Liquid Metal Fast Reactors
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Liquid Metal Fast Reactors
A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, and plasma), and is the only state with a definite volume but no fixed shape. A liquid is made up of tiny vibrating particles of matter, such as atoms, held together by intermolecular bonds. Like a gas, a liquid is able to flow and take the shape of a container. Most liquids resist compression, although others can be compressed. Unlike a gas, a liquid does not disperse to fill every space of a container, and maintains a fairly constant density. A distinctive property of the liquid state is surface tension, leading to wetting phenomena. Water is by far the most common liquid on Earth. The density of a liquid is usually close to that of a solid, and much higher than that of a gas. Therefore, liquid and solid are both termed condensed m ...
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Water Drop 001
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water cov ...
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Superheating
In thermodynamics, superheating (sometimes referred to as boiling retardation, or boiling delay) is the phenomenon in which a liquid is heated to a temperature higher than its boiling point, without boiling. This is a so-called ''metastable state'' or '' metastate'', where boiling might occur at any time, induced by external or internal effects.Debenedetti, P.G.Metastable Liquids: Concepts and Principles; Princeton University Press: Princeton, NJ, USA, 1996.Maris, H., Balibar, S. (2000"Negative Pressures and Cavitation in Liquid Helium"Physics Today 53, 29 Superheating is achieved by heating a homogeneous substance in a clean container, free of nucleation sites, while taking care not to disturb the liquid. This may occur by microwaving water in a very smooth container. Disturbing the water may cause an unsafe eruption of hot water and result in burns. Cause Water is said to "boil" when bubbles of water vapor grow without bound, bursting at the surface. For a vapor bubbl ...
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Amalgam (chemistry)
An amalgam is an alloy of mercury with another metal. It may be a liquid, a soft paste or a solid, depending upon the proportion of mercury. These alloys are formed through metallic bonding, with the electrostatic attractive force of the conduction electrons working to bind all the positively charged metal ions together into a crystal lattice structure. Almost all metals can form amalgams with mercury, the notable exceptions being iron, platinum, tungsten, and tantalum. Silver-mercury amalgams are important in dentistry, and gold-mercury amalgam is used in the extraction of gold from ore. Dentistry has used alloys of mercury with metals such as silver, copper, indium, tin and zinc. Important amalgams Zinc amalgam Zinc amalgam finds use in organic synthesis (e.g., for the Clemmensen reduction). It is the reducing agent in the Jones reductor, used in analytical chemistry. Formerly the zinc plates of dry batteries were amalgamated with a small amount of mercury to pr ...
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Galinstan
Galinstan (R) is a brand name for a alloy composed of gallium, indium, and tin which melts at and is thus liquid at room temperature. However, it is not a eutectic alloy but a near eutectic alloy. In scientific literature, galinstan is also used as an acronym denoting the eutectic composition of the alloy of Ga-In-Sn, which melts at around . The composition of both alloys is roughly the same, albeit the Galinstan (R), the technical product of a company, has likely additions of flux to improve flowability, reduce melting temperature, and reduce surface tension. The physical properties of the Galinstan (R) and the pure eutectic alloy EGaInSn thus differ slightly. Galinstan is composed of 68.5%Ga, 21.5%In, and 10.0%Sn (by weight). Due to the low toxicity and low reactivity of its component metals, in many applications, galinstan has replaced the toxic liquid mercury or the reactive NaK ( sodium– potassium alloy). Name The name "Galinstan" is a portmanteau of gallium, indium, ...
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Rubidium
Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope 85Rb, and 28% is slightly radioactive 87Rb, with a half-life of 48.8 billion years—more than three times as long as the estimated age of the universe. German chemists Robert Bunsen and Gustav Kirchhoff discovered rubidium in 1861 by the newly developed technique, flame spectroscopy. The name comes from the Latin word , meaning deep red, the color of its emission spectrum. Rubidium's compounds have various chemical and electronic applications. Rubidium metal is easily vaporized and has a convenient spectral absorption range, making it a frequent target for laser manipulation of atoms. Rubidium is not a known nutrient for any living organisms. H ...
