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LiPF6
Lithium hexafluorophosphate is an inorganic compound with the formula Li PF6. It is a white crystalline powder. Production LiPF6 is manufactured by reacting phosphorus pentachloride with hydrogen fluoride and lithium fluoride :PCl5 + LiF + 5 HF → LiPF6 + 5 HCl Suppliers include Targray and Morita Chemical Industries Co., Ltd Chemistry The salt is relatively stable thermally, but loses 50% weight at 200 °C (392 °F). It hydrolyzes near 70 °C (158 °F) according to the following equation forming highly toxic HF gas: :LiPF6 + H2O → HF + PF5 + LiOH Owing to the Lewis acidity of the Li+ ions, LiPF6 also catalyses the tetrahydropyranylation of tertiary alcohols. In lithium-ion batteries, LiPF6 reacts with Li2CO3, which may be catalysed by small amounts of HF: :LiPF6 + Li2CO3 → POF3 + CO2 + 3 LiF Application The main use of LiPF6 is in commercial secondary batteries, an application that exploits its high solubility in polar aprotic solvents. S ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium-ion Battery
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also sees significant use for grid-scale energy storage and military and aerospace applications. Compared to other rechargeable battery technologies, Li-ion batteries have high energy densities, low self-discharge, and no memory effect (although a small memory effect reported in LFP cells has been traced to poorly made cells). Chemistry, performance, cost and safety characteristics vary across types of lithium-ion batteries. Most commercial Li-ion cells use intercalation compounds as the active materials. The anode or negative electrode is usually graphite, although silicon-carbon is also being increasingly used. Cells can be manufactured to prioritize either energy or power density. Handheld electronics mostly use lithium polymer batteries ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium Tetrafluoroborate
Lithium tetrafluoroborate is an inorganic compound with the formula Li BF4. It is a white crystalline powder. It has been extensively tested for use in commercial secondary batteries, an application that exploits its high solubility in nonpolar solvents.Xu, Kang. "Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries."Chemical Reviews 2004, volume 104, pp. 4303-418. Applications Although BF4− has high ionic mobility, solutions of its Li+ salt are less conductive than other less associated salts. As an electrolyte in lithium-ion batteries, LiBF4 offers some advantages relative to the more common LiPF6. It exhibits greater thermal stability and moisture tolerance. For example, LiBF4 can tolerate a moisture content up to 620 ppm at room temperature whereas LiPF6 readily hydrolyzes into toxic POF3 and HF gases, often destroying the battery's electrode materials. Disadvantages of the electrolyte include a relatively low conductivity and difficulties forming ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Hexafluorophosphate
Sodium hexafluorophosphate is an inorganic compound with the chemical formula Na F6 In 2015 it has been utilised as a component of non-aqueous electrolyte in rechargeable sodium-ion batteries. NaPF6 can be prepared by the reaction :PCl5 + NaCl + 6 HF → NaPF6 + 6 HCl Further reading * References Sodium compounds Hexafluorophosphates {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrahydropyran
Tetrahydropyran (THP) is the organic compound consisting of a saturated six-membered ring containing five carbon atoms and one oxygen atom. It is named by reference to pyran, which contains two double bonds, and may be produced from it by adding four hydrogens. In 2013, its preferred IUPAC name was established as oxane. The compound is a colourless volatile liquid. Derivatives of tetrahydropyran are, however, more common. 2-Tetrahydropyranyl (THP-) ethers derived from the reaction of alcohols and 3,4-dihydropyran are commonly used as protecting groups in organic synthesis. Furthermore, a tetrahydropyran ''ring system'', i.e., five carbon atoms and an oxygen, is the core of pyranose sugars, such as glucose. Structure and preparation In gas phase, the THP exists in its lowest energy Cs symmetry chair conformation. One classic procedure for the organic synthesis of tetrahydropyran is by hydrogenation of the 3,4-isomer of dihydropyran with Raney nickel. Tetrahydropyranyl deri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium Salts
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly reactive and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. When cut, it exhibits a metallic luster, but moist air corrodes it quickly to a dull silvery gray, then black tarnish. It never occurs freely in nature, but only in (usually ionic) compounds, such as pegmatitic minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from brines. Lithium metal is isolated electrolytically from a mixture of lithium chloride and potassium chloride. The nucleus of the lithium atom verges on instability, since the two stable lithium isotopes found i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolyte
