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M. Frederick Hawthorne
Marion Frederick Hawthorne (August 24, 1928 – July 8, 2021) was an inorganic chemist who made contributions to the chemistry of Boranes, boron hydrides, especially their Cluster chemistry, clusters. Early life and education Hawthorne was born on August 24, 1928, in Fort Scott, Kansas, Fort Scott, Kansas. He received his elementary and secondary education in Kansas and Missouri. Prior to high school graduation, he entered the Missouri University of Science and Technology, Missouri School of Mines and Metallurgy, Rolla, Missouri through examination as a chemical engineering student. He then transferred to Pomona College, where he received a B.A. degree in chemistry in 1949. While there he conducted research with Corwin Hansch. Hawthorne completed his Ph.D. in organic chemistry under Donald J. Cram at the University of California, Los Angeles in 1953. He conducted postdoctoral research at Iowa State University with George S. Hammond, before joining the Redstone Arsenal Research Div ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fort Scott, Kansas
Fort Scott is a city in and the county seat of Bourbon County, Kansas, United States. As of the 2020 census, the population of the city was 7,552. It is named for Gen. Winfield Scott. The city is located south of Kansas City on the Marmaton River. It is the home of the Fort Scott National Historic Site and the Fort Scott National Cemetery. History Established and garrisoned by the U.S. Army from 1842–1853, soldiers at military Fort Scott assisted with the protection of the Permanent Indian Frontier. After the army abandoned the fort in 1853, the buildings were purchased by local settlers at a government auction in 1855. The community of Fort Scott was laid out in 1857, and was chartered as a city in 1860. Between 1855 and 1861, the citizens of Fort Scott experienced the violent unrest that preceded the American Civil War on the Kansas and Missouri border. Eastern newspapers described this violence as "Bleeding Kansas", a result of the national controversy concerning t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cluster Chemistry
In chemistry, an atom cluster (or simply cluster) is an ensemble of bound atoms or molecules that is intermediate in size between a simple molecule and a nanoparticle; that is, up to a few nanometers (nm) in diameter. The term ''microcluster'' may be used for ensembles with up to couple dozen atoms. Clusters with a definite number and type of atoms in a specific arrangement are often considered a specific chemical compound and are studied as such. For example, fullerene is a cluster of 60 carbon atoms arranged as the vertices of a truncated icosahedron, and decaborane is a cluster of 10 boron atoms forming an incomplete icosahedron, surrounded by 14 hydrogen atoms. The term is most commonly used for ensembles consisting of several atoms of the same element, or of a few different elements, bonded in a three-dimensional arrangement. Transition metals and main group elements form especially robust clusters. Indeed, in some contexts, the term may refer specifically to a metal cl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dodecaborate
The dodecaborate(12) anion, 12H12sup>2−, is a borane with an icosahedral arrangement of 12 boron atoms, with each boron atom being attached to a hydrogen atom. Its symmetry is classified by the molecular point group Ih. Synthesis and reactions The existence of the dodecaborate(12) anion, 12H12sup>2−, was predicted by H. C. Longuet-Higgins and M. de V. Roberts in 1955. Hawthorne and Pitochelli first made it 5 years later, by the reaction of 2-iododecaborane with triethylamine in benzene solution at 80 °C. It is more conveniently prepared in two steps from sodium borohydride. First the borohydride is converted into a triborate anion using the etherate of boron trifluoride: : 5 NaBH4 + BF3 → 2 NaB3H8 + 3 NaF + 2 H2 Pyrolysis of the triborate gives the twelve-boron cluster as the sodium salt. A variety of other synthetic methods have been published. Salts of the dodecaborate ion are stable in air and do not react with hot aqueous sodium hydroxide or hydrochloric acid. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dodecaborate(12)-dianion-from-xtal-3D-bs-17
