus of 20 species of flowering plants of South American origin. The popular flower of the same name derived its epithet from the French, which took the word ''petun'', meaning "tobacco," from a Tupi–Guarani language. A tender perennial, most of the varieties seen in gardens are hybrids ( ''Petunia'' × ''atkinsiana'', also known as ''Petunia'' × ''hybrida''). Taxonomy ''Petunia'' is a genus in the family Solanaceae, subfamily Petunioideae. Well known members of Solanaceae in other subfamilies include tobacco (subfamily Nicotianoideae), and the cape gooseberry, tomato, potato, deadly nightshade and chili pepper (subfamily Solanoideae). Some botanists place the plants of the genus '' Calibrachoa'' in the genus ''Petunia'', but this is not accepted by others. ''Petchoa'' is a hybrid genus derived from crossing ''Calibrachoa'' and ''Petunia''. Species Species include: Ecology Petunias are generally insect pollinated, with the exception of '' P. exserta'', w ...
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Acylated Malvidin 3-rutinoside
In chemistry, acylation (or alkanoylation) is the chemical reaction in which an acyl group () is added to a compound. The compound providing the acyl group is called the acylating agent. Because they form a strong electrophile when treated with some metal catalysts, acyl halides are commonly used as acylating agents. For example, Friedel–Crafts acylation uses acetyl chloride (ethanoyl chloride or ) as the agent and aluminum chloride () as a catalyst to add an ethanoyl (acetyl) group to benzene: The mechanism of this reaction is electrophilic aromatic substitution. Acyl halides and acid anhydrides of carboxylic acids are also commonly used acylating agents. In some cases, active esters exhibit comparable reactivity. All react with amines to form amides and with alcohols to form esters by nucleophilic acyl substitution. Acylation can be used to prevent rearrangement reactions that would normally occur in alkylation. To do this an acylation reaction is performed, then the carb ...
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Curcuma Alismatifolia
''Curcuma alismatifolia'', Siam tulip or summer tulip ( th, ปทุมมา, ; , ; , ) is a tropical plant native to Laos, northern Thailand, and Cambodia. Despite its name, it is not related to the tulip, but to the various ginger species such as turmeric. It can grow as an indoor plant, and is also sold as a cut flower. One of the most famous wild fields of Siam tulips is in Pa Hin Ngam National Park in Chaiyaphum Province, Thailand. Malvidin 3-rutinoside Malvidin is an O-methylated anthocyanidin, the 3',5'-methoxy derivative of delphinidin. As a primary plant pigment, its glycosides are highly abundant in nature. Natural occurrences Malvidin is responsible for the blue color found in petals o ... is a pigment responsible for bract color in ''C. alismatifolia''. References alismatifolia Flora of Cambodia Flora of Laos Flora of Thailand Plants described in 1903 {{Zingiberales-stub ...
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Malvidin 3-rutinoside
Malvidin is an O-methylated anthocyanidin, the 3',5'-methoxy derivative of delphinidin. As a primary plant pigment, its glycosides are highly abundant in nature. Natural occurrences Malvidin is responsible for the blue color found in petals of the ''Primula'' plants of the ''polyanthus'' group. Blue flowers of the blue pimpernel (''Anagallis monelli'') have also a higher concentration of malvidin. It is responsible primarily for the color of red wine, ''Vitis vinifera'' being one of its sources. It is also present in other berries, such as blueberries (''Vaccinium corymbosum'') or the saskatoon berries (''Amelanchier alnifolia''). Chemistry Slightly acidic and neutral solutions of malvidin are characteristically of a red color, while basic solutions of malvidin yield a blue color. The breakdown of malvidin releases syringic acid. Use as a marker in archaeology The breakdown of malvidin releases syringic acid as revealed in the examination of jars containing shedeh, a dri ...
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Galactoside
A galactoside is a glycoside containing galactose. The H of the OH group on carbon-1 of galactose is replaced by an organic moiety. Depending on whether the glycosidic bond lies "above" or "below" the plane of the galactose molecule, galactosides are classified as α-galactosides or β-galactosides. A β-galactoside is a type of galactoside in which the glycosidic bond lies above the plane of the galactose residue. The most commonly recognized and used β-galactoside in biochemistry is lactose Lactose is a disaccharide sugar synthesized by galactose and glucose subunits and has the molecular formula C12H22O11. Lactose makes up around 2–8% of milk (by mass). The name comes from ' (gen. '), the Latin word for milk, plus the suffix '' - .... However, other chemicals, such as ONPG, are known, but these are typically synthesized for biochemical assays. Galactosides play significant roles in metabolic processes of many organisms and are hydrolyzed by a class of enzymes called ga ...
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Primulin (flavonoid)
Primulin is an anthocyanin. It is the 3-galactoside A galactoside is a glycoside containing galactose. The H of the OH group on carbon-1 of galactose is replaced by an organic moiety. Depending on whether the glycosidic bond lies "above" or "below" the plane of the galactose molecule, galactosides ... of malvidin. It can be found in '' Primula sinensis''. The first crystalline form of this pigment was prepared by Rose Scott-Moncrieff in about 1930. This was the first crystalline anthrocyanine pigment ever identified. This was possible because of her insight into linking genetics with chemistry.Rose Scott-Moncrieff and the dawn of (Bio) Chemical Genetics
Cathie Martin, April 2016, Biochemical classics, Biochemist.org, Retrieved 5 July 2016


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Oenin
Oenin is an anthocyanin. It is the 3-glucoside of malvidin. It is one of the red pigments found in the skin of purple grapes and in wine. Color stabilization of malvidin 3-glucoside at a higher pH can be explained by self-aggregation of the flavylium cation and copigmentation with the Z-chalcone form. In the presence of procyanidin C2, the red color of oenin appears more stable. However, the HPLC chromatogram shows a decrease in the amplitude of the peaks of oenin and procyanidin C2. Concomitantly, a new peak appears with a maximal absorption in the red region. This newly formed pigment probably comes from the condensation of oenin and procyanidin C2. Malvidin 3-glucoside alone is not oxidized in the presence of grape polyphenol oxidase, whereas it is degraded in the presence of a crude grape PPO extract and of caftaric acid forming anthocyanidin-caftaric acid adducts. See also * Phenolic compounds in wine * Wine color * Malvidin glucoside-ethyl-catechin Malvidin glucoside-et ...
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