Lead(IV) Fluoride
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Lead(IV) Fluoride
Lead tetrafluoride is a compound of lead and fluorine. The yellow solid (melting point 600 °C) is the only room-temperature stable tetrahalide of lead. Lead tetrafluoride is isostructural with tin(IV) fluoride and contains planar layers of octahedrally coordinated lead, where the octahedra share four corners and there are two terminal, unshared, fluorine atoms ''trans Trans- is a Latin prefix meaning "across", "beyond", or "on the other side of". Used alone, trans may refer to: Arts, entertainment, and media * Trans (festival), a former festival in Belfast, Northern Ireland, United Kingdom * ''Trans'' (film ...'' to one another.Inorganic Chemistry aperback2d Edition, Housecroft, Sharpe,2004, Pearson Education , References Lead(IV) compounds Fluorides Metal halides {{Inorganic-compound-stub ...
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Lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the ...
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Fluorine
Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reactive, as it reacts with all other elements except for the light inert gases. Among the elements, fluorine ranks 24th in universal abundance and 13th in terrestrial abundance. Fluorite, the primary mineral source of fluorine which gave the element its name, was first described in 1529; as it was added to metal ores to lower their melting points for smelting, the Latin verb meaning 'flow' gave the mineral its name. Proposed as an element in 1810, fluorine proved difficult and dangerous to separate from its compounds, and several early experimenters died or sustained injuries from their attempts. Only in 1886 did French chemist Henri Moissan isolate elemental fluorine using low-temperature electrolysis, a process still employed for modern pr ...
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Tin(IV) Fluoride
Tin(IV) fluoride is a chemical compound of tin and fluorine with the chemical formula SnF4 and is a white solid with a melting point above 700 °C. SnF4 can be prepared by the reaction of tin metal with fluorine gas: :Sn + 2F2 → SnF4 However, a passivating metal fluoride layer will be created and the surface will eventually become unreactive. An alternative synthesis is the reaction of SnCl4 with anhydrous hydrogen fluoride: :SnCl4 + 4HF → SnF4 + 4HCl With alkali metal fluorides (e.g. KF) hexafluorostannates are produced (e.g.K2SnF6), which contain the octahedral SnF62− anion. SnF4 behaves as a Lewis acid and adducts L2·SnF4 and L·SnF4 have been produced. Structure Unlike the other tin tetrahalides, tin(IV) chloride, tin(IV) bromide, and tin(IV) iodide, which contain tetrahedrally coordinated tin, tin(IV) fluoride contains planar layers of octahedrally coordinated tin, where the octahedra share four corners and there are two terminal, unshared, fluorine atoms ...
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Lead(IV) Compounds
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, lead is a shiny gray with a hint of blue. It tarnishes to a dull gray color when exposed to air. Lead has the highest atomic number of any stable element and three of its isotopes are endpoints of major nuclear decay chains of heavier elements. Lead is toxic, even in small amounts, especially to children. Lead is a relatively unreactive post-transition metal. Its weak metallic character is illustrated by its amphoteric nature; lead and lead oxides react with acids and bases, and it tends to form covalent bonds. Compounds of lead are usually found in the +2 oxidation state rather than the +4 state common with lighter members of the carbon group. Exceptions are mostly limited to organolead compounds. Like the lighter members of the grou ...
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Fluorides
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nomenc ...
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