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Magnetic Resonance
Magnetic resonance is a process by which a physical excitation (resonance) is set up via magnetism. This process was used to develop magnetic resonance imaging and Nuclear magnetic resonance spectroscopy technology. It is also being used to develop Nuclear magnetic resonance quantum computers. History The first observation of electron-spin resonance was in 1944 by Y. K. Zavosky, a Soviet physicist then teaching at Kazan State University (now Kazan Federal University). Nuclear magnetic resonance was first observed in 1946 in the US by a team led by Felix Bloch at the same time as a separate team led by Edward Mills Purcell, the two of whom would later be the 1952 Nobel Laureates in Physics. See also *Resonant inductive coupling, a method of transferring electrical power * Magnetic resonance (quantum mechanics), a quantum resonance process *Nuclear magnetic resonance, a special case * Giant resonance *Electron paramagnetic resonance Electron paramagnetic resonance (EPR ...
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Magnetic Resonance (quantum Mechanics)
In quantum mechanics, magnetic resonance is a resonant effect that can appear when a magnetic dipole is exposed to a static magnetic field and perturbed with another, oscillating electromagnetic field. Due to the static field, the dipole can assume a number of discrete energy eigenstates, depending on the value of its angular momentum (azimuthal) quantum number. The oscillating field can then make the dipole transit between its energy states with a certain probability and at a certain rate. The overall transition probability will depend on the field's frequency and the rate will depend on its amplitude. When the frequency of that field leads to the maximum possible transition probability between two states, a magnetic resonance has been achieved. In that case, the energy of the photons composing the oscillating field matches the energy difference between said states. If the dipole is tickled with a field oscillating far from resonance, it is unlikely to transition. That is anal ...
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Excited State
In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state. The temperature of a group of particles is indicative of the level of excitation (with the notable exception of systems that exhibit negative temperature). The lifetime of a system in an excited state is usually short: spontaneous or induced emission of a quantum of energy (such as a photon or a phonon) usually occurs shortly after the system is promoted to the excited state, returning the system to a state with lower energy (a less excited state or the ground state). This return to a lower energy level is often loosely described as decay and is the inverse of excitation. Long-lived excited states are often called ...
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Edward Mills Purcell
Edward Mills Purcell (August 30, 1912 – March 7, 1997) was an American physicist who shared the 1952 Nobel Prize for Physics for his independent discovery (published 1946) of nuclear magnetic resonance in liquids and in solids. Nuclear magnetic resonance (NMR) has become widely used to study the molecular structure of pure materials and the composition of mixtures. Friends and colleagues knew him as Ed Purcell. Biography Born and raised in Taylorville, Illinois, Purcell received his BSEE in electrical engineering from Purdue University, followed by his M.A. and Ph.D. in physics from Harvard University. He was a member of the Alpha Xi chapter of the Phi Kappa Sigma fraternity while at Purdue. After spending the years of World War II working at the MIT Radiation Laboratory on the development of microwave radar, Purcell returned to Harvard to do research. In December 1946, he discovered nuclear magnetic resonance (NMR) with his colleagues Robert Pound and Henry Torrey. NMR p ...
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Magnetic Resonance Imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio waves to generate images of the organs in the body. MRI does not involve X-rays or the use of ionizing radiation, which distinguishes it from CT and PET scans. MRI is a medical application of nuclear magnetic resonance (NMR) which can also be used for imaging in other NMR applications, such as NMR spectroscopy. MRI is widely used in hospitals and clinics for medical diagnosis, staging and follow-up of disease. Compared to CT, MRI provides better contrast in images of soft-tissues, e.g. in the brain or abdomen. However, it may be perceived as less comfortable by patients, due to the usually longer and louder measurements with the subject in a long, confining tube, though "Open" MRI designs mostly relieve this. Additionally, implants and oth ...
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Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fie ...