The dodecaborate(12) anion, 2−, is a borane with an icosahedral arrangement of 12 boron atoms, with each boron atom being attached to a hydrogen atom. Its symmetry is classified by the molecular point group Ih. Synthesis and reactions The existence of the dodecaborate(12) anion, 2−, was predicted by H. C. Longuet-Higgins and M. de V. Roberts in 1955. Hawthorne and Pitochelli first made it 5 years later, by the reaction of 2-iododecaborane with triethylamine in benzene solution at 80 °C. It is more conveniently prepared in two steps from sodium borohydride. First the borohydride is converted into a triborate anion using the etherate of boron trifluoride: : 5 NaBH4 + BF3 → 2 NaB3H8 + 3 NaF + 2 H2 Pyrolysis of the triborate gives the twelve-boron cluster as the sodium salt. A variety of other synthetic methods have been published. Salts of the dodecaborate ion are stable in air and do not react with hot aqueous sodium hydroxide or hydrochloric acid. The anion can be e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Chemistry (journal)
''Inorganic Chemistry'' is a biweekly peer-reviewed scientific journal published by the American Chemical Society since 1962. It covers research in all areas of inorganic chemistry. The current editor-in-chief is William B. Tolman (Washington University). Abstracting and indexing The journal is abstracted and indexed in: According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 5.436. See also * ''Organometallics ''Organometallics'' is a biweekly journal published by the American Chemical Society. Its area of focus is organometallic and organometalloid chemistry. This peer-reviewed journal has an impact factor of 3.837 as reported by the 2021 Journal Cit ...'' References External links * American Chemical Society academic journals Biweekly journals Publications established in 1962 English-language journals Inorganic chemistry journals {{chem-journal-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nanomedicine
Nanomedicine is the medical application of nanotechnology. Nanomedicine ranges from the medical applications of nanomaterials and BioBrick, biological devices, to Nanoelectronics, nanoelectronic biosensors, and even possible future applications of molecular nanotechnology such as Molecular machine#Biological, biological machines. Current problems for nanomedicine involve understanding the issues related to Nanotoxicology, toxicity and Implications of nanotechnology, environmental impact of Nanomaterials, nanoscale materials (materials whose structure is on the scale of nanometers, i.e. billionths of a meter). Functionalities can be added to nanomaterials by interfacing them with biological molecules or structures. The size of nanomaterials is similar to that of most biological molecules and structures; therefore, nanomaterials can be useful for both in vivo and in vitro biomedical research and applications. Thus far, the integration of nanomaterials with biology has led to the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
University Of California, Riverside
The University of California, Riverside (UCR or UC Riverside) is a public land-grant research university in Riverside, California. It is one of the ten campuses of the University of California system. The main campus sits on in a suburban district of Riverside with a branch campus of in Palm Desert. In 1907, the predecessor to UCR was founded as the UC Citrus Experiment Station, Riverside which pioneered research in biological pest control and the use of growth regulators responsible for extending the citrus growing season in California from four to nine months. Some of the world's most important research collections on citrus diversity and entomology, as well as science fiction and photography, are located at Riverside. UCR's undergraduate College of Letters and Science opened in 1954. The Regents of the University of California declared UCR a general campus of the system in 1959, and graduate students were admitted in 1961. To accommodate an enrollment of 21,000 stud ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alabama
(We dare defend our rights) , anthem = "Alabama (state song), Alabama" , image_map = Alabama in United States.svg , seat = Montgomery, Alabama, Montgomery , LargestCity = Huntsville, Alabama, Huntsville , LargestCounty = Baldwin County, Alabama, Baldwin County , LargestMetro = Birmingham metropolitan area, Alabama, Greater Birmingham , area_total_km2 = 135,765 , area_total_sq_mi = 52,419 , area_land_km2 = 131,426 , area_land_sq_mi = 50,744 , area_water_km2 = 4,338 , area_water_sq_mi = 1,675 , area_water_percent = 3.2 , area_rank = 30th , length_km = 531 , length_mi = 330 , width_km = 305 , width_mi = 190 , Latitude = 30°11' N to 35° N , Longitude = 84°53' W to 88°28' W , elevation_m = 150 , elevation_ft = 500 , elevation_max_m = 735.5 , elevation_max_ft = 2,413 , elevation_max_point = Mount Cheaha , elevation_min_m = 0 , elevation_min_ft = 0 , elevation_min_point = Gulf of Mexico , OfficialLang = English language, English , Languages = * English ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Huntsville, Alabama
