Lead Molybdate
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Lead Molybdate
Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore". It crystallizes in the tetragonal system, often occurring as stubby, pyramidal or tabular crystals. It also occurs as earthy, granular masses. It is found in many localities, associated with lead ores as a secondary mineral associated with the oxidized zone of lead deposits. It is also a secondary ore of molybdenum, and is sought by collectors. Discovery and occurrence Wulfenite was first described in 1845 for an occurrence in Bad Bleiberg, Carinthia, Austria. It was named for Franz Xavier von Wulfen (1728–1805), an Austrian mineralogist. It occurs as a secondary mineral in oxidized hydrothermal lead deposits. It occurs with cerussite, anglesite, smithsonite, hemimorphite, vanadinite, pyr ...
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Molybdate Mineral
In chemistry a molybdate is a compound containing an oxoanion with molybdenum in its highest oxidation state of 6. Molybdenum can form a very large range of such oxoanions which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxoanions are members of group of compounds termed polyoxometalates, and because they contain only one type of metal atom are often called isopolymetalates. The discrete molybdenum oxoanions range in size from the simplest , found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, , , and ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten. Examples of molybdate anions Examples of molybdate oxoanion ...
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Hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge crests, and the much-lower-temperature, diffuse flow of water through sedim ...
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Pyramid (geometry)
In geometry, a pyramid () is a polyhedron formed by connecting a polygonal base and a point, called the apex. Each base edge and apex form a triangle, called a ''lateral face''. It is a conic solid with polygonal base. A pyramid with an base has vertices, faces, and edges. All pyramids are self-dual. A right pyramid has its apex directly above the centroid of its base. Nonright pyramids are called oblique pyramids. A regular pyramid has a regular polygon base and is usually implied to be a ''right pyramid''. When unspecified, a pyramid is usually assumed to be a ''regular'' square pyramid, like the physical pyramid structures. A triangle-based pyramid is more often called a tetrahedron. Among oblique pyramids, like acute and obtuse triangles, a pyramid can be called ''acute'' if its apex is above the interior of the base and ''obtuse'' if its apex is above the exterior of the base. A right-angled pyramid has its apex above an edge or vertex of the base. In a tetrahedro ...
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Peca (mountain)
Petzen (German) or Peca ( Slovene) is the highest mountain of the eastern Karawanks, the second-highest mountain of the Northern Karawanks and the most eastern two-thousand-metre mountain of Slovenia. It is a mighty mountain with a characteristic shape of a tableland with rocky peaks protruding from it. The mountain borders the Meža Valley and the Topla Valley to the south and east, and the Jaun Valley to the north, and is separated by the narrow valley of the Bela Creek from Hochobir. Two thirds of the mountain lies in Austria, and one third in Slovenia. The mountain reaches its highest elevation on the mountain crest of the Kordež Head (Slovene: , German: , ). The border runs across it. The mountain is built of Triassic Wetterstein limestone and Wetterstein dolomite. In the past, lead and zinc was mined on Peca, the shafts belonging to the Topla and Mežica mines. The lead-zinc ore occurs in Middle to Upper Triassic carbonate rocks deposited in an anoxic supratidal marine ...
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Mexico
Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatemala, Belize, and the Caribbean Sea; and to the east by the Gulf of Mexico. Mexico covers ,Mexico
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making it the world's 13th-largest country by are ...
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Arizona
Arizona ( ; nv, Hoozdo Hahoodzo ; ood, Alĭ ṣonak ) is a state in the Southwestern United States. It is the 6th largest and the 14th most populous of the 50 states. Its capital and largest city is Phoenix. Arizona is part of the Four Corners region with Utah to the north, Colorado to the northeast, and New Mexico to the east; its other neighboring states are Nevada to the northwest, California to the west and the Mexican states of Sonora and Baja California to the south and southwest. Arizona is the 48th state and last of the contiguous states to be admitted to the Union, achieving statehood on February 14, 1912. Historically part of the territory of in New Spain, it became part of independent Mexico in 1821. After being defeated in the Mexican–American War, Mexico ceded much of this territory to the United States in 1848. The southernmost portion of the state was acquired in 1853 through the Gadsden Purchase. Southern Arizona is known for its desert cl ...
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Plattnerite
Plattnerite is an oxide mineral and is the beta crystalline form of lead dioxide (β-PbO2), scrutinyite being the other, alpha form. It was first reported in 1845 and named after German mineralogist Karl Friedrich Plattner. Plattnerite forms bundles of dark needle-like crystals on various minerals; the crystals are hard and brittle and have tetragonal symmetry. Occurrence Plattnerite is found in numerous arid locations in North America (US and Mexico), most of Europe, Asia (Iran and Russia), Africa (Namibia) and Southern and Western Australia. It occurs in weathered Hydrothermal circulation, hydrothermal base-metal deposits as hay-like bundles of dark prismatic crystals with a length of a few millimeters; the bundles grow on, or sometimes within various minerals, including cerussite, smithsonite, hemimorphite, leadhillite, hydrozincite, rosasite, aurichalcite, murdochite, limonite, pyromorphite, wulfenite, calcite and quartz. Properties and applications Basic properties of plat ...