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Giant Resonance
Giant resonance is a high-frequency collective excitation of atomic nuclei, as a property of many-body quantum systems. In the macroscopic interpretation of such an excitation in terms of an oscillation, the most prominent giant resonance is a collective oscillation of all protons against all neutrons in a nucleus. In 1947, G. C. Baldwin and G. S. Klaiber observed the giant dipole resonance (GDR) in photonuclear reactions, and in 1972 the giant quadrupole resonance (GQR) was discovered, and in 1977 the giant monopole resonance (GMR) was discovered in medium and heavy nuclei.Chomaz, section 2.2.2.1 Giant dipole resonance Giant dipole resonances may result in a number of de-excitation events, such as nuclear fission, emission of neutrons or gamma rays, or combinations of these. Giant dipole resonances can be caused by any mechanism that imparts enough energy to the nucleus. Classical causes are irradiation with gamma rays at energies from 7 to 40 MeV, which couple to nuclei ...
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Nuclear Magnetic Resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20  tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. ...
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Resonant Inductive Coupling
Resonant inductive coupling or magnetic phase synchronous coupling is a phenomenon with inductive coupling where the coupling becomes stronger when the "secondary" (load-bearing) side of the loosely coupled coil resonates. A resonant transformer of this type is often used in analog circuitry as a bandpass filter. Resonant inductive coupling is also used in wireless power systems for portable computers, phones, and vehicles. Applications Various resonant coupling systems in use or are under development for short range (up to 2 meters) wireless electricity systems to power laptops, tablets, smartphones, robot vacuums, implanted medical devices, and vehicles like electric cars, SCMaglev trains and automated guided vehicles.10 kW) of resonant inductive energy transfer. High power levels are required for rapid recharging and high energy transfer efficiency is required both for operational economy and to avoid negative environmental impact of the system. An experimental ...
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Felix Bloch
Felix Bloch (23 October 1905 – 10 September 1983) was a Swiss-American physicist and Nobel physics laureate who worked mainly in the U.S. He and Edward Mills Purcell were awarded the 1952 Nobel Prize for Physics for "their development of new ways and methods for nuclear magnetic precision measurements."Sohlman, M (Ed.) ''Nobel Foundation directory 2003.'' Vastervik, Sweden: AB CO Ekblad; 2003. In 1954–1955, he served for one year as the first Director-General of CERN. Felix Bloch made fundamental theoretical contributions to the understanding of ferromagnetism and electron behavior in crystal lattices. He is also considered one of the developers of nuclear magnetic resonance. Biography Early life, education, and family Bloch was born in Zürich, Switzerland to Jewish parents Gustav and Agnes Bloch. Gustav Bloch, his father, was financially unable to attend University and worked as a wholesale grain dealer in Zürich. Gustav moved to Zürich in 1890 to become a Swiss c ...
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Resonance
Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillating force is applied at a resonant frequency of a dynamic system, the system will oscillate at a higher amplitude than when the same force is applied at other, non-resonant frequencies. Frequencies at which the response amplitude is a relative maximum are also known as resonant frequencies or resonance frequencies of the system. Small periodic forces that are near a resonant frequency of the system have the ability to produce large amplitude oscillations in the system due to the storage of vibrational energy. Resonance phenomena occur with all types of vibrations or waves: there is mechanical resonance, orbital resonance, acoustic resonance, electromagnetic resonance, nuclear magnetic resonance (NMR), electron spin resonance (ESR) and reso ...
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Kazan Federal University
Kazan (Volga region) Federal University (russian: Казанский (Приволжский) федеральный университет, tt-Cyrl, Казан (Идел буе) федераль университеты) is a public research university located in Kazan, Russia. Founded in 1804 as Imperial Kazan University, astronomer Nikolai Ivanovich Lobachevsky served there as the rector from 1837 until 1876. In 1929, the university was renamed in honour of its student Vladimir Ilyich Ulyanov (Lenin). The university is known as the birthplace of organic chemistry due to works by Aleksandr Butlerov, Vladimir Markovnikov, Aleksandr Arbuzov, and the birthplace of electron spin resonance discovered by Evgeny Zavoisky. In 2011, Kazan University received a federal status. It is also one of 18 Russian universities that were initially selected to participate in the Project 5-100, coordinated by the Government of the Russian Federation and aimed to improve their international competit ...
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Electron-spin Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the field ...
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