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Gallium
Gallium is a chemical element with the symbol Ga and atomic number 31. Discovered by French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in group 13 of the periodic table and is similar to the other metals of the group ( aluminium, indium, and thallium). Elemental gallium is a soft, silvery metal in standard temperature and pressure. In its liquid state, it becomes silvery white. If too much force is applied, the gallium may fracture conchoidally. Since its discovery in 1875, gallium has widely been used to make alloys with low melting points. It is also used in semiconductors, as a dopant in semiconductor substrates. The melting point of gallium is used as a temperature reference point. Gallium alloys are used in thermometers as a non-toxic and environmentally friendly alternative to mercury, and can withstand higher temperatures than mercury. An even lower melting point of , well below the freezing point of water, is claimed for the alloy galinstan ( ...
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Caesium
Caesium ( IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at . It is the least electronegative element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. The element has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the newly developed method of flame spectroscopy. The first small-scale applications fo ...
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Francium
Francium is a chemical element with the symbol Fr and atomic number 87. It is extremely radioactive; its most stable isotope, francium-223 (originally called actinium K after the natural decay chain it appears in), has a half-life of only 22 minutes. It is the second-most electropositive element, behind only caesium, and is the second rarest naturally occurring element (after astatine). The isotopes of francium decay quickly into astatine, radium, and radon. The electronic structure of a francium atom is n7s1, and so the element is classed as an alkali metal. Bulk francium has never been seen. Because of the general appearance of the other elements in its periodic table column, it is presumed that francium would appear as a highly reactive metal, if enough could be collected together to be viewed as a bulk solid or liquid. Obtaining such a sample is highly improbable, since the extreme heat of decay resulting from its short half-life would immediately vaporize any ...
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Room Temperature
Colloquially, "room temperature" is a range of air temperatures that most people prefer for indoor settings. It feels comfortable to a person when they are wearing typical indoor clothing. Human comfort can extend beyond this range depending on humidity, air circulation and other factors. Food or beverages may be served at ''room temperature'', meaning neither heated nor cooled. In certain fields, like science and engineering, and within a particular context, ''room temperature'' can mean different agreed-upon ranges. In contrast, ''ambient temperature'' is the actual temperature, as measured by a thermometer, of the air (or other medium and surroundings) in any particular place. The ambient temperature (e.g. an unheated room in winter) may be very different from an ideal ''room temperature''. Comfort temperatures ''The American Heritage Dictionary of the English Language'' identifies room temperature as around , while the ''Oxford English Dictionary'' states that it is "co ...
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Bromine
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek (bromos) meaning "stench", referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a native element in nature but it occurs in colourless soluble crystalline mineral halide salts, analogous to table salt. In fact, bromine and all the halogens are so reactive that they form bonds in pairs—never in single atoms. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Commer ...
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Mercury (element)
Mercury is a chemical element with the symbol Hg and atomic number 80. It is also known as quicksilver and was formerly named hydrargyrum ( ) from the Greek words, ''hydor'' (water) and ''argyros'' (silver). A heavy, silvery d-block element, mercury is the only metallic element that is known to be liquid at standard temperature and pressure; the only other element that is liquid under these conditions is the halogen bromine, though metals such as caesium, gallium, and rubidium melt just above room temperature. Mercury occurs in deposits throughout the world mostly as cinnabar ( mercuric sulfide). The red pigment vermilion is obtained by grinding natural cinnabar or synthetic mercuric sulfide. Mercury is used in thermometers, barometers, manometers, sphygmomanometers, float valves, mercury switches, mercury relays, fluorescent lamps and other devices, though concerns about the element's toxicity have led to mercury thermometers and sphygmomanometers being largely p ...
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Standard Conditions For Temperature And Pressure
Standard temperature and pressure (STP) are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these are not universally accepted standards. Other organizations have established a variety of alternative definitions for their standard reference conditions. In chemistry, IUPAC changed its definition of standard temperature and pressure in 1982: * Until 1982, STP was defined as a temperature of 273.15  K (0 °C, 32 °F) and an absolute pressure of exactly 1  atm (101.325  kPa). * Since 1982, STP has been defined as a temperature of 273.15  K (0 °C, 32 °F) and an absolute pressure of exactly 105  Pa (100 kPa, 1 bar). STP should not be confused with the standard stat ...
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