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Descloizite
Descloizite is a rare mineral species consisting of basic lead and zinc vanadate, , crystallizing in the orthorhombic crystal system and isomorphous with olivenite. Appreciable gallium and germanium may also be incorporated into the crystal structure. The color is deep cherry-red to brown or black, and the crystals are transparent or translucent with a greasy lustre; the streak is orange-yellow to brown; specific gravity 5.9 to 6.2; hardness 31/2. A variety known as cuprodescloizite is dull green in color; it contains a considerable amount of copper replacing zinc and some arsenic replacing vanadium. There is also an arsenate analogue called arsendescloizite. Discovery and occurrence It was discovered in the Sierra de Córdoba deposit in Córdoba, Argentina in 1854 and named in honor of the French mineralogist Alfred Des Cloizeaux (1817–1897). It occurs as small prismatic or pyramidal crystals, usually forming drusy crusts and stalactitic aggregates; also as fibrous encrus ...
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Mimetite
Mimetite is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek Μιμητής ''mimetes'', meaning "imitator" and refers to mimetite's resemblance to the mineral pyromorphite. This resemblance is not coincidental, as mimetite forms a mineral series with pyromorphite () and with vanadinite (). Notable occurrences are Mapimi, Durango, Mexico and Tsumeb, Namibia. Properties Mimetite is a lead chloride arsenate mineral with the composition . It is a secondary mineral, formed by oxidation of primary lead minerals in arsenic-bearing lead deposits. It typically forms short hexagonal crystals that are yellow to brown to orange in color, very brittle, moderately hard (Mohs hardness 3.5-4), and dense (specific gravity 7.24). It is distinctive for its lack of transparency, its resinous to adamantine luster, and its solubility in nitric acid. Mimetite fo ...
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Pyromorphite
Pyromorphite is a mineral species composed of lead chlorophosphate: Pb5( P O4)3 Cl, sometimes occurring in sufficient abundance to be mined as an ore of lead. Crystals are common, and have the form of a hexagonal prism terminated by the basal planes, sometimes combined with narrow faces of a hexagonal pyramid. Crystals with a barrel-like curvature are not uncommon. Globular and reniform masses are also found. It is part of a series with two other minerals: mimetite (Pb5( AsO4)3Cl) and vanadinite (Pb5( VO4)3Cl), the resemblance in external characters is so close that, as a rule, it is only possible to distinguish between them by chemical tests. They were formerly confused under the names green lead ore and brown lead ore (''German: Grünbleierz and Braunbleierz''). The phosphate was first distinguished chemically by M. H. Klaproth in 1784, and it was named pyromorphite by J. F. L. Hausmann in 1813. The name is derived from the Greek for ''pyr'' (fire) and ''morfe'' (form) due to ...
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Vanadinite
Vanadinite is a mineral belonging to the apatite group of phosphates, with the chemical formula Pb5( V O4)3 Cl. It is one of the main industrial ores of the metal vanadium and a minor source of lead. A dense, brittle mineral, it is usually found in the form of red hexagonal crystals. It is an uncommon mineral, formed by the oxidation of lead ore deposits such as galena. First discovered in 1801 in Mexico, vanadinite deposits have since been unearthed in South America, Europe, Africa, and North America. Origins Vanadinite is an uncommon mineral, only occurring as the result of chemical alterations to a pre-existing material. It is therefore known as a secondary mineral. It is found in arid climates and forms by oxidation of primary lead minerals. Vanadinite is especially found in association with the lead sulfide, galena. Other associated minerals include wulfenite, limonite, and barite. It was originally discovered in Mexico by the Spanish mineralogist Andrés Manuel del Río ...
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Hemimorphite
Hemimorphite is the chemical compound Zn4( Si2O7)( OH)2 ·H2O, a component of mineral calamine. It is a silicate mineral which, together with smithsonite (ZnCO3), has been historically mined from the upper parts of zinc and lead ores. Both compounds were originally believed to be the same mineral and classified as calamine. In the second half of the 18th century, it was discovered that these two different compounds were both present in calamine. They closely resemble one another. The silicate was the rarer of the two and was named ''hemimorphite'' because of the hemimorph development of its crystals. This unusual form, which is typical of only a few minerals, means that the crystals are terminated by dissimilar faces. Hemimorphite most commonly forms crystalline crusts and layers, also massive, granular, rounded and reniform aggregates, concentrically striated, or finely needle-shaped, fibrous or stalactitic, and rarely fan-shaped clusters of crystals. Some specimens show stro ...
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