An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also function as electrolytes. El ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vinylene Carbonate
Vinylene carbonate (VC) or 1,3-dioxol-2-one, is the simplest unsaturated cyclic carbonic acid ester. Vinylene carbonate can also be thought of as the cyclic carbonate of the hypothetical (''Z'')-ethene-1,2-diol. The activated double bond in this five-membered oxygen-containing heterocycle makes the molecule a reactive monomer for homopolymerization and copolymerization and a dienophile in Diels-Alder reactions. Below room temperature vinylene carbonate is a colorless stable solid. Preparation Since its first description in 1953, ethylene carbonate has been commonly used as starting material for vinylene carbonate. In the first stage, monochlorethylene carbonate is produced in a UV-initiated photochlorination reaction with chlorine or sulfuryl chloride at 60-70 °C in bulk. In the second stage, monochlorethylenecarbonate undergoes dehydrochlorination with a base such as triethylamine. : Instead of in the liquid phase, the dehydrochlorination may also be carried out in the g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diethyl Carbonate
Diethyl carbonate (sometimes abbreviated DEC) is an ester of carbonic acid and ethanol with the formula OC(OCH2CH3)2. At room temperature (25 °C) diethyl carbonate is a colorless liquid with a low flash point. Diethyl carbonate is used as a solvent such as in erythromycin intramuscular injections. It can be used as a component of electrolytes in lithium batteries. It has been proposed as a fuel additive to support cleaner diesel fuel combustion because its high boiling point might reduce blended fuels' volatility, minimizing vapor buildup in warm weather that can block fuel lines. As a fuel additive, it can reduce emissions such as volatile organic compounds, CO2, and particulates.{{cite journal , last1=Shukla , first1=Kartikeya , last2=Srivastava , first2=Vimal Chandra , date=2016 , title=Diethyl carbonate: critical review of synthesis routes, catalysts used and engineering aspects , url=https://pubs.rsc.org/en/content/pdf/article/2016/ra/c6ra02518h , journal=RSC Advance ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimethyl Carbonate
Dimethyl carbonate (DMC) is an organic compound with the formula OC(OCH3)2. It is a colourless, flammable liquid. It is classified as a carbonate ester. This compound has found use as a methylating agent and more recently as a solvent that is exempt from the restrictions placed on most volatile organic compounds (VOCs) in the US. Dimethyl carbonate is often considered to be a green reagent. Production World production in 1997 was estimated at 1000 barrels a day. Production of dimethyl carbonate worldwide is limited to Asia, the Middle East, and Europe. Dimethyl carbonate is traditionally prepared by the reaction of phosgene and methanol. Methyl chloroformate is produced as an intermediate: : COCl2 + CH3OH → CH3OCOCl + HCl : CH3OCOCl + CH3OH → CH3OCO2CH3 + HCl This synthesis route has been largely replaced by oxidative carbonylation. In this process, carbon monoxide and an oxidizer provide the equivalent of CO2+: :: CO + 1/2 O2 + 2 CH3OH → (CH3O)2CO + H2O It can ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ethylene Carbonate
Ethylene carbonate (sometimes abbreviated EC) is the organic compound with the formula (CH2O)2CO. It is classified as the Cyclic compound, cyclic carbonate ester of ethylene glycol and carbonic acid. At room temperature (25 °C) ethylene carbonate is a transparent crystalline solid, practically odorless and colorless, and somewhat soluble in water. In the liquid state (m.p. 34-37 °C) it is a colorless odorless liquid. JEFFSOL ETHYLENE CARBONATE catalog entry at www.huntsman.com. Accessed on 2010-02-18. Production and reactions Ethylene carbonate is produced by the reaction between ethylene oxide and carbon dioxide. The reaction is catalyzed by a variety of cations and complexes: :(CH2)2O + CO2[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polar Aprotic Solvent
A polar aprotic solvent is a solvent that lacks an acidic proton and is polar. Such solvents lack hydroxyl and amine groups. In contrast to protic solvents, these solvents do not serve as proton donors in hydrogen bonding In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a l ..., although they can be proton acceptors. Many solvents, including chlorocarbons and hydrocarbons, are classifiable as aprotic, but polar aprotic solvents are of particular interest for their ability to dissolve salts. Methods for purification of common solvents are available. References {{Chemical solutions Solvents ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tertiary Alcohol
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula . Simple monoalcohols that are the subject of this article include primary (), secondary () and tertiary () alcohols. The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix ''hydroxy-'' is used in its IUPAC name. The suffix ''-ol'' in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
