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MOX
Mixed oxide fuel, commonly referred to as MOX fuel, is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an alternative to the low-enriched uranium (LEU) fuel used in the light-water reactors that predominate nuclear power generation. For example, a mixture of 7% plutonium and 93% natural uranium reacts similarly, although not identically, to LEU fuel (3 to 5% uranium-235). MOX usually consists of two phases, UO2 and PuO2, and/or a single phase solid solution (U,Pu)O2. The content of PuO2 may vary from 1.5 wt.% to 25–30 wt.% depending on the type of nuclear reactor. One attraction of MOX fuel is that it is a way of utilizing surplus weapons-grade plutonium, an alternative to storage of surplus plutonium, which would need to be secured against the risk of theft for use in nuclear weapons. On the other hand, some studies warned that normalising th ...
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Nuclear Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. A breeder reactor is not restricted to using recycled plutonium and uranium. It can employ all the actinides, closing the nuclear fuel cycle and potentially multiplying the energy extracted from natural uranium by about 60 times. Reprocessing must be highly controlled and carefully executed in advanced facilities by highly specialized personnel. Fuel bundles which arrive at the sites from nuclear power plants (after having cooled down for several years) are completely dissolv ...
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Plutonium
Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthetically produced and isolated in late 1940 and early 1941, by a deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 ( half-life 2.1 days) was synthesized, which subsequently beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since ...
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Nuclear Fuel
Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing and sustaining nuclear fission. The three most relevant fissile isotopes are uranium-233, uranium-235 and plutonium-239. When the unstable nuclei of these atoms are hit by a slow-moving neutron, they frequently split, creating two daughter nuclei and two or three more neutrons. In that case, the neutrons released go on to split more nuclei. This creates a self-sustaining chain reaction that is controlled in a nuclear reactor, or uncontrolled in a nuclear weapon. Alternatively, if the nucleus absorbs the neutron without splitting, it creates a heavier nucleus with one additional neutron. The processes involved in mining, refining, purifying, using, and disposing of nuclear fuel are collectively known as the nuclear fuel cycle. Not all typ ...
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Used Nuclear Fuel
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and depending on its point along the nuclear fuel cycle, it may have considerably different isotopic constituents. The term "fuel" is slightly confusing, as it implies a combustion of some type, which does not occur in a nuclear power plant. Nevertheless, this term is generally accepted. Nature of spent fuel Nanomaterial properties In the oxide fuel, intense temperature gradients exist that cause fission products to migrate. The zirconium tends to move to the centre of the fuel pellet where the temperature is highest, while the lower-boiling fission products move to the edge of the pellet. The pellet is likely to contain many small bubble-like pores that form during use; the fission product xenon migrates to these voids. Some of this xeno ...
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Nuclear Power
Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced by nuclear ''fission'' of uranium and plutonium in nuclear power plants. Nuclear ''decay'' processes are used in niche applications such as radioisotope thermoelectric generators in some space probes such as ''Voyager 2''. Generating electricity from fusion power, ''fusion'' power remains the focus of international research. Most nuclear power plants use thermal reactors with enriched uranium in a Nuclear fuel cycle#Once-through nuclear fuel cycle, once-through fuel cycle. Fuel is removed when the percentage of neutron poison, neutron absorbing atoms becomes so large that a nuclear chain reaction, chain reaction can no longer be sustained, typically three years. It is then cooled for several years in on-site spent fuel pools before being tr ...
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Uranium-238
Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is ''fertile'', meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control. Around 99.284% of natural uranium's mass is uranium-238, which has a half-life of 1.41 seconds (4.468 years, or 4.468 billion years). Due to its natural abundance and half-life relative to other radioactive elements, 238U produces ~40% of the radioactive heat produced within th ...
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Plutonium-239
Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main isotopes demonstrated usable as fuel in thermal spectrum nuclear reactors, along with uranium-235 and uranium-233. Plutonium-239 has a half-life of 24,110 years. Nuclear properties The nuclear properties of plutonium-239, as well as the ability to produce large amounts of nearly pure 239Pu more cheaply than highly enriched weapons-grade uranium-235, led to its use in nuclear weapons and nuclear power plants. The fissioning of an atom of uranium-235 in the reactor of a nuclear power plant produces two to three neutrons, and these neutrons can be absorbed by uranium-238 to produce plutonium-239 and other isotopes. Plutonium-239 can also absorb neutrons and fission along with the uranium-235 in a reactor. Of all the common nuclear fuels ...
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Actinide
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Since ''actinoid'' literally means ''actinium-like'' (cf. ''humanoid'' or ''android''), it has been argued for semantic reasons that actinium cannot logically be an actinoid, but IUPAC acknowledges its inclusion based on common usage. All the actinides are f-block elements, except the final one (lawrencium) which is a d-block element. Actinium has sometimes been considered d-block instead of lawrencium, but the class ...
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Low-enriched Uranium
Enriched uranium is a type of uranium in which the percent composition of uranium-235 (written 235U) has been increased through the process of isotope separation. Naturally occurring uranium is composed of three major isotopes: uranium-238 (238U with 99.2739–99.2752% natural abundance), uranium-235 (235U, 0.7198–0.7202%), and uranium-234 (234U, 0.0050–0.0059%). 235U is the only nuclide existing in nature (in any appreciable amount) that is fissile with thermal neutrons. Enriched uranium is a critical component for both civil nuclear power generation and military nuclear weapons. The International Atomic Energy Agency attempts to monitor and control enriched uranium supplies and processes in its efforts to ensure nuclear power generation safety and curb nuclear weapons proliferation. There are about 2,000 tonnes of highly enriched uranium in the world, produced mostly for nuclear power, nuclear weapons, Nuclear marine propulsion, naval propulsion, and smaller quantiti ...
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Reprocessed Uranium
Reprocessed uranium (RepU) is the uranium recovered from nuclear reprocessing, as done commercially in France, the UK and Japan and by nuclear weapons states' military plutonium production programs. This uranium makes up the bulk of the material separated during reprocessing. Commercial LWR spent nuclear fuel contains on average (excluding cladding) only four percent plutonium, minor actinides and fission products by weight. Despite it often containing more fissile material than natural uranium, reuse of reprocessed uranium has not been common because of low prices in the uranium market of recent decades, and because it contains undesirable isotopes of uranium. Given sufficiently high uranium prices, it is feasible for reprocessed uranium to be re- enriched and reused. A higher enrichment level is required to compensate for the 236U which is lighter than 238U and therefore concentrates in the enriched product. As enrichment concentrates lighter isotopes on the "enriched" side an ...
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Energy
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat and light. Energy is a conserved quantity—the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Common forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, and the internal energy contained within a thermodynamic system. All living organisms constantly take in and release energy. Due to mass–energy equivalence, any object that has mass whe ...
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Nuclear Cross Section
The nuclear cross section of a nucleus is used to describe the probability that a nuclear reaction will occur. The concept of a nuclear cross section can be quantified physically in terms of "characteristic area" where a larger area means a larger probability of interaction. The standard unit for measuring a nuclear cross section (denoted as σ) is the barn, which is equal to , or . Cross sections can be measured for all possible interaction processes together, in which case they are called total cross sections, or for specific processes, distinguishing elastic scattering and inelastic scattering; of the latter, amongst neutron cross sections the absorption cross sections are of particular interest. In nuclear physics it is conventional to consider the impinging particles as point particles having negligible diameter. Cross sections can be computed for any nuclear process, such as capture scattering, production of neutrons, or nuclear fusion. In many cases, the number of partic ...
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