Huntsville is a city in Madison County, Limestone County, and Morgan County, Alabama, United States. It is the county seat of Madison County. Located in the Appalachian region of northern Alabama, Huntsville is the most populous city in the state. Huntsville was founded within the Mississippi Territory in 1805 and became an incorporated town in 1811. When Alabama was admitted as a state in 1819, Huntsville was designated for a year as the first capital, before that was moved to more central settlements. The city developed across nearby hills north of the Tennessee River, adding textile mills in the late nineteenth century. Its major growth has taken place since World War II. During the war, the Army established Redstone Arsenal near here with a chemical weapons plant, and nearby related facilities. After the war, additional research was conducted at Redstone Arsenal on rockets, followed by adaptations for space exploration. NASA's Marshall Space Flight Center, the Unit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rohm And Haas
Rohm and Haas Company is a manufacturer of specialty chemicals for end use markets such as building and construction, electronic devices, packaging, household and personal care products. Headquartered in Philadelphia, the company is organized into three business groups of Specialty Materials, Performance Materials and Electronic Materials, and also has two stand-alone businesses of Powder Coatings and Salt. Formerly a Fortune 500 Company, Rohm and Haas employs more than 17,000 people in 27 countries, with its last sales revenue reported as an independent company at US$8.9 billion. Dow Chemical Company bought Rohm and Haas for $15 billion in 2009. History The company was founded in Esslingen, Germany, by Dr. Otto Röhm and Mr. Otto Haas in 1907. Haas moved to Philadelphia and began the American side of the business on September 1, 1909, from an office on Front Street, while Otto Röhm remained in Germany to run a company that would eventually become Röhm GmbH. Röhm improv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
George S
George may refer to: People * George (given name) * George (surname) * George (singer), American-Canadian singer George Nozuka, known by the mononym George * George Washington, First President of the United States * George W. Bush, 43rd President of the United States * George H. W. Bush, 41st President of the United States * George V, King of Great Britain, Ireland, the British Dominions and Emperor of India from 1910-1936 * George VI, King of Great Britain, Ireland, the British Dominions and Emperor of India from 1936-1952 * Prince George of Wales * George Papagheorghe also known as Jorge / GEØRGE * George, stage name of Giorgio Moroder * George Harrison, an English musician and singer-songwriter Places South Africa * George, Western Cape ** George Airport United States * George, Iowa * George, Missouri * George, Washington * George County, Mississippi * George Air Force Base, a former U.S. Air Force base located in California Characters * George (Peppa Pig), a 2-year-old pig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iowa State University
Iowa State University of Science and Technology (Iowa State University, Iowa State, or ISU) is a public land-grant research university in Ames, Iowa. Founded in 1858 as the Iowa Agricultural College and Model Farm, Iowa State became one of the nation's first designated land-grant institution when the Iowa Legislature accepted the provisions of the 1862 Morrill Act on September 11, 1862, making Iowa the first state in the nation to do so. On July 4, 1959, the college was officially renamed Iowa State University of Science and Technology. Iowa State is classified among "R1: Doctoral Universities – Very high research activity". The university is home to the Ames Laboratory, one of ten national U.S. Department of Energy Office of Science research laboratories, the Biorenewables Research Laboratory, the Plant Sciences Institute, and various other research institutes. Iowa State is the second-largest university in the State of Iowa by undergraduate enrollment. The university's ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
